Nitrate reduction by green rusts modified with trace metals

A kinetic study of nitrate reduction by green rust (GR), a group of layered Fe(II)-Fe(III) hydroxide solids, was performed using a batch reactor system. The reduction rate of nitrate by GRs was affected by the anion content in the interlayer of GRs. GR containing F^- (GR-F) showed the fastest reduction rate while GR-SO₄ showed 9 times slower reaction rate than GR-F. The addition of 1 mM Pt or Cu to GR that contained 85 mM Fe(II) improved the reduction kinetics of nitrate by up to 200 times. Pt was an effective activating agent for all GRs. The sequential step reaction model that we proposed appropriately simulated the experimental data. The fastest nitrate reduction by GR-F with Pt was achieved at pH 9 among 7.5 to 11. At that condition, 1 mM nitrate transformed completely into ammonium within 23 min.     

Application of Wavelet Coherence Method to Investigate Karst Spring Discharge Response to Climate Teleconnection Patterns

The impact of climate teleconnections on the regional hydrometeorology has been well studied, but very little effort has been made to relate climate teleconnections with groundwater flow variation. In this study, we used a wavelet coherence method to analyze monthly climate indices, precipitation, and spring discharge data, and investigated the relation between major teleconnection patterns (the Arctic Oscillation, North Atlantic Oscillation, Pacific Decadal Oscillation, El Niño‐Southern Oscillation, and Indian Ocean Dipole) and karst hydrological process in Niangziguan Springs Basin, China. The results indicate precipitation and spring discharges correlate well with climate indices at intra‐ and inter‐annual time scales. Further, the climate indices are mainly correlated with precipitation at shorter periodicities, but correlated with spring discharge at longer scales. The difference reflects the modulation of karst aquifers on precipitation‐spring discharge during the processes of precipitation infiltration into the ground, and subsequent transformation into spring discharge. When teleconnection signals are transmitted into spring discharge via precipitation infiltration and groundwater propagation, some high‐frequency climatic signals are likely to be filtered, attenuated, and delayed, thus only low‐frequency climatic signals are preserved in spring discharge.     

Ozone Predictions in Atlanta,Georgia: Analysis of the 1999 Ozone Season

ABSTRACT

Ozone prediction has become an important activity in many U.S. ozone nonattainment areas. In this study, we describe the ozone prediction program in the Atlanta metropolitan area and analyze the performance of this program during the 1999 ozone-forecasting season. From May to September, a team of 10 air quality regulators, meteorologists, and atmospheric scientists made a daily prediction of the next-day maximum 8-hr average ozone concentration. The daily forecast was made aided by two linear regression models, a 3-dimensional air quality model, and the no-skill ozone persistence model. The team's performance is compared with the numerical models using several numerical indicators. Our analysis indicated that (1) the team correctly predicted next-day peak ozone concentrations 84% of the time, (2) the two linear regression models had a better performance than a 3-dimensional air quality model, (3) persistence was a strong predictor of ozone concentrations with a performance of 78%, and (4) about half of the team's wrong predictions could be prevented with improved meteorological predictions.     

Amendment of hydroxyapatite in reduction of tetrachloroethylene by zero-valent zinc: its rate enhancing effect and removal of Zn(II)

The effects of hydroxyapatite (HAP) on dechlorination of tetrachloroethylene (PCE) by zero-valent zinc (ZVZ) were examined in batch systems. PCE was primarily transformed to trichloroethylene by ZVZ, with 1,2-trans-dichloroethylene representing a minor product. Dechlorination of PCE was accelerated by the presence of HAP, and the pseudo-first order rate constants increased with increasing amount of HAP. Zn(II), mostly generated from oxidative dissolution of ZVZ by PCE, was effectively removed from the solution by HAP. Ion substitution, coprecipitation, and adsorption are proposed as the possible mechanisms for Zn(II) removal. These reactions appeared to occur simultaneously and the contribution of each reaction to overall removal of Zn(II) was primarily dependent on HAP loading at constant ZVZ loading. The results indicate that the use of HAP in combination with conventional zero-valent metals is promising in that it can achieve both degradation of organic contaminants and stabilization of inorganic contaminants.     

Computer and Electronics Product Stewardship: Are We Ready for the Challenge?

