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391.
392.
Wu SP Tao S Zhang ZH Lan T Zuo Q 《Environmental pollution (Barking, Essex : 1987)》2007,147(1):203-210
Total suspended particle (TSP) was collected and analyzed at rural and urban sites in Tianjin, China during the domestic heating season (from 15 November to 15 March) of 2003/4 for n-alkanes and 16 polycyclic aromatic hydrocarbons (PAHs). The normalized distribution of n-alkanes with the peak at C22, C23, C24 or C25 suggested that fossil fuel utilization was the major source of particulate n-alkanes at both sites. PAHs normalized distribution for each sample was similar and the higher molecular weight PAH dominated the profile (around 90%) indicating a stronger combustion source at both sites. Precipitation and wind were the most important meteorological factors influencing TSP and PAHs atmospheric concentrations. In the urban area the emission height had significant influence on PAHs levels at different heights under the relative stable atmospheric conditions. Coal combustion was the major source for TSP-bound PAHs at both sites based on some diagnostic ratios. 相似文献
393.
The Yellow River in winter as source water is characterized as high alkalinity, low temperature and low particle concentrations,
which have brought many difficulties to water treatment plants. This study fully examines the optimized coagulation process
of the Yellow River by conventional and pre-polymerized metal coagulants, pH adjustment and polyelectrolytes as the primary
coagulants or coagulant aids. For all the metal coagulants, polyaluminum chlorides are superior to traditional metal coagulants
due to their stable polymeric species and low consumption of alkalinity. The removal of natural organic matter by monomeric
metal coagulants can be improved through pH adjustment, which is in accordance with the higher concentration of polymeric
species formed at corresponding pH value. With the addition of polyelectrolytes as coagulant aids, the coagulation performance
is significantly improved. The effective removal of dissolved organic matter is consistent with high charge density, while
molecular weight is relatively important for removing particles, which is consistent with polyelectrolytes as primary coagulants.
These results suggest that the coagulation mechanisms in the removal of dissolved organic matter and particles are different,
which may be exploited for optimized coagulation for the typical source water in practice. 相似文献
394.
395.
We measured the in situ suspended sediment concentration (SSC) and hydrodynamics (waves, currents, and sea level) concurrently during a storm event using self-recording instruments at offshore of the Shandong Peninsula in the Yellow Sea. We analyzed the temporal variation in suspended sediment carrying capacity and its correlation with wave, current, and water-level conditions. There was about 40% increase in SSC during the storm event. A 3-4-h lag was observed between the peak of wave height and SSC. The SSC increased in a fluctuating pattern up to the peak then decreased rapidly. This process was positively correlated with wave height and duration. The maximum SSC was 524.3 mg/l, which is about 10 times of that under normal weather conditions. This peak was observed after of a series of 1.8 m waves. The increased suspended sediments were the fine particles resuspended by the storm waves from seabed near the observation spot and transported by northward ebb currents from Shidao Bay. 相似文献
396.
Assessment of ecosystem health based on fish assemblages in the Wei River basin,China 总被引:1,自引:0,他引:1
Wei Wu Zongxue Xu Xuwang Yin Depeng Zuo 《Environmental monitoring and assessment》2014,186(6):3701-3716
In the Wei River basin, the ecosystem is gradually deteriorating due to the rapid growth of the population and the development of economies. It is thus important to assess the ecosystem health and take measures to restore the damaged ecosystem. In this study, an index of biotic integrity (IBI) for fish was developed to aid the conservation of the ecosystem based on a calibration data set. An index of water and habitat quality (IWHQ) was calculated based on environmental variables and habitat quality (QHEI) to identify the environmental degradation in the studied sites. The least degraded sites (IWHQ?≤?2; W1, W5, W10, W12, W13, W14, and W16) were chosen as the reference sites. Six metrics that are sensitive to environmental degradation were utilized to differentiate the reference and the impaired sites using statistical methods. These metrics included the number of species (P1), the total biomass (P2), the number of Cobitidae species (P8), the proportion of species in the middle and low tiers (P10), the proportion of individuals that were classified as sensitive species (P25), and number of individuals in the sample (P39). A continuous scoring method was used to score the six metrics, and four classes were defined to characterize the ecosystem health of the Wei River basin. The fact that the overall IBI scores were negatively correlated with the index of environmental quality (IWHQ) based on the validation data set indicated that the index should be useful for biomonitoring and the conservation of biodiversity. According to the results, more than half of the sites were classified as poor or very poor. The ecosystem health in the Wei River was better than that in the Jing River and the Beiluo River, and this study will be a great reference for water resources management and ecosystem restoration in the Wei River basin. 相似文献
397.
