Capital and Operating Costs of Selected Air Pollution Control Systems — I

This is the first installment of a 4-part series which will present capital and operating costs of selected air pollution control systems. The objective of the Series is to identify the individual component costs so that realistic system cost estimates can be determined for any specific application. In Part I, cost estimating procedures and curves are provided to develop the equipment costs for electrostatic pre-cipitators, venturi scrubbers, fabric filters, incinerators, and adsorbers.     

Data requirements of GREAT-ER: Modelling and validation using LAS in four UK catchments

Higher-tier environmental risk assessments on “down-the-drain” chemicals in river networks can be conducted using models such as GREAT-ER (Geography-referenced Regional Exposure Assessment Tool for European Rivers). It is important these models are evaluated and their sensitivities to input variables understood. This study had two primary objectives: evaluate GREAT-ER model performance, comparing simulated modelled predictions for LAS (linear alkylbenzene sulphonate) with measured concentrations, for four rivers in the UK, and investigate model sensitivity to input variables. We demonstrate that the GREAT-ER model is very sensitive to variability in river discharges. However it is insensitive to the form of distributions used to describe chemical usage and removal rate in sewage treatment plants (STPs). It is concluded that more effort should be directed towards improving empirical estimates of effluent load and reducing uncertainty associated with usage and removal rates in STPs. Simulations could be improved by incorporating the effect of river depth on dissipation rates.     

Organophosphorus insecticide residues in farm ditches of the Lower Fraser Valley of British Columbia

Abstract

Farm ditches flowing into three important rivers in the Lower Fraser Valley of British Columbia, Canada, were sampled periodically at seven locations from July to December in 1991, to determine the occurrence and levels of seven organophosphorus (OP) insecticides. Based oh sales records for the year, the uses of OP insecticides in this area were as follows: malathion > diazinon > parathion > dimethoate > azinphos‐methyl > fensulfothion, but no sales of chlorfenvinphos. Residues of parathion, diazinon, fensulfothion, dimethoate and chlorfenvinphos were detected at levels ranging from 1 ‐ 7,785 >μg/kg in cropped soils collected from areas adjacent to the sites for sampling ditch water and sediments. Malathion and azinphos‐methyl were not detected in any of the substrates studied, demonstrating their rapid degradation in the environment. Diazinon and dimethoate were consistently found in ditch water at seven locations, with an average concentration of 0.07 μg/L and 0.27 μg/L, respectively. Fensulfothion and parathion, with an average concentration of 0.08 μg/L and 0.17 μg/L, respectively, were sporadically found in ditch water at two locations. In ditch sediments, diazinon was detected at three locations and fensulfothion at two. The average concentrations of these two insecticides were 16 μg/kg and 9 jug/kg, respectively. The potential impact on aquatic organisms of these OP insecticides in ditches is discussed.     

Capital and Operating Costs of Selected Air Pollution Control Systems—V

Several methods are available for estimating the capital costs of systems and each has its own degree of accuracy. These methods range from presenting overall installed costs on a per unit basis, to detailed cost estimates based on preliminary designs, schematics, and contractor quotes. The least accurate method is the equating of overall capital costs to a basic operating parameter such as tons per hour or cfm since this method only produces accuracies in the "order of magnitude" category, at best. The detailed cost estimate, in turn, can produce accuracies of ±5 % depending on the amount of preliminary engineering involved. These estimates, however, take many months of engineering effort and require process and engineering flow sheets, material and energy balances, plot plans, and equipment arrangement drawings before a cost estimate can be developed. For first-cut estimating purposes, the technique described in this article for developing capital costs for a specific pollution control system is based on the factored method of establishing direct and indirect installations costs as a function of known equipment costs. The cost factors developed are based on both quoted and estimated installation costs of pollution control systems. The annual operating costs for these systems are based on unit costs for utilities and operating and maintenance labor together with fixed percentages of capital costs for the indirect costs.     

