Molecular-level investigation of monoaromatic compound sorption to suspended soil particles by deuterium nuclear magnetic resonance

Molecular-level sorption behavior of monoaromatic compounds in suspensions of water-dispersable clay components was studied by measuring 2H nuclear magnetic resonance (NMR) spin-spin relaxation times (T2). In general, decreased T2 values indicate stronger solute-sorbent interactions and increased sorption of the solute. A decreasing trend for T2 values in the order benzene > fluorobenzene > toluene (-C6D5 moiety) was observed, which was probably caused by the hydrophobic effect. The T2 values for benzene and the -C6D5 moiety of toluene increased with increasing pH, whereas the trend with pH was much weaker and less consistent for fluorobenzene and the methyl group of toluene. Conversely, no clear relationship was found between T2 values and pH for dichloromethane. These contrasting results cannot be explained by the pH-dependent self-assembly and hydrophobicity of humics. Instead, directed specific forces, including hydrogen bonding, cation-pi interactions, and aromatic-aromatic interactions, are proposed between the benzene ring of monoaromatic solutes and soil organic matter (SOM). Substituents of benzene affect these interactions by varying the pi electron density. When the soil fraction was treated with NaOH to remove humic and fulvic acids, T2 values for the different monoaromatic solutes were surprisingly lower compared with those for the untreated soil fraction. This result is probably caused by the increased ratio of solutes adsorbed to "hard" or "glassy" SOM components, which leads to less mobile sorbed solute molecules, after removing NaOH-extractable humics that contain more "soft" or "rubbery" SOM components.     

Indicators Assessment for Habitat Conservation Plan of Yolo County, California, USA

/ Whereas habitat conservation plans (HCPs) have been intended to provide comprehensive environmental mitigation for multiple species, they often narrow in focus to one species and either one mitigation site or unspecified sites. We developed an indicators framework from which to rate land units for their ecological integrity, collateral values (nonbiological qualities that can improve conservation), and restoration and conservation opportunities. The ratings of land units were guided by the tenets of conservation biology and principles of landscape and ecosystem ecology, and they were made using existing physical and floral information managed on a GIS. As an example of how the indicators approach can be used for HCPs, the 29 legally rare species targeted by the Yolo County HCP were each associated with vegetation complexes and agricultural crops, the maps of which were used for rating some of the landscape indices. The ratings were mapped so that mitigation can be directed to the places on the landscape where the legally rare species should benefit most from conservation practices. The most highly rated land units for conservation opportunity occurred along streams and sloughs, especially where they emerged from the foothills and entered the Central Valley and where the two largest creeks intersected the Sacramento River flood basin. We recommend that priority be given to mitigation or conservation at the most highly rated land units. The indices were easy to measure and can be used with other tools to monitor the mitigation success. The indicators framework can be applied to other large-area planning efforts with some modifications.KEY WORDS: Ecosystem; Indicators; Landscape; Mitigation; Planning; Yolo County; California     

Timing of hurricane emergency actions

Emergency actions to prepare for hurricanes often require more time than is available from official public warnings. This means that the preparedness official must decide not onlywhat to do butwhen to do it. The action decision system, described here, developed for use in the State of Florida, reformats the hurricane track forecast, a 72-h projection, prepared at the National Hurricane Center in Miami, to specify the probability of a strike at each of 12 vulnerable coastal communities, and then normalizes the value in terms of a composite of probabilities computed for historic hurricanes that struck the respective communities. The normalization, a ratio of the two probability values, current and historic, expressed as a percentage is defined as the level of risk. When this level reaches or exceeds 100% the risk level is defined as critical and the system recommends that emergency actions to prepare begin immediately.The system is founded upon individual hurricane climatologies and decision procedures that are tailored for use at each community. The action recommendations generated by the risk analyses with a 93% level of confidence relieve the preparedness official of the need to make meteorological decisions in timing evacuations and other critical measures, even when these must begin before official hurricane warnings are received.The work that provided the basis for this publication was supported by funding under a Cooperative Agreement with the Federal Emergency Management Agency. The substance and findings of the work are dedicated to the public. The authors are solely responsible for the accuracy of the statements and interpretations contained in the publication. Such interpretations do not necessarily reflect the views of the government.     

