高级氧化技术机理及在水处理中的应用进展

综述了近年来发展迅速的高级氧化技术，主要包括Fenton法、臭氧氧化法、湿式氧化技术、超临界水氧化法、纳米光催化氧化法电化学催化降解法及超声降解法等。介绍了各种高级氧化技术的基本原理及在废水处理中的应用进展，并对其特点进行了评述。     

Synthesis and structure-activity relationship of diene modified analogs of<Emphasis Type="Italic"> Matsucoccus</Emphasis> sex pheromones

The biological activity of the Matsucoccus spp. sex pheromones and diene modified analogs has been tested in forests of Israel and Portugal in order to explore the structure-activity relationship of the pine bast scale pheromone/kairomone system. The response of the adult predatory bugs, Elatophilus hebraicus and E. crassicornis and of the brown lacewing, Hemerobius stigma is more selective than that of the conspecific Matsucoccus males. The removal of the terminal methyl group from the diene terminus of both pheromones 1 and 2 eliminates all kairomonal activity but retains moderate pheromonal activity. Addition of a methyl group to the diene terminus of pheromones 1 and 2 sustains full pheromonal and kairomonal activities of the Elatophilus spp. but eliminates entirely the kairomonal activity of H. stigma. Subtle designed alterations in the structure of the diene group, typical of all Matsucoccus pheromones, change the mode of the kairomonal activity markedly.     

狭窄海湾潮交换的分段模式Ⅰ.模式的建立

Ｋｕｏ 和 Ｎｅｉｌｓｏｎ 的分区段潮交换模式基于 Ｋｅｔｃｈｕｍ 潮冲程理论划分区段，并以各断面的回流系数来反映区段间的交换特征，是一个适合于狭长小潮湾沿程水交换近似估算的简捷有效的模式。本研究对该模式中的混合过程物理简化方式作了更为合理的修正，即引进了“内湾各相邻区段间水体混合交换同时发生”的设定。同时，基于对交换率概念的系统分析，本文还对模式中最重要的特征参数回流系数的特性及其简化确定方法作了进一步探讨     

对多氯联苯的全球分馏加以量化

由于有广泛的理化特性,多氯联苯(PCBs)在全球分馏假设求导中担任着重要角色,这种假设预测持久性有机污染混合物的组成随纬度产生变化.最新的历史排放估计、内部一致的特性数据集和按气候带平均的全球命运和运输模型结合在一起允许把PCBs所经历的成分转移作为环境区划、纬度和时间的一个函数的定量调查.模型模拟复制出纬度越高在大气和土壤中所观察到的较轻PCB同类物的相对丰度就越高,并量化了分割、持久性和排放在建立PCB格局过程中的相对重要性.组成变化不仅与倒转的浓度剖面一致(北极区浓度高于低纬度区)也与全球分馏一致,但只与向北转移的全球PCB存量的较小部分一致.     

Triploid fetus: An important consideration in the evaluation of very high maternal serum alpha-fetoprotein

Two patients referred for evaluation of very high maternal serum alpha-fetoprotein (10–20 multiples of the median) were carrying triploid fetuses with placentas showing features of partial hydatidiform mole. The diagnosis of fetal triploidy should be considered when there is a very high maternal serum alpha-fetoprotein and no ultrasound evidence of open neural tube defect, ventral wall defect, or any other explanation. Therefore, chromosomal analysis of amniotic fluid cells in such cases is essential.