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101.
Incineration of acrylic waste solution in a lab scale quartz tube vertical incinerator showed the presence of 12–15 polycyclic
aromatic hydrocarbons (PAHs) from a list of 16 priority pollutants at 700–1100˚C after an interval of 50˚C. The amount of total 16 PAHs at 900 and 1100˚C was about 8.5 and 1.25 times higher than those at 700˚C (739.48 μg g−1) respectively. The amount of total probable (2A) and possible (2B) human carcinogenic PAHs was minimum at 700˚C. 相似文献
102.
Amal Chandra Das Hemanta Nayek Arunabha Chakravarty 《Environmental monitoring and assessment》2012,184(12):7453-7459
An experiment was conducted under laboratory conditions to investigate the effect of two systemic herbicides, viz. pendimethalin (a dinitroaniline) and quizalofop (an arylphenoxy propionic acid) at their recommended field application rates (1.0?kg and 50?g active ingredient per hectare, respectively), either separately or in a combination, on growth and activities of phosphate-solubilizing microorganisms in relation to their effects on biochemical transformations and availability of organic carbon, total and available phosphorus in a Typic Haplustept soil of West Bengal, India. Application of herbicides, in general, significantly stimulated the growth and activities of phosphate-solubilizing microorganisms which increased microbial biomass resulting in higher accumulation of oxidizable organic carbon, total and available phosphorus in soil as compared to untreated control. The combined application of both the herbicides highly stimulated the proliferations of phosphate-solubilizing microorganisms, while pendimethalin alone significantly accentuated phosphate-solubilizing capacities 36.4% as compared to untreated control and retained highest amount of total phosphorus due to greater microbial activities in soil. The separate application of quizalofop also manifested an induced effect on the proliferations of phosphate-solubilizing microorganisms and accounted significant amounts of organic carbon and available phosphorus in the soil system. The results of the present study thus indicated that the cited herbicides at their field application rates can be safely used to eradicate weeds in the crop fields. 相似文献
103.
A multivariate time series approach vector autoregression (VAR) along with impulse response function and variance decomposition
technique has been employed to look into the interrelationship among O3, NO, NO2, and volatile organic compounds (VOCs, namely, benzene, ethylbenzene, toluene, and xylene in the present study) using 3 months
long continuous time series data of 1 h average concentration of these pollutants at one of the traffic sites in Delhi, India.
It is found that the VAR of order 2 (i.e., past two lagged values of 1 h interval) is sufficient to represent the observed
time series at the station studied. The impulse response function and variance decomposition analysis indicate that O3 concentration shows an immediate rise and persists for a longer duration (typically 8–10 h) once the impulse of NO2, benzene, ethylbenzene, or xylene is given in the ambient environment. However, in case of toluene, the reverse effect has
been observed. Since O3 forms in the troposphere due to photolysis of NO2, it is not surprising that its impulse triggers O3 formation in the ambient environment. However, in case of VOCs, this has been attributed to their tendency to show higher
inclination toward intermediary reactions leading to the formation of O3 rather than their (VOCs) reaction with O3. Among VOCs, only toluene has been observed to show higher inclination toward its reaction with O3. Apart from this, variance decomposition technique also reveals that the relation of NO with NO2 is more important than the relation of NO with O3 creating a conducive atmosphere for O3 formation in the present scenario. Thus, the multivariate time series approach provides significant insight about the role
played by the dominant individual VOCs and NO
x
in influencing the O3 concentration in ambient urban atmosphere whereas a photochemical modeling approach gives an overall view of NO
x
and VOCs behavior with respect to O3 by using the O3 isopleth technique. 相似文献
104.
Deepak Singh Amit Prakash A. K. Srivastava Krishan Kumar V. K. Jain 《Environmental monitoring and assessment》2013,185(2):1873-1882
The acoustic environment in urban areas has gained prominence in recent times due to rapid industrial and commercial development in metropolitan cities. Various attempts have been made to predict and model the trends in urban ambient noise levels using different statistical and dynamic models. The present study makes an attempt to examine the role of meteorological parameters affecting the ambient noise levels in Delhi. The results show significant improvement in overall noise scenario of Delhi since the introduction of compressed natural gas vehicles in public transport of Delhi. The noise level is significantly reduced by high vegetation cover as well as by low relative humidity over Delhi. The regression models developed for the present study clearly show the significant contribution of meteorological parameters in governing the ambient noise levels in Delhi. 相似文献
105.
Chow JC Watson JG Lowenthal DH Park K Doraiswamy P Bowers K Bode R 《Environmental monitoring and assessment》2008,144(1-3):179-189
PM(2.5) nitrate [Formula: see text] and sulfate ([Formula: see text]) were measured continuously with R&P8400N and R&P8400S instruments, respectively, and compared with filter-based measurements at the Fresno Supersite from October, 2000 through December, 2005. [Formula: see text] concentrations were higher in winter than summer with a long-term decreasing trend. Correlations between 24-h average continuous and filter-based [Formula: see text] were greater than 0.96 in 4 out of 5 years. Continuous [Formula: see text] was generally lower than filter-based [Formula: see text] although the difference decreased over time, from -52% in 2001 to +13% in 2005. These differences were similar in winter (-23%) and summer (-19%) while the corresponding differences between ambient and instrument temperature were -12 and 0.7 degrees C, respectively. Neither seasonal nor long-term trends in [Formula: see text] can be explained by variations in ambient temperature, the difference between ambient and instrument temperature, or changes in aerosol chemical composition. There were no seasonal or long-term trends in [Formula: see text] concentrations, partially due to low concentrations observed in Fresno. Long-term variability in the performance of R&P8400 [Formula: see text] and [Formula: see text] instruments suggest that collocation with filter measurements is needed for long-term measurements. 相似文献
106.
