Pollution source analyses using 1-dimensional time series

Lake Holiday, a human-made recreational lake in northern Illinois, was threatened with closure due to high bacterial levels. A factorially designed experiment with multivatiate responses was developed to study and identify the main sources of pollution. Data on total coliform, fecal coliform, fecal streptococci, dissolved oxygen, pH, ammonia-N, total phosphorus, nitrate/nitrite-N were analyzed using regression models describing dam spillway loads as a function of source loads and time. The results suggest that the relationships among source, time, and load are complex, even though only two sources account for most of the lake's loading Stevens Brook, which receives the discharge from the Somonauk Sewage Treatment Plant, and Somonauk Creek, which is the major drainage, contribute high loads of bacteria and nutrients to the lake. The influent loads contributed to the lake are discharged at the dam over about 4 weeks     

Degradation of explosives-related compounds using nickel catalysts

We report the ability of nickel-based catalysts to degrade explosives compounds in aqueous solution. Several nickel catalysts completely degraded the explosives, although rates varied. Nearly all of the organic explosive compounds tested, including 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), were rapidly degraded to below detection limits by a powdered nickel on an alumina-silicate support (Aldrich nickel catalyst). Perchlorate degradation was minimal (<25%). Degradation of TNT by Aldrich nickel catalyst resulted in apparent first-order kinetics. Significant gaseous 14C was released and collected in an alkaline solution (most likely carbon dioxide) from [14C]RDX and [14C]HMX, indicating heterocyclic ring cleavage. Significant gaseous 14C was not produced from [14C]TNT, but spectrophotometric evidence indicated loss of aromaticity. Degradation occurred in low ionic strength solutions, groundwater, and from pH 3 to pH 9. Degradation of TNT, RDX, and HMX was maintained in flow-through columns of Aldrich nickel catalyst mixed with sand down to a hydraulic retention time of 4h. These data indicate that nickel-based catalysts may be an effective means for remediation of energetics-contaminated groundwater.     

Appraising different models for predicting biomethane potential: the case of avocado oil processing by-products

Journal of Material Cycles and Waste Management - Biomethane potentials (BMPs) for avocado oil processing by-products were determined using six different theoretical BMP prediction models and...     

THE SOCIAL CONTEXT OF WESTERN WATER DEVELOPMENT1

ABSTRACT: Social scientists were included in the planning and design for an integrated, trans-basin water resource project. Within this complex project, a socioeconomic impact assessment (SIA) concentrated on identifying the social, political, and economic issues and potential impacts inherent in developing a city's water rights. Before the SIA began, some of the development alternatives had already generated widespread hostility and organized opposition from communities within the watershed. The SIA involved residents of affected communities in the study design and project planning. The study found a number of components that constituted the concerns, beliefs, and expectations about perceived, potential impacts that might result from the different alternatives. In most cases these issues constituted threats to valued environmental resources, valued community resources, the social environment, the economic base, and a secure future. The social science component was a key factor in the ultimate decision to pursue a particular alternative which was sensitive to the social and political issues, minimized environmental and socioeconomic impacts, and ultimately had support among the communities potentially affected. The experience from this case study suggests that the approach used can be applied successfully in the planning of other water development projects and result in cooperation from the wide range of interest groups that often present costly obstacles to such projects.     

Managing environmental problems during transitions: The department of energy as a case study

Many federal, state, and private agencies deal with long‐term environmental problems within a transition framework where political administrations, funds, regulators, regulatory requirements, environmental conditions, and tribal and stakeholder concerns change. In this article, we examine the types of transitions, as well as important stabilities, that agencies face, the interactions with stakeholders that are vulnerable to disruption or failure, and some of the problems that develop as a result of these conditions, using the U.S. Department of Energy (US DOE's) Office of Environmental Management (EM) as a case study. Transitions, or instabilities, include changes in administrations at the federal, state, and local level; public perceptions and concerns; political climate; available funds; environmental conditions (e.g., global climate change, global contaminant transport, local and regional contamination); international and national business conditions; and site conditions (physical, chemical, biological). Governmental agencies operate under several different kinds of uncertainties, including scientific, fiscal‐year economic, technological, and societal. Not all information can be known, and the outcomes from scientific issues or technologies cannot always be predicted. The authors believe that transitions from one set of conditions to another can be more effectively integrated with the long‐term stability of environmental laws and regulations, and with the stability of the treaty rights and concerns of tribal nations, as well as the shorter‐term stability of career personnel and established programs. A sense of stability for government agencies allowing maintenance of ongoing environmental management programs can also be achieved through processes and programs, such as establishing long‐term contracts (for remediation or restoration work), schedule and scope documents, future land‐use documents, National Environmental Research Parks (which obligate lands to study and conservation), and other programs that set the direction of work and activities for many years. Further, two other factors are essential for success within any agency facing transitions: (1) expectations should be both forward‐looking and realistic, and (2) there must be flexibility in both programs and processes. The authors conclude that several features are essential to addressing some of the problems created by transitions, including information, integration, iteration, interaction, and inclusion. © 2009 Wiley Periodicals, Inc.     

