Determination of volatile organic profiles and photochemical potentials from chemical manufacture process vents

The main objective of this study was to monitor the volatile organic compounds (VOCs) in the stack gas released from organic chemical industrial plants to determine emission factors. Samples from 52 stacks, with or without air pollution control devices (APCDs), from seven industrial processes were taken and VOCs measured using U.S. Environmental Protection Agency (EPA) Method 18. These 7 processes, including 26 plants, were the manufacturers of acrylonitrile-butadiene-styrene (ABS), polyvinyl chloride (PVC), polystyrene (PS), acrylic resin (ACR), vinyl chloride (VC), para-terephthalic acid (PTA), and synthetic fiber (SYF). The results clearly indicate significant variations of emission factors among the various industrial processes, particularly emission factors for those without APCDs. As expected, those with APCDs yield much less emission factors. Regardless of those with or without APCDs, the order of manufacturing processes with regard to VOC emission factors is SYF > ABS > PS >ACR > PTA > PVC > VC. The emission factors for some processes also differ from those in EPA-42 data file. The VOC profiles further indicate that some VOCs are not listed in the U.S. VOC/Particulate Matter Speciation Data System (SPECIATE). The potential O3 formation is determined from the total amount of VOC emitted for each of seven processes. The resultant O3 yield varied from 0.22 (ACR) to 2.33 g O3 g(-1) VOC (PTA). The significance of this O3 yield is discussed.     

水中微量弱极性内分泌干扰物测定方法的研究

使用ENVITM Chrom P固相萃取小柱、双(三甲基硅烷基)三氟乙酰胺(BSTFA)衍生剂及气质联机,系统研究了水中弱极性内分泌干扰物(EDCs)的测定方法.通过正交试验,得到最佳固相萃取条件为:水样流速5 mL/min,洗脱剂为二氯甲烷,洗脱速率0.5 mL/min,洗脱剂体积6 mL.最佳衍生化条件为:BSTFA 100 μL,60 ℃,反应时间30 min.结果表明,双酚A、五氯酚、2,4-二氯苯酚、4-壬基酚、雌二醇、雌三醇、雌酮、炔雌二醇的回收率在82.4%～101.9%,检出限为0.01～0.06 μg/L.     

Effect of SiO2 addition on NH4HSO4 decomposition and SO2 poisoning over V2O5–MoO3/TiO2–CeO2 catalyst

The deposition of NH₄HSO₄ and the poisoning effect of SO₂ on SCR catalyst are the main obstacles that restrict the industrial application of CeO₂-doped SCR catalysts. In this work, deposited NH₄HSO₄ decomposition behavior and SO₂ poisoning over V₂O₅–MoO₃/TiO₂ catalysts modified with CeO₂ and SiO₂ were investigated. By the means of characterization analysis, it was found that the addition of SiO₂ into VMo/Ti–Ce had an impact on the interaction existed between catalyst surface atoms and NH₄HSO₄. Temperature-programmed methods and in situ diffused reflectance infrared Fourier transform spectroscopy (DRIFTS) experiments indicated that the doping of SiO₂ promoted the decomposition of deposited NH₄HSO₄ on VMo/Ti–Ce catalyst surface by reducing the thermal stability of NH₄HSO₄ and enhancing the NH₄HSO₄ reactivity with NO in low temperature. And this improvement may be the reason for the better catalytic activity than VMo/Ti–Ce in the case of NH₄HSO₄ deposition. Accompanied with cerium sulfate species generated over catalyst surface, the conversion of SO₂ to SO₃ was inhibited in SiCe mixed catalyst. The addition of SiO₂ could promote the decomposition of cerium sulfate, which may be a potential strategy to enhance the resistance of SO₂ poisoning over CeO₂-modifed catalysts.     

运用模拟方法解决步行街人车混流区问题

在分析城市步行街及其周边存在人车混行、人员密度高、通行效率低、潜在的危险大的基础上,笔者用计算机模拟方法研究了沈阳市中街步行街的一个人车混行的交叉路口,实际勘察了十字路口道路格局、车流、人流状况,测量、估计通过路口的人数、流量,根据获得的数据,对不设置交通信号灯、设置信号灯、建设过街天桥或地下通道等几种情况进行模拟,得到各种情况下的通行效率,并对不同的过街方案的优缺点进行比较。最终选择过街方案需要综合考虑影响安全和效率的多种因素,包括地域、人流量、路口宽度、周边交通等因素,用较小的经济投入取得最大的通行效率。文中的模拟采用EXODUS软件。     

高风险社会及其对策研究

经济和技术不断发展的过程中伴随的副作用使人类社会逐渐处于“风险社会”乃至“高风险社会”之中。当前我国正处于结构调整和社会转型中,存在着自然灾害、事故灾难、公共卫生事件和社会安全事件等各种各样的风险。在对现代社会风险的特点进行归纳后,对其量化方法也进行了初步探讨,并结合我国实际情况从影响风险大小的各因素入手,拟定了若干风险管理对策,对如何面对“风险社会”和提高风险承受能力可起到积极的参考作用。     

职业安全培训效果定量评估方法应用研究

职业安全培训是企业安全管理的重要内容,是提高员工安全意识和事故风险管理技能的主要手段。但是职业安全培训效果如何,目前尚无有效的定量评估方法。针对安全培训这个复杂的多因素、多变量、多层次系统,通过对影响培训效果的各因素以及因素之间的相互联系进行系统深入的分析,建立起科学、全面和客观的评价指标体系;通过运用层次分析法(AHP)法,合理准确地确定各评价因素的权重,在此基础上运用模糊数学基本理论构建职业安全培训效果定量评估模型;并通过案例加以应用,表明该模型的评价结果能较好地反映实际情况,对于提高和改善培训质量,降低事故风险,具有重要的应用价值。     

Use of Chitosan as Coagulant to Treat Wastewater from Milk Processing Plant

Chitosan is a natural high molecular polymer made from crab, shrimp and lobster shells. When used as coagulant in water treatment, not like aluminum and synthetic polymers, chitosan has no harmful effect on human health, and the disposal of waste from seafood processing industry can also be solved. In this study the wastewater from the system of cleaning in place (CIP) containing high content of fat and protein was coagulated using chitosan, and the fat and the protein can be recycled. Chitosan is a natural material, the sludge cake from the coagulation after dehydrated could be used directly as feed supplement, therefore not only saving the spent on waste disposal but also recycling useful material. The result shows that the optimal result was reached under the condition of pH 7 with the coagulant dosage of 25 mg/l. The analysis of cost-effective shows that no extra cost to use chitosan as coagulant in the wastewater treatment, and it is an expanded application for chitosan.     

石英负载TiO2光催化材料的制备及降解性能研究

选用石英作为载体,采用溶胶-凝胶法负载TiO2制备石英负载TiO2光催化材料.光电子能谱分析结果表明：石英表面成功负载了TiO2.石英负载TiO2光催化材料对偶氮染料废水处理4h后,脱色率达到了96.28%.     

服务期的法律定性和法律后果

案例 张某自2000年进入某公司工作,任公司技术开发部副主任,劳动合同每年签订一次.2001年,张某参与了公司的技术开发工作,9月12日与公司签订《技术保密协议》.约定：保密产品主要为公司已在生产和开发成功的各类浸渍手套.