水系沉积物重金属分析前处理方法

建立了水系沉积物中6种重金属分析的前处理方法,研究了样品粒径、消解前处理对测定结果的影响,对方法适用性作出评价,并对实际样品进行测定。结果表明:通过Hg元素含量的测定,粒径为0.147 mm的沉积物粒径可满足分析要求;采用微波-硝酸-盐酸-氢氟酸消解、ICP-MS法,对5种不同类型沉积物标准样品的6种重金属的测定结果显示,该方法精密度好、准确度高。利用建立的方法测定广西某河流湖库沉积物样品,6种元素测定结果 RSD为1.57%~11.1%,加标回收率大于74.4%。     

环境标准样品在国家地表水采测分离工作中的应用

按照《国家地表水环境质量监测网监测任务作业指导书(试行)》中实验室分析测试的质量保证和质量控制要求,结合江苏省南京环境监测中心的实际工作,综合分析2017年10月—2018年8月间国家地表水采测分离工作中环境标准样品在样品测试准确度验证、检测人员能力确认、检测设备期间核查及关键化学试剂检查等方面的应用情况。为保障环境监测结果量值溯源的统一性、准确性、一致性和可比性,提出丰富水环境标准样品的浓度水平、解决标准样品供需不平衡问题、改善消耗量大的标准样品操作方法、建立环境标准样品使用信息共享平台等实践建议,为合理提升环境标准样品应用效能、有效保证水环境监测数据质量提供参考。     

高温后砂岩抗拉强度及应变场演化实验研究

为研究高温后砂岩的抗拉力学特性及变形破坏规律,对不同温度作用后的砂岩进行巴西劈裂实验,同时采用数字散斑相关方法对砂岩变形破坏进行监测。研究表明:高温作用后砂岩质量损失率增加,波速整体呈降低趋势,砂岩物理特性出现一定劣化;高温作用使砂岩抗拉强度呈先增加后减小的趋势,25~400℃增大了16.08%,400~1 000℃减小了69.30%,砂岩表现为脆性破坏特征;砂岩劈裂过程中,水平应变场演化过程为:局部小变形产生、扩展→小变形区域聚集、合并、连接→应变局部化带产生→应变局部化带扩展并贯穿→宏观劈裂破坏;随着温度升高,应变局部化启动水平先增加后降低,400℃为转折点。该研究方法可为煤矿火灾安全等领域提供借鉴。     

Spatial and temporal variation of soil organic carbon in the North China Plain

The organic carbon, permeability test, grain size, chemical composition, and mineral composition were analyzed for 147 samples collected from the Luan River catchment, Hebei province, China, to quantitatively characterize the effects of land use, climate change, sedimentary environment, mineral composition, and chemical composition on the spatial and temporal variation of soil organic carbon (SOC). The results indicate that there was higher SOC content and stronger variation in the south plain than in the northern low mountain. The effects of land use, climate change, and sedimentary environment on SOC distribution were greater than the effects of mineral composition and chemical composition. The cropping systems in the Luan River catchment resulted in significant difference in SOC concentration between the south plain and north mountain. The precipitation mainly transmitted its effects through the sedimentary environment to SOC, which caused the stronger temporal variation in SOC from June to October in the south plain. The north mountain did not have significant temporal variation because of the lower hydraulic conductivity of the sedimentary sequence. The spatial variation of SOC was correlated with land use, and their temporal variation was attributed to climate change and sedimentary environment. Apart from land use, the decision maker can also affect the organic carbon mineral and sequence through the sedimentary environment.     

农户认知、外部环境与绿色农业生产意愿——基于湖北省632个农户调研数据

以湖北省632个农户调研数据为实证,在考虑绿色农业生产外部环境的情况下,结合农户对绿色农业生产的认知和农户特征因素,利用logistic回归探析农户绿色农业生产意愿的影响因素。结果表明:（1）农业收入占家庭总收入比重、绿色技术的经济效益和了解程度、农村环境污染现状、政府补贴都对农户绿色农业生产意愿具有正向影响;（2）农户年龄、绿色技术采用风险和政府管制则会减弱农户的绿色生产意愿。因此在推进农业生产绿色化转型的过程中,应加强职业农民培育和绿色农业生产技术的宣传培训,确保绿色技术的适用可靠性。同时政府应加强完善农业绿色生产制度,通过激励政策替代管制和惩罚机制,引导和规范农户绿色农业生产行为     

