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981.
Romeu Casarano Denise F. S. Petri Michael Jaffe Luiz H. Catalani 《Journal of Polymers and the Environment》2010,18(1):33-44
A new aliphatic block copolyester was synthesized in bulk from transesterification techniques between poly((R)-3-hydroxybutyrate)
(PHB) and poly(isosorbide succinate) (PIS). Additionally, other two block copolyesters were synthesized in bulk either from
transesterification reactions involving PHB and poly(l-lactide) (PLLA) or from ring-opening copolymerization of l-lactide and hydroxyl-terminated PHB, as result of a previous transesterification reactions with isosorbide. Two-component
blends of PHB and PIS or PLLA were also prepared as comparative systems. SEC, MALDI-TOF mass spectrometry (MALDI-TOFMS), 1H and 13C NMR spectroscopy, WAXD, solubility tests, and TG thermal analysis were used for characterization. The block copolymer structures
of the products were evidenced by MALDI-TOFMS, 13C NMR, and WAXD data. The block copolymers and the corresponding binary blends presented different solubility properties,
as revealed by solubility tests. Although the incorporation of PIS sequences into PHB main backbone did not enhance the thermal
stability of the product, it reduced its crystallinity, which could be advantageous for faster biodegradation rate. These
products, composed of PHB and PIS or PLLA sequences, are an interesting alternative in biomedical applications. 相似文献
982.
Analysis of arable land loss and its impact on rural sustainability in Southern Jiangsu Province of China 总被引:2,自引:0,他引:2
Rapid urbanization and industrialization in southern Jiangsu Province have consumed a huge amount of arable land. Through comparative analysis of land cover maps derived from TM images in 1990, 2000 and 2006, we identified the trend of arable land loss. It is found that most arable land is lost to urbanization and rural settlements development. Urban settlements, rural settlements, and industrial park-mine-transport land increased, respectively, by 87 997 ha (174.65%), 81 041 ha (104.52%), and 12 692 ha (397.99%) from 1990 to 2006. Most of the source (e.g., change from) land covers are rice paddy fields and dryland. These two covers contributed to newly urbanized areas by 37.12% and 73.52% during 1990–2000, and 46.39% and 38.86% during 2000–2006. However, the loss of arable land is weakly correlated with ecological service value, per capita net income of farmers, but positively with grain yield for some counties. Most areas in the study site have a low arable land depletion rate and a high potential for sustainable development. More attention should be directed at those counties that have a high depletion rate but a low potential for sustainable development. Rural settlements should be controlled and rationalized through legislative measures to achieve harmonious development between urban and rural areas, and sustainable development for rural areas with a minimal impact on the ecoenvironment. 相似文献
983.
Anaerobic lagoons are commonly used for the treatment of swine wastewater. Although these lagoons were once thought to be relatively simple, their physical, chemical, and biological processes are very complex. This study of anaerobic lagoons had two objectives: (i) to quantify denitrification enzyme activity (DEA) and (ii) to evaluate the influence of lagoon characteristics on the DEA. The DEA was measured by the acetylene inhibition method. Wastewater samples and physical and chemical measurements were taken from the wastewater column of nine anaerobic swine lagoons from May 2006 to May 2009. These lagoons were typical for anaerobic swine lagoons in the Carolinas relative to their size, operation, and chemical and physical characteristics. Their mean value for DEA was 87 mg N2O-N m(-3) d(-1). In a lagoon with 2-m depth, this rate of DEA would be compatible with 1.74 kg N ha(-1) d(-1) When nonlimiting nitrate was added, the highest DEA was compatible with 4.38 kg N ha(-1) d(-1) loss. Using stepwise regression for this treatment, the lagoon characteristics (i.e., soluble organic carbon, total nitrogen, temperature, and NO3-N) provided a final step model R2 of 0.69. Nitrous oxide from incomplete denitrification was not a significant part of the system nitrogen balance. Although alternate pathways of denitrification may exist within or beneath the wastewater column, this paper documents the lack of sufficient denitrification enzyme activity within the wastewater column of these anaerobic lagoons to support large N2 gas losses via classical nitrification and denitrification. 相似文献
984.
Bernhardt ES Colman BP Hochella MF Cardinale BJ Nisbet RM Richardson CJ Yin L 《Journal of environmental quality》2010,39(6):1954-1965
Growing concerns over the potential for unintended, adverse consequences of engineered nanoparticles (ENPs) in the environment have generated new research initiatives focused on understanding the ecological effects of ENPs. Almost nothing is currently known about the fate and transport of ENPs in environmental waters, soils, and sediments or about the biological impacts of ENPs in natural environments, and the bulk of modern nanotoxicogical research is focused on highly controlled laboratory studies with single species in simple media. In this paper, we provide an ecological perspective on the current state of knowledge regarding the likely environmental impacts of nanomaterials and propose a strategy for making rapid progress in new research in ecological nanoscience. 相似文献
985.
986.
987.
