Variations in the Emissions of Volatile Organic Compounds from the Toner for a Specific Photocopier

ABSTRACT

A laboratory thermal desorption apparatus was used to measure emissions from a number of nominally identical photocopier toners—manufactured to meet the specifications of one specific model copier—when these toners were heated to fuser temperature (180-200 °C). The objective was to assess how potential volatile organic compound (VOC) emissions from the toner for a given copier can vary, depending upon the production run and the supplier. Tests were performed on a series of toner (and associated raw polymer feedstock) samples obtained directly from a toner manufacturer, representing two production runs using a nonvented extrusion process, and on toner cartridges purchased from two local retailers, representing three different production lots (histories unknown). The results showed that the retailer toners consistently had up to 350% higher emissions of some major compounds (expressed as |ig of compound emit-ted/g of toner), and up to 100% lower emissions of others, relative to the manufacturer toners (p ≤ 0.01). The manufacturer toners from one production run had emissions of certain compounds, and of total VOCs, that were modestly higher (13-18%) than those from the other run (p ≤ 0.01). The emission differences between the retailer and manufacturer toners are probably due to differences     

Validation of Three New Methods for Determination of Metal Emissions Using a Modified Environmental Protection Agency Method 301

Abstract

Three new methods applicable to the determination of hazardous metal concentrations in stationary source emissions were developed and evaluated for use in U.S. Environmental Protection Agency (EPA) compliance applications. Two of the three independent methods, a continuous emissions monitor-based method (Xact) and an X-ray-based filter method (XFM), are used to measure metal emissions. The third method involves a quantitative aerosol generator (QAG), which produces a reference aerosol used to evaluate the measurement methods. A modification of EPA Method 301 was used to validate the three methods for As, Cd, Cr, Pb, and Hg, representing three hazardous waste combustor Maximum Achievable Control Technology (MACT) metal categories (low volatile, semivolatile, and volatile). The modified procedure tested the methods using more stringent criteria than EPA Method 301; these criteria included accuracy, precision, and linearity. The aerosol generation method was evaluated in the laboratory by comparing actual with theoretical aerosol concentrations. The measurement methods were evaluated at a hazardous waste combustor (HWC) by comparing measured with reference aerosol concentrations. The QAG, Xact, and XFM met the modified Method 301 validation criteria. All three of the methods demonstrated precisions and accuracies on the order of 5%. In addition, correlation coefficients for each method were on the order of 0.99, confirming the methods’ linear response and high precision over a wide range of concentrations. The measurement methods should be applicable to emissions from a wide range of sources, and the reference aerosol generator should be applicable to additional analytes. EPA recently approved an alternative monitoring petition for an HWC at Eli Lilly’s Tippecanoe site in Lafayette, IN, in which the Xact is used for demonstrating compliance with the HWC MACT metal emissions (low volatile, semivolatile, and volatile). The QAG reference aerosol generator was approved as a method for providing a quantitative reference aerosol, which is required for certification and continuing quality assurance of the Xact.     

Fire Regimes and Tree Growth in Low Rainfall Jarrah Forest of South-west Australia

Regular fuel reduction burning is an important management strategy for reducing the scale and intensity of wildfires in south-west Australian native forests, but the long term effects of this on tree and stand growth are not well understood. Five fire treatments, including application of frequent and infrequent low intensity burns, and 25 years of fire exclusion, were applied to small (4 ha) experimental plots in a low rainfall mixed jarrah (Eucalyptus marginata) and marri (Corymbia calophylla) forest to investigate the effects of these treatments on tree stem diameter growth, stand basal area increment and tree mortality. Mean tree stem growth measured over 20 years was lowest in the long unburnt treatment compared with the burn treatments, although surface soil nutrient levels were generally higher in the unburnt treatment, suggesting these sites may be moisture limited. There was no clear pattern of the effects of the burn treatments, including the number of fires and the interval between fires, on tree stem growth, stand basal area increment, crown health or mortality. These factors were strongly influenced by dominance condition, with dominant and co-dominant trees growing most and suppressed trees growing least and experiencing the highest mortality levels. There was no evidence of deteriorating tree or stand health that could be attributed to either regular low intensity burning or to a long period (25 years) of fire exclusion.     

Ecologically Functional Floodplains: Connectivity,Flow Regime,and Scale1

Opperman, Jeffrey J., Ryan Luster, Bruce A. McKenney, Michael Roberts, and Amanda Wrona Meadows, 2010. Ecologically Functional Floodplains: Connectivity, Flow Regime, and Scale. Journal of the American Water Resources Association (JAWRA) 46(2):211-226. DOI: 10.1111/j.1752-1688.2010.00426.x Abstract: This paper proposes a conceptual model that captures key attributes of ecologically functional floodplains, encompassing three basic elements: (1) hydrologic connectivity between the river and the floodplain, (2) a variable hydrograph that reflects seasonal precipitation patterns and retains a range of both high and low flow events, and (3) sufficient spatial scale to encompass dynamic processes and for floodplain benefits to accrue to a meaningful level. Although floodplains support high levels of biodiversity and some of the most productive ecosystems on Earth, they are also among the most converted and threatened ecosystems and therefore have recently become the focus of conservation and restoration programs across the United States and globally. These efforts seek to conserve or restore complex, highly variable ecosystems and often must simultaneously address both land and water management. Thus, such efforts must overcome considerable scientific, technical, and socioeconomic challenges. In addition to proposing a scientific conceptual model, this paper also includes three case studies that illustrate methods for addressing these technical and socioeconomic challenges within projects that seek to promote ecologically functional floodplains through river-floodplain reconnection and/or restoration of key components of hydrological variability.     