ASsessment Of Alcohol Ethoxylate Surfactants And Fatty Alcohols Mixtures In River Sediments And Prospective Risk Assessment

A feasible and relatively readily available analytical method was adapted for the assessment of alcohol ethoxylates (AE) and fatty alcohols (FA) in sediments. This study illustrates the simultaneous measurement of 38 of 114 possible alcohol ethoxylate ethoxymers (AE) and fatty alcohols (FA) found in commercially important AE products. We predicted toxicity for all identified fractions, as well as the total mixture toxicity, relative to three exposure scenarios via sewage treatment plants (STP) for these widely used chemicals in consumer products and hence generate a preliminary environmental risk screening for AE and FA in sediments. The method is based on derivatization of solvent or solid-phase extracts with 2-fluoro-N-methylpyridinium p-toluenesulfonate (Pyr+). The derivatized extracts were analyzed with liquid chromatography/mass spectrometry (LC/MS) operating in the positive ion electrospray mode. The extraction efficiency of AE and FA in three different sediments of varying composition was evaluated with spike-recovery studies, ranging from 64% to 80%. The detection limits for individual ethoxymers typically ranged from 1 to 5ngg⁻¹on a dry weight basis. The mean limit of detection (LOD) was 6ngg⁻¹and the median LOD was 3ngg⁻¹. AE and FA in sediments were found to be stable for two weeks if preserved with 3% (v/v) formalin and stored at 4–6^∘C. Based on equilibrium partitioning, background concentrations of AE and FA were predicted to be below concentrations known to elicit chronically toxic effects. Total worst case mixture toxicities for all AE ethoxymers combined with FA were predicted to result in a risk quotient less than 0.6. Activated sludge treatment (STP) significantly reduced the release of total AE and FA by four-fold, suggesting that the total mixture risk quotient would be < 0.15 for sediment dependent organisms.     

Charging versus exclusion: Choice between recreation management tools

Overuse of recreation sites seems to justify regulation, and the principal tools for this are fee charging or physical exclusion. Both seem equally costly to administer. Both involve equal costs to consumers if recreationists visit from one origin, but if they come from different origins, costs may be greater and consumers' surplus less under either tool, depending on the shape of the demand curve. Which is the more equitable tool depends on the relative representation of rich and poor participants from near and distant origins. Potentially beneficial use of site revenues is an advantage of charging. Neither availability of substitutes nor variation in daily demand seems likely to change these results substantially, but a system of booking admissions before the trip outset might neutralize the advantages of charging. The optimal level of use varies with the regulatory tool chosen. The optimal admissions under exclusion could be fewer than or more than under charging, or may even be equal to unregulated use.     

Evaluating Quality of Life, Economic Vulnerabilities, and Drivers of Ecosystem Change

We examined regional conditions and trends related to quality of life and potential vulnerabilities of these factors to changes in the condition of natural resources in the Mid-Atlantic Region, USA. We selected a variety of variables on economic and socio-demographic conditions that demonstrate links between the condition of natural areas and human concerns and that quantify dependencies on resources. We extracted data from economic and population census databases for counties within the study area and present a subset of results of the cluster analyses used to describe condition and potential risks due to distinct combinations of variables. We found that the same variables used to judge quality of life were often correlated with increasing population and thus were likely to be related to land pressures and risks to natural resources. Within the region, economic dependence on resource-harvesting industries such as forestry and fisheries was low (less than 4% of total earnings at most), however, the potential for natural amenities to attract residents appeared to be growing as the self-employed and otherwise mobile people settled in areas with affordable housing and natural amenities. Suburban residential spread had been occurring in both the close-in and distant suburbs of the region's urban areas and some rural, growth appeared to be driven, in part, by businesses migrating to suburbs. Further work is needed to tease apart causal factors for the trends we observed, but correlations clearly existed in some areas between increasing populations and quality of natural surroundings.     

Iodine in terrestrial wildlife on the U.S. department of energy's Hanford Site in southcentral Washington

Iodine-129 in controlled amounts has been released into the air from the operating chemical separations facilities on the Hanford Site. Small amounts of ¹²⁹I have accumulated in surface soils especially at locations near the chemical separations facilities. Enriched levels of ¹²⁹I also occur in the thyroid glands of mule deer (Odocoileus hemionus) residing on the Hanford Site.Stable iodine is present in low concentrations in Hanford Site soils and it is not avidly accumulated by wild plants. Soils at high elevations have greater concentrations of ¹²⁷I than low elevations soils. Mule deer thyroids had higher concentrations of stable iodine than the thyroids of black-tailed jackrabbits. Stable iodine in black-tailed jackrabbit thyroids varied with the season with maximal concentrations in summer.Iodine-131 has not been released into the air from operating chemical separations facilities for more than 10 yr. Because of its short half-life ¹³¹I of Hanford Site origin has disappeared from the Hanford Site. In the event of a future restart of the chemical separations facilities black-tailed jackrabbits can be used as biological indicators of ¹³¹I in the terrestrial environment of the Hanford Site.