EFFECT OF FILTRATION PRESSURE ON ANALYSES FOR CHLOROPHYLL1

ABSTRACT: Nine samples, each with different kinds and numbers of algae, were filtered at five pressures from 5 to 75 pounds per square inch and the amounts of chlorophylls a and b were measured. Pressures in the range tested had no effect on the measured amounts.     

DEVELOPMENT AND EVALUATION OF A DIMENSIONLESS UNIT HYDROGRAPH1

ABSTRACT: A generalized unit hydrograph method is developed and evaluated for ungaged watersheds. A key component in this method is the value of a dimensionless storage coefficient. Procedures to estimate this coefficient are given using calibrated values from 142 rainfall-runoff events gaged in watershed located mainly in the Eastern US. Only limited success was obtained in predicting this storage coefficient. Thirty-seven, independent rainfall-runoff events were used to test the proposed technique. The generalized unit hydrograph predicted the observed runoff hydrographs fairly well with considerable improvement in accuracy over the SCS dimensionless unit hydrograph. Approximately one-half of test storms had percent errors in predicted peak flow rates that were less than 34 percent compared to percent error of 88 percent with the SCS method.     

DEVELOPING AND ASSESSING A MODEL OF RESIDENTIAL WATER CONSERVATION1

ABSTRACT: Relevant literature was reviewed from which a model of residential water conservation was developed. Four residential conservation program interventions were posited: 1) public education, 2) pricing variables, 3) water use restrictions, and 4) building code requirements. Four exogenous variables affecting residential water use were also posited: 1) temperature, 2) rainfall, 3) household income, and 4) household size. The impacts of these eight variables on residential per capita daily use were assessed by cross sectional and time series analysis. Study results generally supported the porposed model, with less consistent support obtained for pricing variables and conservation beliefs. The paper concludes with the hypothesis that an inclining block rate structure coupled with an informational program designed to inform consumers of their consumption under each block will have a synergistic impact.     

Potential for reducing indoor styrene exposure from copied paper through use of low-emitting toners

Tests were conducted using 53-L dynamic chambers to determine airborne styrene emission rates over time from freshly copied paper. Copies were produced on a single photocopier using two toners manufactured for this copier but having different styrene contents. The resulting emission models were used to predict whether indoor styrene concentrations resulting from copied paper in a typical office might be significantly reduced by use of a low-emitting toner for a given copier. The styrene emissions were best represented by either a 3rd-order decay model or by a power law model having an exponent between 0.3 and 0.5 (R2 = 0.94-0.99). The two toners resulted in copied paper having significantly different styrene emissions (p < 0.01), with unit mass emissions over 1000 hr being nine times greater with the higher-emitting toner. But copied paper is predicted to produce peak indoor styrene concentrations in a typical office no more than 1% of the World Health Organization health-based guideline. Thus, for the toners considered here, indoor styrene exposures from copied paper appear to be too limited to provide incentive for switching to the lower-emitting toner. The ability to generalize these conclusions is limited by the fact that only one copier and two toners could be tested.     

Yard waste compost as a stormwater protection treatment for construction sites.

Runoff water quality improvement from three yard waste compost erosion control treatments were compared with two conventional treatments and an untreated control on plots of 3:1 slope during two growing seasons, using natural events and simulated rainfall. Runoff volume, suspended solids, nutrients, biomass, turf shear strength, and turfgrass color scale were monitored. The most effective compost treatment, a 5-cm thick blown compost blanket, produced 12.7 times less runoff and 9.8 times less sediment load than a straw mat and silt fence treatment. The compost treatments generated eight times more biomass than the straw mat treatments. Root development was significantly better on the compost treatments based on turf shear strength measurements. Tilled-in compost was not as effective as a compost blanket at reducing sediment loss, particularly before the establishment of grass on the plot. The cost of compost treatments was similar to that of straw mat with silt fence treatments.     

Assessment of municipal waste compost as a daily cover material for odour control at landfill sites

The ability of municipal waste compost as a daily cover material to reduce the odorous emissions associated with landfill surfaces was investigated. Trials were carried out using landfill gas, a certified sulphurous gas mix and ambient air as a control. Odorous gas was passed through portable test column filled with compost at different densities (590 kg/m3 and 740 kg/m3). Gas samples were taken from the inlet, outlet and at varying column depths and examined using a combination of sensory analysis (olfactometry) and a novel analytical method (Transportable Selected Ion Flow Tube--TSIFT). Results for the trials using landfill gas showed a 69% odour reduction (OU/m3) through the column for compost with a bulk density of 590 kg/m3, and a reduction of 97% using compost with a bulk density of 740 kg/m3. TSIFT analysis showed an overall decrease in the concentration of terpenes, and sulphurous compounds in the outlet gas from the column for both bulk densities. No significant trend could be identified for the concentrations at different depths within the column. Results show the ability of compost to reduce landfill odours under differing conditions. The inconclusive data provided by TSIFT analysis may be due to the analysis of compounds that are not contributing to odour, and thus highlights the potential for synergetic effects and the importance of sensory measurement when examining odorous emissions.     