Encouraging pro-environmental behaviour: An integrative review and research agenda

Environmental quality strongly depends on human behaviour patterns. We review the contribution and the potential of environmental psychology for understanding and promoting pro-environmental behaviour. A general framework is proposed, comprising: (1) identification of the behaviour to be changed, (2) examination of the main factors underlying this behaviour, (3) design and application of interventions to change behaviour to reduce environmental impact, and (4) evaluation of the effects of interventions. We discuss how environmental psychologists empirically studied these four topics, identify apparent shortcomings so far, and indicate major issues for future research.     

Development of artificial neural network based metamodels for inactivation of anthrax spores in ventilated spaces using computational fluid dynamics

Linear, quadratic, and artificial neural network (ANN)-based metamodels were developed for predicting the extent of anthrax spore inactivation by chlorine dioxide in a ventilated three-dimensional space over time from computational fluid dynamics model (CFD) simulation data. Dimensionless groups were developed to define the design space of the problem scenario. The Hammersley sequence sampling (HSS) method was used to determine the sampling points for the numerical experiments within the design space. A CFD model, comprised of multiple submodels, was applied to conduct the numerical experiments. Large eddy simulation (LES) with the Smagorinsky subgridscale model was applied to compute the airflow. Anthrax spores were modeled as a dispersed solid phase using the Lagrangian treatment. The disinfectant transport was calculated by solving a mass transport equation. Kinetic decay constants were included for spontaneous decay of the disinfectant and for the reaction of the disinfectant with the surfaces of the three-dimensional space. To enhance the mixing of the disinfectant with the room air, a momentum source was included in the simulation. An inactivation rate equation accounted for the reaction between the spores and the disinfectant. The ANN-based metamodels were most successful in predicting the number of viable bioaerosols remaining in an arbitrary enclosed space. Sensitivity analysis showed that the mass fraction of the disinfectant, inactivation rate constant, and contact time had the most influence on the inactivation of the spores.     

New perspectives on the energy return on (energy) investment (EROI) of corn ethanol

Research on corn ethanol is overly focused on whether corn ethanol is a net energy yielder and, consequently, has missed some other fundamental issues, including (1) whether there is significant error associated with current estimates of the EROI of corn ethanol, (2) whether there is significant spatial variability in the EROI of corn ethanol production, (3) whether yield increases will translate linearly to increases in EROI, (4) the extent to which assumptions about co-product credits impact the EROI of corn ethanol, and (5) how much of the ethanol production from biorefineries is net energy. We address all of these concerns in this research by: (1) performing a meta-error analysis of the calculation of EROI, (2) calculating the EROI for 1,287 counties across the United States, and (3) performing a sensitivity analysis for the values of both yield and co-products within the calculation of EROI. Our results show that the average EROI calculated from the meta-error analysis was 1.07 ± 0.2, meaning that we are unable to assert whether the EROI of corn ethanol is greater than one. The average EROI calculated across 1,287 counties in our spatial analysis was 1.01, indicating that the literature tended to use optimal values for energy inputs and outputs compared to the average conditions across the Unites States. Increases in yield had a trivial impact on EROI, while co-product credits had a large impact on EROI. Based on our results from the spatial analysis and the location of biorefineries across the United States, we conclude that the net energy supplied to society by ethanol is only 0.8% of that supplied from gasoline. Recent work indicates that only energy sources extracted at EROIs of 3:1 or greater have the requisite net energy to sustain the infrastructure of the transportation system of the United States. In light of this work, we conclude that production of corn ethanol within the United States is unsustainable and requires energy subsidies from the larger oil economy.     

Effect of temperature on the containment properties of argillaceous rocks: The case study of Callovo-Oxfordian claystones

Heat generated by high level radioactive wastes could alter the performance of a clay repository. It was intended to investigate the effect of such a thermal period on the diffusive properties of Callovo-Oxfordian claystones. Thus, through-diffusion experiments with HTO, Cl-36, Na-22 and Cs-137 were performed before, during and after stages of heating at 80°C that lasted for up to one year. A special attention was paid to limit the occurrence of any chemical disturbance. Therefore (i) the temperature was raised to 80°C, then progressively brought back to 21°C, thanks to three intermediate temperature stages, and (ii) specific synthetic solutions were used for each temperature, chemistry of which being close to the equilibrium state, especially with respect to the carbonate and sulphate minerals. It was found that experiments carried out at 80°C showed a clear increase of the effective diffusion coefficient values for the four tracers with respect to those obtained at 21°C (by a factor of 3 for HTO and Cl-36, 5 for Na-22 and 2 for Cs-137). On the other hand, the porosity and rock capacity values did not exhibit any significant discrepancy between 21°C and 80°C, indicating no observable damage of both the pore conducing network and the sorption properties of clay minerals. The Stokes-Einstein relationship, based on the temperature dependency of the viscosity of bulk water, could be used to describe the temperature dependence of the diffusion of HTO and Cl-36 but failed to describe the diffusive evolution of the two sorbing cations, Na-22 and Cs-137. Furthermore, experiments performed after the thermal period led to diffusive properties well matching those obtained before heating. All these results suggest that at the lab scale the heating of rock samples would not alter the claystone containment properties.