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991.
992.
上海燃煤电厂大气汞排放初探 总被引:2,自引:0,他引:2
燃煤电厂是主要的人为汞排放源之一,也是上海城市范围内最大的大气汞排放点源。耗煤量、煤汞含量、燃烧装置的结构以及空气污染控制装置的协同除汞能力是影响燃煤电厂大气汞排放的主要因素。文章利用历年的统计数据和美国环境保护局的经验值筛选出汞排放的影响因子,粗略估算了上海燃煤电厂的大气汞年排放量,从空气污染控制装置的协同除汞效果.改进颗粒物控制装置、提高烟气脱硫系统的汞捕集能力、投加粉末状活性碳的除汞效果等方面,分析了空气污染控制装置的除汞效果及其改进方法。 相似文献
993.
火炬气回收及排放系统的优化 总被引:1,自引:0,他引:1
阐述了洛阳石化总厂火炬气排放及回收系统的优化改造措施,评价了在降低生产成本及环境保护等方面的效果。 相似文献
994.
IntroductionTheBashangregionissituatedateastlongitude113°50′-118°00′andnorthlatitude40°58′-42°42′,withanareaof17371km2fromZhangjiakouofnorthernHebeitothenorthofChengde.TheregionliesinthemiddlesectionofatransitionzonefromagriculturaltopastoralregionsofnorthernChina… 相似文献
995.
中国主要土壤对钴的吸附特征 总被引:1,自引:2,他引:1
对我国几种土类对钴吸附的研究表明,在平衡钴浓度不很高的条件下,土壤对钴的等温吸附表现为直线型,吸附量有明显的从南到北增加的趋势.通过修正竞争吸附方程对pH-钴吸附量曲线的描述,揭示出影响我国土壤对钴吸附容量的主要因素是粘土矿物类型,其次为土壤有机质及粘粒含量;随着土壤中铁锰氧化物的增加;其吸附强度增加.可变电荷高的土壤对钴吸附受pH的影响非常明显.永久电荷为主的土壤则不然.低的土壤pH可抑制铁锰氧化物对钴的强烈吸附. 相似文献
996.
997.
This study investigates the mechanism of photosensitization and the recombination of excited electron–hole pairs affected by depositing platinum (Pt) on the surface of titanium dioxide (TiO2). A new catalyst of Pt–TiO2 was prepared by a photoreduction process. Being model reactions, the photocatalytic oxidation of methylene blue (MB) and methyl orange (MO) in aqueous solutions using the Pt–TiO2 catalyst was carried out under either UV or visible light irradiation. The experimental results indicate that an optimal content of 0.75%Pt–TiO2 achieves the best photocatalytic performance of MB and MO degradation and that the Pt–TiO2 catalyst can be sensitized by visible light. The interaction of Pt and TiO2 was investigated by means of UV–Vis absorption spectra, photoluminescence emission spectra, and X-ray photoelectron emission spectroscopy. The Pt0, Pt2+ and Pt4+ species existing on the surface of Pt–TiO2, and the Ti3+ species existing in its lattice may form a defect energy level. The Pt impurities, including Pt, Pt(OH)2, and PtO2, and the defect energy level absorb visible light more efficiently in comparison with the pure TiO2 and hinder the recombination rate of excited electron–hole pairs. 相似文献
998.
Henschel DB Fortmann RC Roache NF Liu X 《Journal of the Air & Waste Management Association (1995)》2001,51(5):708-717
A laboratory thermal desorption apparatus was used to measure emissions from a number of nominally identical photocopier toners--manufactured to meet the specifications of one specific model copier--when these toners were heated to fuser temperature (180-200 degrees C). The objective was to assess how potential volatile organic compound (VOC) emissions from the toner for a given copier can vary, depending upon the production run and the supplier. Tests were performed on a series of toner (and associated raw polymer feedstock) samples obtained directly from a toner manufacturer, representing two production runs using a nonvented extrusion process, and on toner cartridges purchased from two local retailers, representing three different production lots (histories unknown). The results showed that the retailer toners consistently had up to 350% higher emissions of some major compounds (expressed as microgram of compound emitted/g of toner), and up to 100% lower emissions of others, relative to the manufacturer toners (p < or = 0.01). The manufacturer toners from one production run had emissions of certain compounds, and of total VOCs, that were modestly higher (13-18%) than those from the other run (p < or = 0.01). The emission differences between the retailer and manufacturer toners are probably due to differences in the manufacturing processes and/or feedstocks used to produce the toners from these different sources. 相似文献
999.
Trickle-bed air biofilters (TBABs) are suitable for treating volatile organic compounds (VOCs) at a significantly high practical loading because of their controlled environmental conditions. The application of TBAB for treating styrene-contaminated air under periodic backwashing and cyclical nonuse periods at a styrene loading of 0.64-3.17 kg chemical oxygen demand (COD)/m3 x day was the main focus of this study. Consistent long-term efficient performance of TBAB strongly depended on biomass control. A periodic in situ upflow with nutrient solution under media fluidization, that is, backwashing, was approached in this study. Two different nonuse periods were employed to simulate a shutdown for equipment repair or during weekends and holidays. The first is a starvation period without styrene loading, and the second is a stagnant period, which reflects no flow passing through the biofilter. For styrene loadings up to 1.9 kg COD/m3 x day, removal efficiencies consistently above 99% were achieved by conducting a coordinated biomass control strategy, that is, backwashing for 1 hr once per week. Under cyclical nonuse periods for styrene loadings up to 1.27 kg COD/m3 x day, stable long-term performance of the biofilter was maintained at more than 99% removal without employing backwashing. No substantial impact of nonuse periods on the biofilter performance was revealed. However, a coordinated biomass control by backwashing subsequently was unavoidable for attaining consistently high removal efficiency at a styrene loading of 3.17 kg COD/m3 x day. As styrene loading was increased, reacclimation of the biofilter to reach the 99% removal efficiency following backwashing or the nonuse periods was delayed. After the non-use periods, the response of the biofilter was a strong function of the biomass in the bed. No significant difference between the effects of the two different nonuse periods on TBAB performance was observed during the study period. 相似文献
1000.
Role of amination of a polymeric adsorbent on phenol adsorption from aqueous solution 总被引:7,自引:0,他引:7
Adsorption of seven phenols, one aromatic carboxylic acid and one sulfonated aromatic acid from aqueous solution, by a hypercrosslinked polymeric adsorbent (CHA-111) and the derivative animated by dimethylamine was compared. The results of different adsorption isotherms indicated that amino group on the polymeric matrix played a significant role on adsorption of almost all the employed compounds. For most employed compounds adsorption capacities increase to different degree and significantly for those with lower value of pK(a). It may be attributed to the enhanced adsorbent-adsorbate interaction for amino group introduced on the polymeric matrix. The empirical Freundlich isotherm equation was employed to interpret the adsorbent-adsorbate interaction. The adsorption enthalpy change indicated the uptake of phenols on MCH-111 to be an enhanced physical adsorption because of the hydrogen-bonding interaction. Adsorption kinetic study of phenols on CHA-111 and MCH-111 was also conducted and amino group on the matrix will reduce the adsorption rate for change of pore size distribution and loss of macroprous volume as well as the hydration effect on the surface partly. 相似文献