Resident Motivations and Willingness-to-Pay for Urban Biodiversity Conservation in Guangzhou (China)
The monetary assessment of biodiversity measures the welfare damages brought by biodiversity losses and the cost-benefit analysis
of conservation projects in a socio-economic context. The contingent valuation method could include motivational factors to
strengthen economic analysis of nature conservation. This study analyzed Guangzhou residents’ motivations and willingness-to-pay
(WTP) for an urban biodiversity conservation program in the National Baiyun Mountain Scenic Area (BMSA). The peri-urban natural
site, offering refuge to some endemic species, is under increasing development pressures for recreational and residential
use. A questionnaire survey was conducted in the Guangzhou metropolitan area during June to October 2007. We interviewed face-to-face
720 stratified sampled households to probe residents’ attitudes towards the city’s environmental issues, motivations for urban
nature conservation, and WTP for biodiversity conservation. Principal component analysis identified five motivational factors,
including environmental benefit, ecological diversity, nature-culture interaction, landscape-recreation function, and intergenerational
sustainability, which illustrated the general economic values of urban nature. Logistic regression was applied to predict
the probability of people being willing to pay for the urban biodiversity conservation in BMSA. The significant predictors
of WTP included household income and the factor nature-culture interaction. The median WTP estimated RMB149/household (about
US$19.5/household) per year and an aggregate of RMB291 million (approximately US$19.5/household) per year and an aggregate of RMB291 million (approximately US38.2 million) annually to support the urban
conservation project. Including public motivations into contingent valuation presents a promising approach to conduct cost-benefit
analysis of public projects in China. 相似文献
988.
Carbon Storage in Soil Size Fractions Under Two Cacao Agroforestry Systems in Bahia, Brazil 总被引:1,自引:0,他引:1
Emanuela F. Gama-Rodrigues P. K. Ramachandran Nair Vimala D. Nair Antonio C. Gama-Rodrigues Virupax C. Baligar Regina C. R. Machado 《Environmental management》2010,45(2):274-283
Shaded perennial agroforestry systems contain relatively high quantities of soil carbon (C) resulting from continuous deposition
of plant residues; however, the extent to which the C is sequestered in soil will depend on the extent of physical protection
of soil organic C (SOC). The main objective of this study was to characterize SOC storage in relation to soil fraction-size
classes in cacao (Theobroma cacao L.) agroforestry systems (AFSs). Two shaded cacao systems and an adjacent natural forest in reddish-yellow Oxisols in Bahia,
Brazil were selected. Soil samples were collected from four depth classes to 1 m depth and separated by wet-sieving into three
fraction-size classes (>250 μm, 250–53 μm, and <53 μm)—corresponding to macroaggregate, microaggregate, and silt-and-clay
size fractions—and analyzed for C content. The total SOC stock did not vary among systems (mean: 302 Mg/ha). On average, 72%
of SOC was in macroaggregate-size, 20% in microaggregate-size, and 8% in silt-and-clay size fractions in soil. Sonication
of aggregates showed that occlusion of C in soil aggregates could be a major mechanism of C protection in these soils. Considering
the low level of soil disturbances in cacao AFSs, the C contained in the macroaggregate fraction might become stabilized in
the soil. The study shows the role of cacao AFSs in mitigating greenhouse gas (GHG) emission through accumulation and retention
of high amounts of organic C in the soils and suggests the potential benefit of this environmental service to the nearly 6
million cacao farmers worldwide. 相似文献
989.
Rachel F. Brummel Kristen C. Nelson Stephanie Grayzeck Souter Pamela J. Jakes Daniel R. Williams 《Journal of Environmental Planning and Management》2010,53(6):681-699
Policies such as the US Healthy Forests Restoration Act (HFRA) mandate collaboration in planning to create benefits such as social learning and shared understanding among partners. However, some question the ability of top-down policy to foster successful local collaboration. Through in-depth interviews and document analysis, this paper investigates social learning and transformative learning in three case studies of Community Wildfire Protection Planning (CWPP), a policy-mandated collaboration under HFRA. Not all CWPP groups engaged in social learning. Those that did learned most about organisational priorities and values through communicative learning. Few participants gained new skills or knowledge through instrumental learning. CWPP groups had to commit to learning, but the design of the collaborative-mandate influenced the type of learning that was most likely to occur. This research suggests a potential role for top-down policy in setting the structural context for learning at the local level, but also confirms the importance of collaborative context and process in fostering social learning. 相似文献
990.
Carbon dioxide emissions have accelerated since the signing of the Kyoto Protocol. This discouraging development may partly
be blamed on accelerating world growth and on lags in policy instruments. However, it also raises serious question concerning
whether policies to reduce CO2 emissions are as effective as generally assumed. In recent years, a considerable number of studies have identified various
feedback mechanisms of climate policies that often erode, and occasionally reinforce, their effectiveness. These studies generally
focus on a few feedback mechanisms at a time, without capturing the entire effect. Partial accounting of policy feedbacks
is common in many climate scenarios. The IPCC, for example, only accounts for direct leakage and rebound effects. This article
attempts to map the aggregate effects of different types of climate policy feedback mechanisms in a cohesive framework. Controlling
feedback effects is essential if the policy measures are to make any difference on a global level. A general conclusion is
that aggregate policy feedback mechanisms tend to make current climate policies much less effective than is generally assumed.
In fact, various policy measures involve a definite risk of ‘backfiring’ and actually increasing CO2 emissions. This risk is particularly pronounced once effects of climate policies on the pace of innovation in climate technology
are considered. To stand any chance of controlling carbon emissions, it is imperative that feedback mechanisms are integrated
into emission scenarios, targets for emission reduction and implementation of climate policy. In many cases, this will reduce
the scope for subsidies to renewable energy sources, but increase the scope for other measures such as schemes to return carbon
dioxide to the ground and to mitigate emissions of greenhouse gases from wetlands and oceans. A framework that incorporates
policy feedback effects necessitates rethinking the design of the national and regional emission targets. This leads us to
a new way of formulating emission targets that include feedback effects, the global impact target. Once the full climate policy feedback mechanisms are accounted for, there are probably only three main routes in climate
policy that stand a chance of mitigating global warming: (a) returning carbon to the ground, (b) technological leaps in zero-emission
energy technology that make it profitable to leave much carbon in the ground even in Annex II countries and (c) international
agreements that make it more profitable to leave carbon in the ground or in forests. 相似文献