The monthly maximum of the 24-h average time-series data of ambient air quality-sulphur dioxide (SO(2)), nitrogen dioxide (NO(2)) and suspended particulate matter (SPM) concentration monitored at the six National Ambient Air Quality Monitoring (NAAQM) stations in Delhi, was analysed using Box-Jenkins modelling approach (Box et al. 1994). Univariate linear stochastic models were developed to examine the degree of prediction possible for situations where only the past record of pollutant data are available. In all, 18 models were developed, three for each station for each of the respective pollutant. The model evaluation statistics suggest that considerably satisfactory real-time forecasts of pollution concentrations can be generated using the Box-Jenkins approach. The developed models can be used to provide short-term, real-time forecasts of extreme air pollution concentrations for the Air Quality Control Region (AQCR) of Delhi City, India. 相似文献
107.
108.
Sumit Sharma Navin Chandra Kothiyal 《Environmental science and pollution research international》2013,20(12):8986-8995
In this study, a natural adsorbent (activated dry flowers (ADF)) was prepared from plant-derived waste biomass by chemical activation and employed for chromium (VI) removal from aqueous medium using experimental batch technique. Experiments were carried out as function of adsorbent dosage, pH, and contact time. The maximum chromium (Vl) removal was observed at initial pH 3 (~94 % removal). The equilibrium data was fitted well to Langmuir isotherm. The adsorption capacity of ADF was found to be 4.40 (mg chromium (Vl)/g) which was comparable to the adsorption capacity of some other adsorbents documented. Among various kinetic models applied, pseudo second-order model was found to explain the kinetics of chromium (VI) adsorption most effectively (R 2 >0.99). Thermodynamic parameters such as ΔG, ΔS, and ΔH shows that adsorption process was spontaneous and endothermic at all the concentration ranges studied. Desorption of chromium (Vl) with 2 N NaOH was effective (~71 %) and, hence, there exists the possibility of recycling the ADF. The major advantages of using ADF as an adsorbent are due to its effectiveness in reducing the concentration of chromium (Vl) to very low levels. It requires little processing and is reversible as well as eco-friendly in contrast to traditional methods. 相似文献
109.
Prakash Karamchandani Christian Seigneur 《Journal of the Air & Waste Management Association (1995)》2013,63(9):175-181
ABSTRACT The rate of formation of secondary particulate matter (PM) in power plant plumes varies as the plume material mixes with the background air. Consequently, the rate of oxidation of sulfur dioxide (SO2) and nitrogen dioxide (NO2) to sulfate and nitric acid, respectively, can be very different in plumes and in the background air (i.e., air outside the plume). In addition, the formation of sulfate and nitric acid in a power plant plume is a strong function of the chemical composition of the background air and the prevailing meteorological conditions. We describe the use of a reactive plume model, the Reactive and Optics Model of Emissions, to simulate sulfate and nitrate formation in a power plant plume for a variety of background conditions. We show that SO2 and NO2 oxidation rates are maximum in the background air for volatile organic compound (VOC)-limited airsheds but are maximum at some downwind distance in the plume when the background air is nitrogen oxide (NOx)-limited. Our analysis also shows that it is essential to obtain measurements of background concentrations of ozone, aldehydes, peroxyacetyl nitrate, and other VOCs to properly describe plume chemistry. 相似文献
110.
Akula Venkatram Prakash Karamchandani Prasad Pai Christine Sloane Pradeep Saxena Robert Goldstein 《Journal of the Air & Waste Management Association (1995)》2013,63(3):286-301
This paper describes the development and application of the Visibility and Haze in the Western Atmosphere (VISHWA) model to understand the source-receptor relationships that govern chemical species relevant to visibility degradation in the western United States. The model was developed as part of a project referred to as Visibility Assessment for Regional Emission Distributions (VARED), the objective of which is to estimate the contributions of various geographical regions, compounds, and emission sources to light scattering and absorption by particles on the Colorado Plateau. The VISHWA model is a modified version of a comprehensive Eulerian model, known as the Acid Deposition and Oxidant Model.1 The modifications were designed to obtain the computational efficiency required to simulate a one-year period at about 1/25th of real time, and at the same time incorporate mechanistic features relevant to realistic modeling of the fate and transport of visibility degrading species. The modifications included use of a condensed chemical mechanism; incorporation of reactions to simulate the formation of secondary organic particles; and use of a semi-Lagrangian advection scheme to preserve concentration peaks during advection. The model was evaluated with 1992 air quality data from Project MOHAVE (Measurements of Haze and Visual Effects) intensive experiments. An important conclusion of this evaluation is that aqueous-phase oxidation of SO2 to sulfate in nonprecipitating clouds makes a significant contribution to observed sulfate levels during winter as well as summer. Model estimates of ambient sulfate for the winter intensive were within a factor of 2 of the observations for 75% of the values. The corresponding statistic for the summer intensive was 90%. Model estimates of carbon were within a factor of 2 of the limited set of observations. 相似文献