Assessment of the overall resource consumption of germanium wafer production for high concentration photovoltaics

The overall resource requirements for the production of germanium wafers for III–V multi-junction solar cells applied in concentrator photovoltaics have been assessed based on up to date process information. By employing the cumulative energy demand (CED) method and the cumulative exergy extraction from the natural environment (CEENE) method the following resources have been included in the assessment: fossil resources, nuclear resources, renewable resources, land resources, atmospheric resources, metal resources, mineral resources and water resources. The CED has been determined as 216 MJ and the CEENE has been determined as 258 MJ_ex. In addition partial energy and exergy payback times have been calculated for the base case, which entails the installation of the high concentration photovoltaics (HCPVs) in the Southwestern USA, resulting in payback times of around 4 days for the germanium wafer production. Due to applying concentration technology the germanium wafer accounts for only 3% of the overall resource consumption of an HCPV system. A scenario analysis on the electricity input to the wafer production and on the country of installation of the HCPV has been performed, showing the importance of these factors on the cumulative resource consumption of the wafer production and the partial payback times.     

Nitrate-nitrogen losses through subsurface drainage under various agricultural land covers

Nitrate-nitrogen (NO?-N) loading to surface water bodies from subsurface drainage is an environmental concern in the midwestern United States. The objective of this study was to investigate the effect of various land covers on NO?-N loss through subsurface drainage. Land-cover treatments included (i) conventional corn ( L.) (C) and soybean [ (L.) Merr.] (S); (ii) winter rye ( L.) cover crop before corn (rC) and before soybean (rS); (iii) kura clover ( M. Bieb.) as a living mulch for corn (kC); and (iv) perennial forage of orchardgrass ( L.) mixed with clovers (PF). In spring, total N uptake by aboveground biomass of rye in rC, rye in rS, kura clover in kC, and grasses in PF were 14.2, 31.8, 87.0, and 46.3 kg N ha, respectively. Effect of land covers on subsurface drainage was not significant. The NO?-N loss was significantly lower for kC and PF than C and S treatments (p < 0.05); rye cover crop did not reduce NO?-N loss, but NO?-N concentration was significantly reduced in rC during March to June and in rS during July to November (p < 0.05). Moreover, the increase of soil NO?-N from early to late spring in rS was significantly lower than the S treatment (p < 0.05). This study suggests that kC and PF are effective in reducing NO?-N loss, but these systems could lead to concerns relative to grain yield loss and change in farming practices. Management strategies for kC need further study to achieve reasonable corn yield. The effectiveness of rye cover crop on NO-N loss reduction needs further investigation under conditions of different N rates, wider weather patterns, and fall tillage.     

Fertilizer management effects on nitrate leaching and indirect nitrous oxide emissions in irrigated potato production

Potato ( L.) is a N-intensive crop, with high potential for nitrate (NO) leaching, which can contribute to both water contamination and indirect nitrous oxide (NO) emissions. Two approaches that have been considered for reducing N losses include conventional split application (CSA) of soluble fertilizers and single application of polymer-coated urea (PCU). The objectives of this study were to: (i) compare NO leaching using CSA and two PCUs (PCU-1 and PCU-2), which differed in their polymer formulations, and (ii) use measured NO leaching rates and published emissions factors to estimate indirect NO emissions. Averaged over three growing seasons (2007-2009), NO leaching rates were not significantly different among the three fertilizer treatments. Using previously reported direct NO emissions data from the same experiment, total direct plus indirect growing season NO emissions with PCU-1 were estimated to be 30 to 40% less than with CSA. However, PCU-1 also resulted in greater residual soil N after harvest in 2007 and greater soil-water NO in the spring following the 2008 growing season. These results provide evidence that single PCU applications for irrigated potato production do not increase growing season NO leaching compared with multiple split applications of soluble fertilizers, but have the potential to increase N losses after the growing season and into the following year. Estimates of indirect NO emissions ranged from 0.8 to 64% of direct emissions, depending on what value was assumed for the emission factor describing off-site conversion of NO to NO. Thus, our results also demonstrate how more robust models are needed to account for off-site conversion of NO to NO, since current emission factor models have an enormous degree of uncertainty.     

