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641.
Solid-phase microextraction (SPME) was evaluated for the detection and quantification of the gas-phase carbonyls: citronellal, glyoxal, methylglyoxal, and beta-ionone. Prepared air samples containing the carbonyl compounds were collected at a flow rate of 2.8 L min(-1) in an impinger containing a 25% reagent water/75% methanol collection liquid. The aqueous samples were then derivatized with O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride (PFBHA), extracted with a PDMS/DVB coated SPME fiber, and analyzed by GC-MS. Detection limits with a sample air volume of 76 L were calculated to be 0.03 ppbv, 0.34 ppbv, 0.12 ppbv, and 0.28 ppbv for citronellal, glyoxal, methylglyoxal, and beta-ionone, respectively. 相似文献
642.
La Daana K. Kanhai Judith F. Gobin Denise M. Beckles Bruce Lauckner Azad Mohammed 《Environmental monitoring and assessment》2014,186(3):1961-1976
Metals can have significant impacts on inhabitants of mangrove swamps as well as consumers of mangrove-associated fauna. Yet, for several Caribbean islands, assessments regarding the impact of metals on such ecosystems are particularly sparse. The present study investigated the distribution and potential impact of Cd, Cr, Cu, Ni, Pb and Zn in the Caroni Swamp, Trinidad and Tobago’s largest mangrove ecosystem. Surface sediments and mangrove oysters (Crassostrea rhizophorae) from 10 sites in the swamp were analysed for the 6 identified metals. The concentration ranges (in μg/g dry wt.) of metals in sediments from Caroni Swamp were: Zn (113.4–264.6), Cr (27–69.7), Ni (10.7–41.1) and Cu (11–40.7). Based on Canadian Sediment Quality Guidelines (CSQGs), metals in sediments posed a low to medium risk to aquatic life. The concentration ranges (in μg/g wet wt.) for metals in Crassostrea rhizophorae tissues were: Zn (123.2–660), Cu (4.2–12.3), Ni (0.1–5.5), Pb (0.1–0.9), Cr (0.2–0.3) and Cd (0.1–0.2). Multiple evaluations indicated that zinc posed a potential threat to the health of oyster consumers. Information from this study is vital for managing the Caroni Swamp, safeguarding the health of consumers of shellfish on this Caribbean island and serving as a useful baseline for future local and regional risk assessments. 相似文献
643.
Thorsten Stahl Sandy Falk Alice Rohrbeck Sebastian Georgii Christin Herzog Alexander Wiegand Svenja Hotz Bruce Boschek Holger Zorn Hubertus Brunn 《Environmental Sciences Europe》2017,29(1):18
Background
Drinking bottles and stove-top moka pots made of aluminum have become very popular. Storing drinks in bottles and preparing coffee in a moka pot may result in the migration of aluminum to the beverage.Results/Conclusions
In a systematic study of aluminum drinking bottles, it has been shown that drinking a mixture of apple juice and mineral water in an aluminum bottle may reach 86.6% of the total weekly intake (TWI) for adults, and drinking tea from an aluminum bottle may exceed the TWI (145%) for a child weighing 15 kg. In contrast, preparing coffee in an aluminum moka pot results in a maximum of 4% to TWI, if an average of 3.17 L coffee is consumed per week, even if the pots are washed in the dishwasher, against the explicit instructions of the manufacturer.644.
Thorsten Stahl Sandy Falk Alice Rohrbeck Sebastian Georgii Christin Herzog Alexander Wiegand Svenja Hotz Bruce Boschek Holger Zorn Hubertus Brunn 《Environmental Sciences Europe》2017,29(1):19
Background
In spite of the prevalence of aluminum in nature, no organism has been found to date which requires this element for its biological functions. The possible health risks to human beings resulting from uptake of aluminum include detrimental effects to the hemopoietic system, the nervous system and bones. Aluminum is used in many fields and occurs in numerous foodstuffs. Food contact materials containing aluminum represent an anthropogenic source of dietary aluminum.Results
As a result of their frequent use in private households a study was undertaken to detect migration of this metal to foodstuffs from drink containers, coffee pots, grill pans, and camping cookware made of aluminum.Conclusions
An estimate of the health risk to consumers is calculated, based on the tolerable weekly intake (TWI) specified by the European Food Safety Authority of 1 mg/kg body weight for all groups of people. In some instances the TWI is significantly exceeded, dependent upon the food contact material and the food itself.645.
Proctor DM Suh M Aylward LL Kirman CR Harris MA Thompson CM Gürleyük H Gerads R Haws LC Hays SM 《Chemosphere》2012,89(5):487-493
Reduction of hexavalent chromium (Cr(VI)) to trivalent chromium (Cr(III)) in the stomach prior to absorption is a well-recognized detoxification process thought to limit the toxicity of ingested Cr(VI). However, administration of high concentrations of Cr(VI) in drinking water cause mouse small intestinal tumors, and quantitative measures of Cr(VI) reduction rate and capacity for rodent stomach contents are needed for interspecies extrapolation using physiologically-based toxicokinetic (PBTK) models. Ex vivo studies using stomach contents of rats and mice were conducted to quantify Cr(VI) reduction rate and capacity for loading rates (1-400 mg Cr(VI) L−1 stomach contents) in the range of recent bioassays. Cr(VI) reduction was measured with speciated isotope dilution mass spectrometry to quantify dynamic Cr(VI) and Cr(III) concentrations in stomach contents at select time points over 1 h. Cr(VI) reduction followed mixed second-order kinetics, dependent upon concentrations of both Cr(VI) and the native reducing agents. Approximately 16 mg Cr(VI)-equivalents of reducing capacity per L of fed stomach contents (containing gastric secretions, saliva, water and food) was found for both species. The second-order rate constants were 0.2 and 0.3 L mg−1 h−1 for mice and rats, respectively. These findings support that, at the doses that caused cancer in the mouse small intestine (?20 mg Cr(VI) L−1 in drinking water), the reducing capacity of stomach contents was likely exceeded. Thus, for extrapolation of target tissue dose in risk assessment, PBTK models are necessary to account for competing kinetic rates including second order capacity-limited reduction of Cr(VI) to Cr(III). 相似文献
646.