The PC revolution continues to produce faster and smarter machines at a stunning pace. Almost forgotten in the rush are the millions of nearly new, but suddenly outdated, computers that are abandoned every year. Can product stewardship offer life‐after‐end‐of‐life for this growing mountain of “attic‐ware,” while averting a costly—and potentially toxic—waste disposal crisis? © 2001 by Cate Gable, Axioun Books. Used with permission.     

A contingent valuation of the Mar Lodge Estate,Cairngorm Mountains,Scotland

The contingent valuation method is applied to the economic valuation of a significant environmental resource in the Scottish Highlands. Use and non‐use values are estimated. The results of such studies might be used to assist decision makers assess the case for public intervention to support the provision of environmental non‐market goods.     

Inhibition of erythrocyte delta-aminolevulinic acid dehydratase (ALAD) activity in fish from waters affected by lead smelters

We assessed the effects on fish of lead (Pb) released to streamsby smelters located in Trail, BC (Canada), E. Helena, MT, Herculaneum, MO, and Glover, MO. Fish were collected by electrofishing from sites located downstream of smelters and from reference sites. Blood from each fish was analyzed for -aminolevulinic acid dehydratase (ALAD) activity and hemoglobin (Hb), and samples of blood, liver, or carcass were analyzed for Pb, zinc (Zn), or both. Fish collected downstreamof all four smelters sites had elevated Pb concentrations, decreased ALAD activity, or both relative to their respectivereference sites. At E. Helena, fish from the downstream site also had lower Hb concentrations than fish from upstream. Differences among taxa were also apparent. Consistent with previous studies, ALAD activity in catostomids (Pisces: Catostomidae-northern hog sucker, Hypentelium nigricans;river carpsucker, Carpiodes carpio; largescale sucker, Catostomus macrocheilus; and mountain sucker, C. platyrhynchus) seemed more sensitive to Pb-induced ALAD inhibition than the salmonids (Pisces: Salmonidae-rainbow trout,Oncorhynchus mykiss; brook trout, Salvelinus fontinalis) or common carp (Cyprinus carpio). Some of these differences may have resulted from differential accumulation of Zn, which was not measured at all sites. We detected no ALAD activity in channel catfish (Ictaluruspunctatus) from either site on the Mississippi River at Herculaneum, MO. Our findings confirmed that Pb is releasedto aquatic ecosystems by smelters and accumulated by fish, andwe documented potentially adverse effects of Pb in fish. We recommend that Zn be measured along with Pb when ALAD activityis used as a biomarker and the collection of at least 10 fish ofa species at each site to facilitate statistical analysis.     

BAN waste, environmental justice and citizen participation in policy setting

It is widely acknowledged that the poorest sections of society bear a disproportionate burden of poor environmental quality, including toxicity and pollution. The struggles to address environmental injustice instigated at grassroots level also place the burden of righting the injustice on those who often have the least resources in terms of time, money and access to decision makers. The unfolding story of BAN Waste's sophisticated challenge to the proposed building of a replacement incinerator in a working-class area of Newcastle demonstrates many of the issues and stages common to struggles for environmental justice. The struggle became proactive and built wider alliances and a broad coalition across the city for change. The eventual success in preventing the incinerator being built and in producing a superior waste strategy counters the popular belief that environmental concerns are predominantly those of the middle class.     

A watershed management framework for mountain areas: Lessons from 25 years of watershed conservationin Nepal

A watershed management framework for mountain areas is based on lessons learned from watershed management experience, social and institutional learning, and the use of a watershed management program evaluation in Nepal. The lessons led to the adoption of a subwatershed-based ecosystem approach based on local participation at the subwatershed level. An integrated watershed management framework (IWMF) consisting of eight steps with three checklists was developed focusing on improvement-oriented adaptive management. The eight steps lead to the preparation of a watershed management plan. In the process three checklists are used. While the first checklist has general questions pertaining to watershed analysis, the second allows participation analysis of stakeholders in terms of their strengths, weaknesses, opportunities and threats and opens up new prospects for further reinforcing or building new user group institutions based on consensus. The final checklist consists of hierarchical watershed management objectives, including goals, results and activities leading to a program planning matrix. The framework was applied to watershed planning in the Chure Region to compare the framework-based planning with conventional planning procedures. A significant difference in quality and substance of the output, with and without the use of the framework, suggests that an integrated framework is a useful tool for an ecosystem-based approach to natural resource management and socio-technical conservation.