WATERSHED PLANNING FOR ACID MINE DRAINAGE ABATEMENT1

Acid drainage from abandoned mines is a widespread problem in old mining regions. Agencies seeking to abate it face the prospect of dealing with hundreds of potential abatement projects, stretching decades into the future. A systematic regional analysis is necessary to establish locations, objectives, priorities, and phasing of such projects. The U.S. Bureau of Mines developed a novel procedure for abatement planning in the 420 square mile Blacklick Creek Watershed in Pennsylvania. The plan sought to direct abatement projects toward pollution sources where degradation was worst and adverse effects greatest. It established abatement priorities by comparing the “supply” of sources to be reclaimed (the degrees of old mines' water quality degradation) with the “demand” for abatement to be done (the natural and cultural values represented by the region's demography, land use and other non-mining characteristics). Matrices were used to define the relationships among mining and non-mining factors; maps were developed to show the geographic distribution of the conclusions. The locations, priorities, and phasing of abatement objectives shown on the maps should provide guidance for any abatement effort, no matter what type of technology is applied to achieve the objectives. Over the many years in which abatement projects are to be performed in the Watershed, the plan can be used to define, coordinate, and establish priorities for the projects in a manner that can result in maximum abatement benefits from the application of limited funds.     

WATER CONSERVATION METHODS IN URBAN LANDSCAPE IRRIGATION: AN EXPLORATORY OVERVIEW1

ABSTRACT: The increasing use of irrigation for urban landscapes is causing new demands for efficient watering systems. Conservation techniques for irrigated agricultural fields cannot be applied to urban landscapes without amendment. This paper attempts to review methods of urban landscape water conservation in the context of the diversity and complexity of urban landscapes and the demands upon them for quality of the urban environment. A development's initial site layout and planting design fundamentally determine how much irrigation water will be required; the complexity and creativity inherent in urban design open a number of specific possibilities for reducing water demand. Irrigation hardware is then designed to deliver the required volume of water to the specified landscape efficiently by implementing a number of physical and operational principles. Maintenance of the finished development involves monitoring results and making adjustments as the plantings grow and develop. The potential for conserving urban irrigation water is large. Effective conservation need not compromise other qualities of the urban environment such as aesthetics, screening, or shade. Urban design can address both the kinds of landscapes people need, and minimal consumption of irrigation water.     

SUSPENDED SEDIMENT AND TURBIDITY FOLLOWING ROAD CONSTRUCTION AND LOGGING IN WESTERN MONTANA1

ABSTRACT: Forest management activities in a second order drainage basin increased suspended sediment yields 7.7 fold in the first year following road construction, and two-fold following logging in the second year. Sediment supply limitations resulted in poor correlations between sediment concentrations with discharge. Sediment transport was strongly hysteretic, with the highest sediment concentrations occurring on the rising limbs of snowmelt hydrographs and individual peaks. In addition to discharge, hydrograph characteristics such as limb, dQ/dt, and the product of dQ/dt and limb aided in explaining variability of observed sediment concentrations. Sediment-turbidity relationships were strongly discharge dependent, reflecting the changing composition of the suspended load with stream power and sediment supplies.     

NEW HAMPSHIRE WATER SYSTEMS: ENVIRONMENTAL AND OWNERSHIP CONSIDERATIONS1

An econometric model was developed to measure the influence of several environmentally oriented variables and an ownership variable upon the average total residential water costs for New Hampshire water systems. The implementation of leak detection programs, localized institutional rules and regulations, and hazardous waste inspection programs were statistically significant in influencing residential water costs. The existence of a water conservation program did not statistically influence these per unit costs. Water systems that were privately owned resulted in per unit costs that were higher relative to firms that were publicly owned.     

Comparison of field-observed and model-predicted plume trends at fuel-contaminated sites: implications for natural attenuation rates

Subsequent to modeling of natural attenuation processes to predict contaminant trends and plume dynamics, monitoring data were used to evaluate the effectiveness of natural attenuation at reducing contaminant concentrations in groundwater at seven fuel-contaminated sites. Predicted and observed contaminant trends at seven sites were compared in order to empirically assess the accuracy of some fundamental model input parameters and assumptions. Most of the models developed for the study sites tended to overestimate plume migration distance, source persistence, and/or the time required for the benzene, toluene, ethyl benzene, and xylenes (BTEX) plumes to attenuate. Discrepancies between observed and predicted contaminant trends and plume behavior suggested that the influence of natural attenuation process may not have been accurately simulated. The conservatism of model simulations may be attributed to underestimation of natural source weathering rates, overestimation of the mass of contaminant present in the source area, and/or use of overly conservative first-order solute decay rates.