Analysis of a summertime PM2.5 and haze episode in the mid-Atlantic region

Observations of the mass and chemical composition of particles less than 2.5 microm in aerodynamic diameter (PM2.5), light extinction, and meteorology in the urban Baltimore-Washington corridor during July 1999 and July 2000 are presented and analyzed to study summertime haze formation in the mid-Atlantic region. The mass fraction of ammoniated sulfate (SO4(2-)) and carbonaceous material in PM2.5 were each approximately 50% for cleaner air (PM2.5< 10 microg/m3) but changed to approximately 60% and approximately 20%, respectively, for more polluted air (PM2.5>30 microg/m3). This signifies the role of SO4(2-) in haze formation. Comparisons of data from this study with the Interagency Monitoring of Protected Visual Environments network suggest that SO4(2-) is more regional than carbonaceous material and originates in part from upwind source regions. The light extinction coefficient is well correlated to PM2.5 mass plus water associated with inorganic salt, leading to a mass extinction efficiency of 7.6 +/- 1.7 m2/g for hydrated aerosol. The most serious haze episode occurring between July 15 and 19, 1999, was characterized by westerly transport and recirculation slowing removal of pollutants. At the peak of this episode, 1-hr PM2.5 concentration reached approximately 45 microg/m3, visual range dropped to approximately 5 km, and aerosol water likely contributed to approximately 40% of the light extinction coefficient.     

Estimation of octanol/water partition coefficients for organic pollutants using reverse-phase HPLC

Octanol/water partition coefficients (K_ow's) of organic solutes are estimated with reasonable accuracy (standard deviation ± 0.25 log K_ow units) by elution from a C-18 column with 75:25 (v/v) MeOH-H₂O, based on results with 37 test compounds. Changes in solute activity coefficients from water to 75% MeOH account for the slope of the log K_ow-log k' plot, where k' is the HPLC capacity factor. The method is used to estimate K_ow's for 25 additional organic compounds, and some disparities between the results and those calculated using group additivity-constitutive factors are noted.     

Effects of Slash Pine Silviculture on a Florida Population of Flatwoods Salamander

The largest known breeding migration of the flatwoods salamander ( Ambystoma cingulatum ) was monitored over a 22-year period following its discovery in 1970 in Liberty County, Florida (U.S.A.). Nightly migrations of 200–300 adults across a 4.3-km stretch of paved highway in 1970–1972 had dwindled to less than one individual per night in 1990–1992; the decline apparently was already underway in the 1980s. We discuss possible natural and anthropogenic causes of the decline. The silvicultural practice of converting native longleaf pine savanna to bedded slash pine plantation, implemented on our study site about 1968, may have interfered with migration, successful hatching, larval life, feeding, and finding suitable cover post-metamorphosis. Longleaf pine-wiregrass flatwoods inhabited by adults have been drastically reduced and severely degraded throughout the coastal plain and may explain why the species is rare and deserving of threatened status.     

Production of electricity from proteins using a microbial fuel cell.

Electricity generation was examined from proteins and a protein-rich wastewater using a single chamber microbial fuel cell (MFC). The maximum power densities achieved were 354 +/- 10 mW/m2 using bovine serum albumin (BSA) and 269 +/- 14 mW/m2 using peptone (1100 mg/L BSA and 300 mg/L peptone). The recovery of organic matter as electricity, defined as the Coulombic efficiency (CE), was comparable to that obtained with other substrates with CE = 20.6% for BSA and CE = 6.0% for peptone. A meat packing wastewater (MPW), diluted to 1420 mg/L chemical oxygen demand, produced 80 +/- 1 mW/m2, and power was increased by 33% by adding salt (300 mg/L sodium chloride) to increase solution conductivity. A wastewater inoculum generated 33% less power than the MPW inoculum. The MFC was an effective method of wastewater treatment, demonstrated by >86% of biochemical oxygen demand and total organic carbon removal from wastewater.