Modeling the Effects of Tile Drain Placement on the Hydrologic Function of Farmed Prairie Wetlands
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Brett Werner John Tracy W. Carter Johnson Richard A. Voldseth Glenn R. Guntenspergen Bruce Millett 《Journal of the American Water Resources Association》2016,52(6):1482-1492
The early 2000s saw large increases in agricultural tile drainage in the eastern Dakotas of North America. Agricultural practices that drain wetlands directly are sometimes limited by wetland protection programs. Little is known about the impacts of tile drainage beyond the delineated boundaries of wetlands in upland catchments that may be in agricultural production. A series of experiments were conducted using the well‐published model WETLANDSCAPE that revealed the potential for wetlands to have significantly shortened surface water inundation periods and lower mean depths when tile is placed in certain locations beyond the wetland boundary. Under the soil conditions found in agricultural areas of South Dakota in North America, wetland hydroperiod was found to be more sensitive to the depth that drain tile is installed relative to the bottom of the wetland basin than to distance‐based setbacks. Because tile drainage can change the hydrologic conditions of wetlands, even when deployed in upland catchments, tile drainage plans should be evaluated more closely for the potential impacts they might have on the ecological services that these wetlands currently provide. Future research should investigate further how drainage impacts are affected by climate variability and change. 相似文献
647.
Julio L. Rivera Bruce Seely John W. Sutherland 《Environment, Development and Sustainability》2012,14(5):807-825
Nanotechnology-infused products have begun to enter the market in spite of the fact that many sectors of society are still debating whether or not exposure to such products will result in detrimental side effects. Due to a lack of regulation of nanoproducts, it is difficult to track these products to assess how they interact with humans and the environment. Acknowledging this limitation, several studies are starting to investigate situations where individuals are exposed to nanoparticles in the workplace; it is to be noted that manufacturing of materials is the first stage in the product life cycle where exposure may occur. This paper reviews and discusses the potential societal implications associated with the manufacturing of nanoparticles: health concerns, workers’ perceptions, rights, ethics, and the role of policy and regulation. Scenarios are presented, possible implications are discussed, and recommendations are given for appropriate action. Finding the right solution to the identified implications represents a critical challenge. In summary, it is imperative that all stakeholders including industry, academia, government entities, and the public adopt a proactive attitude to ensure that nanotechnology matures in a sustainable manner. 相似文献
648.
Towards metrics of sustainable food systems: a review of the resilience and vulnerability literature
Paolo Prosperi Thomas Allen Bruce Cogill Martine Padilla Iuri Peri 《The Environmentalist》2016,36(1):3-19
Food and nutrition security is a persisting global issue and, in addition, food systems are now facing a new set of intersecting economic, social and environmental challenges. Recurrent socio-economic and biophysical changes put the sustainability of food systems at risk. There is an urgent need to develop knowledge-based tools to assess and monitor food sustainability and to identify pathways for food security and resource conservation. The systemic nature of these interactions calls for multidimensional approaches and integrated assessments for decision-making to guide change. This paper reviews social–ecological system frameworks with the view to conceptualize the sustainability issues that affect the food systems. It is argued that the understanding of the food systems as social–ecological systems, and inputs from the theories of vulnerability and resilience in particular, can provide the concepts necessary to understand and model the complex system dynamics involved in the multiple interactions between human and natural components. 相似文献
649.
John W. Spence Philip L. Hanst Bruce W. Gay Jr. 《Journal of the Air & Waste Management Association (1995)》2013,63(10):994-996
Chlorinated atmospheric pollutants are presently receiving much attention because of expected chlorine-ozone interactions in the stratosphere.1,2 The fully halogenated pollutants,such as CCI3F, CCl2F2, and CCl4, have no known removal processes that operate in the troposphere. These compounds are accumulating on a global scale, their atmospheric mixing ratios having reached about 2 X 10-10 for CCl2F2,1.2 X 10-10 for CCl3F, and 9 X 10-11 for CCl4.3-5 相似文献
650.
Bruce A. Boomer Thomas P. Dux Daniel J. March 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1426-1432
Many organizations and their consultants are involved in sampling programs to characterize waste streams and materials at industrial facilities. Due to financial limitations, calendar deadlines, or other practical restrictions, a short-term, survey-type sampling plan (“sampling survey”) may need to he implemented. Survey results can he used to determine if the wastes are hazardous or if they are being managed in accordance with applicable regulations. This paper brings together practical experience and diverse information to identify the major concerns in conducting sampling surveys and to suggest methods of approaching these concerns. The paper addresses sampling in time and space, “correct” sampling to minimize bias, selecting equipment to minimize contamination, sample handling, and quality assurance/quality control. Even a quick sampling survey can be a high quality effort with a careful approach to the critical issues. 相似文献