Novel two-step vapor-phase synthesis of UV–Vis light active Fe2O3/WO3 nanocomposites for phenol degradation

Supported Fe₂O₃/WO₃ nanocomposites were fabricated by an original vapor phase approach, involving the chemical vapor deposition (CVD) of Fe₂O₃ on Ti sheets and the subsequent radio frequency (RF)-sputtering of WO₃. Particular attention was dedicated to the control of the W/Fe ratio, in order to tailor the composition of the resulting materials. The target systems were analyzed by the joint use of complementary techniques, that is, X-ray diffraction (XRD), field emission-scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), energy dispersive X-ray spectroscopy (EDXS), X-ray photoelectron spectroscopy (XPS), secondary ion mass spectrometry (SIMS), and optical absorption spectroscopy. The results showed the uniform decoration of α-Fe₂O₃ (hematite) globular particles by tiny WO₃ aggregates, whose content could be controlled by modulations of the sole sputtering time. The photocatalytic degradation of phenol in the liquid phase was selected as a test reaction for a preliminary investigation of the system behavior in wastewater treatment applications. The system activity under both UV and Vis light illumination may open doors for further material optimization in view of real-world end-uses.

     

Biologic impact on the coastal belt of the province of Venice (Italy,Northern Adriatic Sea): preliminary analysis for the characterization of the bathing water profile

Background, aim and scope  

This paper presents a preliminary study of the water profile with reference to microbiological parameters, required by Directive 2006/07/EC (European Community 2006) concerning the management of bathing water quality, in the coastal belt of the Province of Venice (Italy, Northern Adriatic Sea). A historical database has been implemented with monitoring data for the period 2000–2006 (data on rivers, bathing and marine coastal waters and on the characterization of Wastewater Treatment Plant (WWTP) discharges) from the institutional activity of Veneto Regional Environmental Prevention and Protection Agency (ARPAV). An integrated areal analysis for the microbiological investigation of homogeneous stretches along the coast of the Province of Venice was performed for a preliminary characterization of the bathing water profile considering water quality status and existing pressure sources.     

Scenarios of change in the realized climatic niche of mountain carnivores and ungulates

Mountains are among the natural systems most affected by climate change, and mountain mammals are considered particularly imperiled, given their high degree of specialization to narrow tolerance bands of environmental conditions. Climate change mitigation policies, such as the Paris Agreement, are essential to stem climate change impacts on natural systems. But how significant is the Paris Agreement to the survival of mountain mammals? We investigated how alternative emission scenarios may determine change in the realized climatic niche of mountain carnivores and ungulates in 2050. We based our predictions of future change in species niches based on how species have responded to past environmental changes, focusing on the probabilities of niche shrink and niche stability. We found that achieving the Paris Agreement's commitments would substantially reduce climate instability for mountain species. Specifically, limiting global warming to below 1.5°C would reduce the probability of niche shrinkage by 4% compared with a high-emission scenario. Globally, carnivores showed greater niche shrinkage than ungulates, whereas ungulates were more likely to shift their niches (i.e., face a level of climate change that allows adaptation). Twenty-three species threatened by climate change according to the IUCN Red List had greater niche contraction than other species we analyzed (3% higher on average). We therefore argue that climate mitigation policies must be coupled with rapid species-specific conservation intervention and sustainable land-use policies to avoid high risk of loss of already vulnerable species.     

A comparison of DEMETRA individual QSARs with an index for evaluation of uncertainty

Quantitative structure-activity relationships (QSARs) urgently need to be applied in regulatory programs. Many QSAR models can predict the effect of a wide range of substances to different endpoints, particularly in the case of ecotoxicity, but it is difficult to choose the most appropriate model on the basis of the requirements of the application. During the EC-funded project DEMETRA (www.demetra-tox.net) a huge number of QSAR models have been developed for the prediction of different ecotoxicological endpoints. DEMETRA individual models on rainbow trout LC50 after 96 h, water flea LC50 after 48 h and honey bee LD50 after 48 h have been used as a QSAR database to test the advantages of a new index for evaluating model uncertainty. This index takes into consideration the number of outliers (weighted on the total number of compounds) and their root mean square error. Application on the DEMETRA QSAR database indicated that the index can identify the models with the best performance with regard to outliers, and can be used, together with other classical statistical measures (e.g., the squared correlation coefficient), to support the evaluation of QSAR models.     

Biodegradation of oxygenated and non-oxygenated imidazolium-based ionic liquids in soil

Aerobic biodegradation of ionic liquids in soil was monitored for the first time. The tests, followed over six months according to ASTM D 5988-96, were carried out on the four ionic liquids obtained from 1-R-3-methylimidazolium cations, with R=CH(3)(CH(2))(3) and CH(3)O(CH(2))(2), and the tetrafluoroborate and dicyanamide counter anions. The n-butyl derivatives, after an induction period of about two months, were found to be degradable, although the degradation rate with the dicyanamide anion was smaller. In contrast, no significant production of CO(2) was observed in the tests with the methoxyethyl derivatives. Calculations at the B3LYP/6-31G(d) level were carried out to characterize the atomic charge distributions and frontier orbital structures of 1-alkyl-3-methylimidazolium cations and point out the changes caused by replacement of a CH(2) group of the alkyl chain with an oxygen atom. The calculations predict an overall negative charge on the nitrogen atoms of the imidazolium-based cations. The energies of the highest occupied (pi) MO and lowest empty (pi( *)) MO are only slightly perturbed by the length and nature of the alkyl chain. However, the electron-donor properties of the oxy derivatives are radically increased. The HOMO becomes a lone pair orbital mainly localized on the oxygen atom, and its ionization energy is sizeably smaller than that of the outermost ring pi MO.     

Mytilus galloprovincialis as bioindicator in embryotoxicity testing to evaluate sediment quality in the lagoon of Venice (Italy)

The possibility of using Mytilus galloprovincialis from natural populations of the lagoon of Venice in toxicity bioassays based on embryo development, according to international standard methods, was investigated. In order to valuate this method for the lagoon, iterative steps including evaluation of reproducibility, sensitivity and discriminatory capacity towards some pure substances and environmental samples were performed. Evaluation of sensitivity towards a reference toxicant (copper) evidenced good replicability and repeatability. Results showed that natural population is better than hatchery population for performing bioassays. Evaluation of applicability to elutriates revealed that the method is able to discriminate among sediments of the lagoon of Venice at different typologies and levels of contamination, showing an important effect for almost all study sites.     

Risk management of terrorist attacks in the transport of hazardous materials using dynamic geoevents

This paper focuses attention on emergency management associated with a terrorist attack in the transport of hazardous materials in urban areas. The case study is in an urban area, a potential target for terrorist attacks due to its high vulnerability. Since it is not possible to predict where and when an attack will occur, the risk associated with terrorism is complex. It is only possible to identify the critical points for potential actions where counter measure must be applied. In the case of incidents which evolve relatively slowly, mitigation actions can be applied. The use of dynamic geoevents permits the immediate location of the event on a georeferenced map and the possibility of having a dynamic evolution of the scenario and of the number of people involved. The dynamic scenario has been created using the output of a consequence simulation code and a GIS software. Some assumptions were necessary but, since the aim of the paper is to define the procedure for the construction of the dynamic geoevent, these can be considered acceptable. The method will be further implemented in future.