Recovery of Sediment Characteristics in Moraine,Headwater Streams of Northern Minnesota After Forest Harvest1

Merten, Eric C., Nathaniel A. Hemstad, Randall K. Kolka, Raymond M. Newman, Elon S. Verry, and Bruce Vondracek, 2010. Recovery of Sediment Characteristics in Moraine, Headwater Streams of Northern Minnesota After Forest Harvest. Journal of the American Water Resources Association (JAWRA) 46(4): 733-743. DOI: 10.1111/j.1752-1688.2010.00445.x Abstract: We investigated the recovery of sediment characteristics in four moraine, headwater streams in north-central Minnesota after forest harvest. We examined changes in fine sediment levels from 1997 (preharvest) to 2007 (10 years postharvest) at study plots with upland clear felling and riparian thinning, using canopy cover, proportion of unstable banks, surficial fine substrates, residual pool depth, and streambed depth of refusal as response variables. Basin-scale year effects were significant (p < 0.001) for all responses when evaluated by repeated-measures ANOVAs. Throughout the study area, unstable banks increased for several years postharvest, coinciding with an increase in windthrow and fine sediment. Increased unstable banks may have been caused by forest harvest equipment, increased windthrow and exposure of rootwads, or increased discharge and bank scour. Fine sediment in the channels did not recover by summer 2007, even though canopy cover and unstable banks had returned to 1997 levels. After several storm events in fall 2007, 10 years after the initial sediment input, fine sediment was flushed from the channels and returned to 1997 levels. Although our study design did not discern the source of the initial sediment inputs (e.g., forest harvest, road crossings, other natural causes), we have shown that moraine, headwater streams can require an extended period (up to 10 years) and enabling event (e.g., high storm flows) to recover from large inputs of fine sediment.     

A Comparative Study of Particulate Loadings in Plumes Using Multiple Sampling Devices

Particle size distributions, particulate concentrations, and particle identities must be known to relate effluents to reduction in visibility and soiling. Similar types of emissions were measured with cascade impactor, membrane filter, and rotorod samplers. The different particle size distributions, concentrations, and identifications are reported. Discussion of and recommendations for utilization of these three methods of sampling are made.     

The Survival of Airborne Serratia marcescens in Urban Concentrations of Sulfur Dioxide

Aerosols of Serratia marcescens ATCC 274 were suspended in a 709L rotating drum at 20 ± 1 °C and high to mid-range relative humidities. At specified times after bacterial aerosolization, sulfur dioxide was added to concentrations of 2.5, or 5 mg/m³. Viable cell decay rate constants, in control aerosols without added sulfur dioxide, increased rapidly from near 100% to 60% RH in the first hour (termed: young aerosol) of suspension, and from a minimum rate constant at 80% in the succeeding four hours (termed: old aerosol).Upon addition of sulfur dioxide to a cloud of S. marcescens, generally, viable cell decay rate constants increased further. One exception was at 80% relative humidity where maximum resistance to SO₂ accelerated death was observed for old aerosols. Cells in young aerosols were particularly sensitive to SO₂ addition at mid-range humidities, while in older aerosols the cells were insensitive to up to 5 mg SO₂/m³ introduced at high RH; but were up to 10 times more sensitive than cells in young aerosols to a given increase (from 2.5 to 5 mg/m³) in SO₂ concentration at mid-range humidities.     

A Critical Review

The Critical Review Session on Atmospheric Dispersion Modeling was attended by nearly 400 people at the 72nd Annual Meeting of APCA at Cincinnati. D. Bruce Turner, whose paper appeared in the May 1979 Journal, summarized his findings. Prepared discussions which were presented by Dr. Egan, Dr. Spengler, and Mr. Mirabella are reproduced here with the floor discussion and a response by Mr. Turner. One of the important aspects of the Critical Review Program has always been the emphasis on this open discussion of the subject under review by peers of the author. Dr. Melvin W. First was Moderator of the Session.     

Growth of soybean at future tropospheric ozone concentrations decreases canopy evapotranspiration and soil water depletion

Tropospheric ozone is increasing in many agricultural regions resulting in decreased stomatal conductance and overall biomass of sensitive crop species. These physiological effects of ozone forecast changes in evapotranspiration and thus in the terrestrial hydrological cycle, particularly in intercontinental interiors. Soybean plots were fumigated with ozone to achieve concentrations above ambient levels over five growing seasons in open-air field conditions. Mean season increases in ozone concentrations ([O₃]) varied between growing seasons from 22 to 37% above background concentrations. The objective of this experiment was to examine the effects of future [O₃] on crop ecosystem energy fluxes and water use. Elevated [O₃] caused decreases in canopy evapotranspiration resulting in decreased water use by as much as 15% in high ozone years and decreased soil water removal. In addition, ozone treatment resulted in increased sensible heat flux in all years indicative of day-time increase in canopy temperature of up to 0.7 °C.