城市建设用地扩张的区域差异及其驱动因素

中国城市建设用地规模随着工业化、城镇化的不断发展而日益剧增。受经济、社会等诸多驱动因素影响,各地建设用地扩张在时间维度、空间维度都存在明显的区域差异,对上述问题进行全面考察,有助于理清建设用地扩张的机理,促进土地集约、节约利用。将城市建设用地扩张的影响因素分为政府推动和市场拉动两个方面,采用基尼系数及基于半对数回归方程的Shapley值分解方法,考察了2006—2015年中国大陆31个省(市、自治区)城市建设用地扩张的区域差异及其驱动因素的贡献程度。结果表明:(1)2006—2015年,中国城市建设用地扩张的区域差异比较明显,衡量差异程度的基尼系数先升后降,最后稳定于0.3左右;(2)财政赤字率、经济政策执行力、经济增长、人口城镇化等因素对建设用地扩张具有正向驱动作用,产业结构调整、建设用地利用效率等因素对建设用地扩张具有负向驱动作用;(3)经济增长、财政赤字率、经济政策执行力等三个因素对建设用地扩张区域差异的贡献最大;(4)影响我国东、中、西三个区域建设用地扩张的主导因素不尽相同。为此,应从促进区域经济平衡发展、拓宽政府融资渠道、加快产业结构调整、提高建设用地利用效率等多方面入手,破解城市建设用地过度扩张的困局。     

Polyoxometalates for photocatalytic degradation of aqueous dyestuff solutions and quantitative structure–property relationship study on photolysis rate constants

Polyoxometalate, K₆TiW₁₁O₃₉Sn·7H₂O (TiW₁₁Sn), was synthesized and characterized. TiW₁₁Sn and K₆ZrW₁₁O₃₉Sn·12H₂O (ZrW₁₁Sn) were evaluated for their photocatalytic degradation of triarylmethane (brilliant green and acid blue 9), bisazo (C.I. reactive black 5), and monoazo dyestuffs (C.I. reactive red 24, C.I. reactive red 194, and C.I. reactive orange 5) with natural sunlight in homogeneous aqueous solutions. TiW₁₁Sn and ZrW₁₁Sn effectively and photocatalytically decolorized the dyestuffs. The TiW₁₁Sn- and ZrW₁₁Sn-mediated photocatalytic degradation of the dyestuffs involved a pseudo-first-order reaction and was modeled by Langmuir–Hinshelwood-type kinetics. The observed pseudo-first-order rate constants (K^/) of triarylmethane dyestuffs were generally bigger than that of the azo dyestuffs. Quantitative structure–property relationship models of the K^/ of the dyestuffs were developed using partial least-square regression. The cumulative variance of the dependent variable explained by the partial least-square components was > 0.753 for each optimal model. This value indicated that the model had good predictive ability and robustness. The K^/ values of the dyestuffs were related to the energy of the lowest unoccupied molecular orbital, and the most positive net atomic charges on a sulfur atom of dyestuffs. The linear correlation coefficients between the predicted and experimental values were all > 0.9950.     

环渤海高铁沿线可达性及其空间格局演变研究

以环渤海高铁沿线城市为对象,研究高铁通车前后的可达性状况及其空间分异格局,预测未来沿线空间格局的演变态势,结果表明:(1)环渤海高铁的开通大大提升了沿线的可达性,时空收敛效应显著,呈以高铁轴带为核心、轴带外围为边缘的"核心-边缘"格局,高铁轴带内部呈现线路"中间高、首末低"的分异特征,可达性最优要素由京、津向环渤海高铁线路两侧扩散;(2)环渤海高铁沿线城市可达性的提升加速沿线地区空间格局的演变和重塑,表现在环渤海高铁"C"形轴带空间极化程度的进一步加深;沿线的辽中南、京津冀、山东半岛三大城市群一体化进程显现,产生1+1+1＞3的组合效应;环渤海港口群对接铁路线,空间分化与组合日趋复杂;响应"一带一路"倡议,强化与中蒙俄经济走廊战略通道的融合.     

NF和RO对致突变物和无机离子去除效果比较

以自来水为原水,采用反渗透和纳渗进行深度处理试验研究,比较了２种膜对致突变物和无机离子的去除率。结果表明,ＲＯ和ＮＦ均能使Ａｍｅｓ试验呈阳性的水转变为阴性;ＮＦ对一价阳离子（Ｋ＾＋、Ｎａ＾＋）的去除率比ＲＯ低１０％左右,对二价阳离子（Ｃａ＾２＋、Ｍｇ＾２＋）的去除率略低于ＲＯ,ＮＦ比ＲＯ能多保留一些离子。     

强化我国引进环境保护技术宏观调控的探讨

１０年来,我国引进环境保护技术近万项,总金额近千亿元。如何充分发挥引进环境保护技术的作用,推动我国环境科学技术的进步,必须对我国引进环境保护技术进行宏观调控,本文对建立和完善我国引进环境保护技术运行机制等进行了探讨。