Hydrogen peroxide-assisted UV photodegradation of Lindane

Aqueous solutions of gamma-hexachlorocyclohexane (Lindane) were photolyzed (lambda=254 nm) under a variety of solution conditions. The initial concentrations of hydrogen peroxide (H(2)O(2)) and Lindane varied from 0 to 20 mM and 0.21 to 0.22 microM, respectively, the pH ranged from 3 to 11, and several concentration ratios of Suwannee River humic acid and fulvic acid were dissolved in the irradiated solutions. Lindane rapidly reacted, and the maximum reaction rate constant (9.7 x 10(-3) s(-1)) was observed at pH 7 and initial [H(2)O(2)]=1 mM. Thus, 90% of the Lindane is destroyed in approximately 4 min under these conditions. In addition, within 15 min, all chlorine atoms were converted to chloride ion, indicating that chlorinated organic by-products do not accumulate. The reactor was characterized by measuring the photon flux (7.04 x 10(-6) E s(-1)) and the cumulative production of *OH during irradiation. The cumulative *OH production during irradiation was fastest at an initial [H(2)O(2)]=5 mM (k=0.77 micro M s(-1)).     

Assessment of the TRMM 3B42 Precipitation Product in Southern Brazil

The increase in the use of satellite‐derived precipitation products generated by different methods and algorithms emphasizes the need for a deeper analysis of their quality and accuracy. Using the contingency table method, we evaluated the accuracy of versions 6 and 7 of the Tropical Rainfall Measuring Mission Precipitation (TRMM) 3B42 product in southern Brazil by comparing daily precipitation over 13 years (V6 was tested for historical context). The interpolated data from 25 rain gauges were compared with both versions of TRMM. The V7 product tended to produce a slight increase in PC (proportion correct). V7 also showed a slight increase in the correlation coefficient (CC) and a significant increase in the H (hit rate) and CSI (critical success) indexes. However, the upgraded version shows an undesirable increase in the false alarm ratio. When the rainfall volumes were compared, V6 clearly underestimated the total rainfall over the entire period, but the V7 product slightly overestimated the cumulative volume (11%) which still represented a more reliable estimate than from V6. Furthermore, the main improvement in V7 was a large increase in the quantitative recognition of extreme precipitation events: V6 detected only 1% of the daily rainfalls above 60 mm, whereas V7 detected 57% of the events.     

Effects of γ-Fe2O3 nanoparticles on the survival and reproduction of Biomphalaria glabrata (Say, 1818) and their elimination from this benthic aquatic snail

Environmental Science and Pollution Research - This study aims to evaluate the effects of maghemite nanoparticles (γ-Fe2O3) coated with meso-2, 3-dimercaptosuccinic acid (DMSA) stabilizer on...     

A review of the main methods for composite adsorbents characterization

Environmental Science and Pollution Research - Adsorption is a promising technology for removing several contaminants from aqueous matrices. In the last years, researchers worldwide have been...