Performance and mechanism for cadmium and lead adsorption from water and soil by corn straw biochar 总被引:2,自引:0,他引:2
Cadmium (Cd) and lead (Pb) in water and soil could be adsorbed by biochar produced from corn straw. Biochar pyrolyzed under 400°C for 2 h could reach the ideal removal efficiencies (99.24%and 98.62% for Cd and Pb, respectively) from water with the biochar dosage of 20 g·L–1 and initial concentration of 20 mg·L–1. The pH value of 4–7 was the optimal range for adsorption reaction. The adsorption mechanism was discussed on the basis of a range of characterizations, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR) and Raman analysis; it was concluded as surface complexation with active sorption sites (-OH, -COO-), coordination with π electrons (C = C, C = O) and precipitation with inorganic anions (OH-, CO3 2–, SO4 2–) for both Cd and Pb. The sorption isotherms fit Langmuir model better than Freundlich model, and the saturated sorption capacities for Cd and Pb were 38.91 mg·g-1 and 28.99 mg·g–1, respectively. When mixed with soil, biochar could effectively increase alkalinity and reduce bioavailability of heavy metals. Thus, biochar derived from corn straw would be a green material for both removal of heavy metals and amelioration of soil. 相似文献
398.
399.
Hua Zi Wang Hai Gen Zuo Ya Juan Ding Shan Shan Miao Chen Jiang Hong Yang 《Environmental science and pollution research international》2014,21(6):4331-4342
Dufulin is a newly developed antiviral agent (or pesticide) that activates systemic acquired resistance of plants. This pesticide is widely used in China to prevent abroad viral diseases in rice, tobacco and vegetables. In this study, the potential impacts such as soil type, moisture, temperature, and other factors on Dufulin degradation in soil were investigated. Degradation of Dufulin followed the first-order kinetics. The half-life values varied from 2.27 to 150.68 days. The dissipation of Dufulin was greatly affected by soil types, with DT50 (Degradation half time) varying between 17.59, 31.36, and 43.32 days for Eutric Gleysols, Cumulic Anthrosols, and Dystric Regosols, respectively. The elevated moisture accelerated the decay of Dufulin in soil. Degradation of Dufulin increased with temperature and its half-life values ranged from 16.66 to 42.79 days. Sterilization of soils and treatment with H2O2 resulted in a 6- and 8-fold decrease in degradation rates compared to the control, suggesting that Dufulin degradation was largely governed by microbial processes. Under different light spectra, the most effective degradation occurred with 100-W UV light (DT50?=?2.27 days), followed by 15-W UV light (DT50?=?8.32 days) and xenon light (DT50?=?14.26 days). Analysis by liquid chromatography-mass spectroscopy (LC-MS) revealed that 2-amino-4-methylbenzothiazole was one of the major decayed products of Dufulin in soils, suggesting that elimination of diethyl phosphate and 2-fluorobenzaldehyde was most like the degradation pathway of Dufulin in Eutric Gleysols. 相似文献
400.
Phenanthrene (Phe) is one of the most abundant polycyclic aromatic hydrocarbons in the aquatic environment as a result of human activities. It is widely accepted that Phe has cardiotoxic effects. Even so, knowledge concerning the mechanism(s) of cardiac development toxicity is still limited. In this study, we exposed zebrafish embryos to environmentally relevant concentrations of Phe and then investigated its cardiotoxic effects and the mechanism(s) involved. Some cardiac morphogenetic defects, which was characterized by an abnormally looped and enlarged heart, dilated and thinner ventricular wall, and increased interstitial fibrosis, were observed in the Phe treated groups. The mRNA and protein expression levels of matrix metalloproteinase-9 (MMP-9), as well as the MMP-9 activity, were induced. Moreover, during co-treatment of the zebrafish embryos with MMP-9 inhibitor, the cardiac defects caused by Phe were attenuated. In addition, Phe exposure led to an up-regulation of transforming growth factor β (TGF-β), which plays a crucial role in mediating cardiac fibrosis. Taken together, our data indicated that the exposure to Phe of zebrafish embryos disrupted normal cardiac development, and that the cardiac defects induced by Phe were mediated by the MMP-9, while TGF-β was also involved in these cardiac defects. 相似文献