Assessment of basin-scale hydrologic impacts of CO2 sequestration,Illinois basin

Idealized, basin-scale sharp-interface models of CO₂ injection were constructed for the Illinois basin. Porosity and permeability were decreased with depth within the Mount Simon Formation. Eau Claire confining unit porosity and permeability were kept fixed. We used 726 injection wells located near 42 power plants to deliver 80 million metric tons of CO₂/year. After 100 years of continuous injection, deviatoric fluid pressures varied between 5.6 and 18 MPa across central and southern part of the Illinois basin. Maximum deviatoric pressure reached about 50% of lithostatic levels to the south. The pressure disturbance (>0.03 MPa) propagated 10–25 km away from the injection wells resulting in significant well–well pressure interference. These findings are consistent with single-phase analytical solutions of injection. The radial footprint of the CO₂ plume at each well was only 0.5–2 km after 100 years of injection. Net lateral brine displacement was insignificant due to increasing radial distance from injection well and leakage across the Eau Claire confining unit. On geologic time scales CO₂ would migrate northward at a rate of about 6 m/1000 years. Because of paleo-seismic events in this region (M5.5–M7.5), care should be taken to avoid high pore pressures in the southern Illinois basin.     

自然保护区、恢复力和动态景观

在这个日益被人类活动所改变的世界里,保护生物多样性对于维持有恢复力的生态系统和确保生态系统产品的可持续流动以及对社会的服务是至关重要的.但是,现有的自然保护区和国家公园不大可能结合生态系统的长期和大尺度的动态.因此,保护策略必须包括大面积的人类利用经营的土地.为了能使生态系统在大规模的自然和人为干扰之后得以重组,以生态存储形式出现的空间恢复力是必备的前提.生态存储包括那些能使生态系统得以重组的物种、相互作用和结构,它的组成部分可能出现在干扰斑块中,也可能出现在周围的景观中.现有的静态自然保护区应该由动态自然保护区加以补充,例如生态休闲地和动态演替保护区,这些都是在景观尺度上模拟自然干扰状况,进行生态系统经营的组成部分.     

The Shallow‐Water Component of the Chesapeake Bay Environmental Model Package

The shallow‐water component of the Chesapeake Bay Environmental Model Package emphasizes the regions of the system inside the 2‐m depth contour. The model of these regions is unified with the system‐wide model but places emphasis on locally significant components and processes, notably submerged aquatic vegetation (SAV), sediment resuspension, and their interaction with light attenuation (Ke). The SAV model is found to be most suited for computing the equilibrium distribution of perennial species. Addition of plant structure and propagation are recommended to improve representation of observed trends in SAV area. Two approaches are taken to examining shallow‐water Ke. The first compares observed and computed differences between deep‐ and shallow‐water Ke. No consistent difference in observations is noted. In the preponderance of regions examined, computed shallow‐water Ke exceeds computed deep‐water Ke. The second approach directly compares Ke measured in shallow water with modeled results. Model values are primarily lower than observed, in contrast to results in deep water where model values exceed observed. The shortfall in computed Ke mirrors a similar shortfall in computed suspended solids. Improved model representation of Ke requires process‐based investigations into suspended solids dynamics as well as increased model resolution in shallow‐water regions.     

Understanding the total life cycle cost implications of reusing structural steel

Reuse of structural steel could be an environmentally superior alternative to the current practice, which is to recycle the majority (88%) of scrap steel. In spite of the potential benefits, and in a time when “sustainability” and “climate change” are critical societal issues, the question arises: why are greater rates of structural steel reuse not being observed? One of the major factors in the rate of structural steel reuse is how decision-makers understand the life cycle implications of their choice to recycle steel rather than reuse it. This paper contributes towards our understanding of these implications, particularly the cost implications, of reuse as an alternative to recycling by presenting a streamlined life cycle analysis and identifying the major contributors to each process. The results of a case study indicate that a significant reduction in some life cycle impact metrics (greenhouse gas emissions, water use) can result from reusing structural steel rather than recycling it. The largest contributors to the life cycle impact of recycling were the shredding, melting, and forming sub-processes. The largest contributor to reuse was the deconstruction sub-process. A total life cycle cost analysis is performed to understand the cost of damages to the environment and human health in combination with the cost of construction activities. Sensitivity and uncertainty analyses are also conducted to quantify variability in the results and determine economic conditions where the two processes have an equal cost.