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81.
In recent years, the Taiwanese government has strongly promoted the concept of ecological engineering in the hope that doing so will encourage the maintenance of the ecosystem and its integrity. As a result, the riprap spur dike is one of the most commonly used measures for protecting stream banks. Traditionally, a spur dike is used at concave banks to prevent their scouring and/or to increase their stabilization. An additional benefit of deflector structures, like spur dikes, may be to increase the weighted usable area (WUA) for aquatic life survival during periods of increased flow (examples include typhoon, flood, etc.). A two-dimensional river habitat simulation program (River2D) coupled with a developed shallow water habitat type diversity module was used for the case study at a headwater stream in central Taiwan. The habitat suitability index for this study was established using substrate, depth, and velocity from field surveys for the fish family Cyprinidae by prepositioned area electrofisher. The ungauged flood conditions were calculated using digital elevation models within a watershed delineation and hydrological modeling system in accordance with local regulations. Simulated results indicate that the spur dikes currently in use on the stream in this study need be improved from a WUA point of view more effectively handle a flood event.  相似文献   
82.
The rates of oxygen production and respiration of the colonial zoanthid of the genus Palythoa were measured in situ at a depth of 3.4m (reef-edge) using an automated respirometer. The respirometer recorded changes in oxygen concentration of four samples of Palythoa enclosed in separate perspex chambers concurrently with light intensity (irradiance) readings every 20 seconds for 24 hours. Photosynthetic parameters (Pm(gross), Rd and Ik) were estimated from photosynthesis-irradiance (PI) curves generated for each of the four samples. Average instantaneous maximum gross photosynthetic (Pm(gross)) and respiration (Rd) rates obtained for Palythoa were 12.50µmo2l cm-2h-1 and - 4.24µmolO2cm-2h-1, giving a Pm(gross)/(-Rd) ratio of 2.92. The net 24 hour production (Pn24) at 3.4m, estimated by integrating the photokinetic parameters over 7 days of light data, was negative, resulting in a daily gross photosynthesis to respiration [Pg24/(-Rd24)] ratio of 0.77, while estimated 24 hour productivity at 1.4m gave a ratio of 1.13. This suggests that Palythoa would be able to sustain positive production at 1.4m but not at 3.4m.  相似文献   
83.
The chemical fate and movement of pesticides may be subject to transient storage in unsaturated soils during periods of light rainfall, and subsequent release into shallow groundwater by increased rainfall. The objective of this study was to conduct field-scale experiments to determine the relative importance of transient storage and subsequent release of agrichemicals from the vadose zone into potential aquifers. Two field-scale experiments were conducted under a rain exclusion shelter. In the 1x experiment, atrazine and chlorpyrifos were applied at application-rate equivalents (1.6 kg ha(-1) and 1.3 kg ha(-1), respectively). In the 4x experiment, atrazine was applied in an amount that was four times greater than that usually applied to fields (6.7 kg ha(-1)). Water was either applied to simulate rain or withheld to simulate dry periods. In the 1x experiment, atrazine was detected in the water samples whereas chlorpyrifos was not detected in the majority of the samples. The dry period imposed on the treatment plot did not appear to result in storage of the chemicals, whereas the wet period resulted in greater leaching of atrazine, although the concentrations remained less than the Maximum Contaminant Level of 3 microg L(-1). Both chemicals were detected in soil samples collected from a 20- to 30-cm depth, but it appeared that both chemicals dissipated before the field experiment was concluded. It appeared that the one-time application of atrazine and chlorpyrifos at the label rates did not result in a sufficient mass to be stored and flushed in significant concentrations to the saturated zone. When atrazine was applied at 4x and a longer drought period was imposed on the treatment plot, the resulting concentrations of dissolved atrazine were still less than 3 microg L(-1) . Atrazine was detected in only the near-surface (0 to 15 cm) soil samples and the herbicide dissipated before the onset of the dry period in the treatment plot. The results of this field study demonstrated that atrazine and chlorpyrifos were not sufficiently persistent to be stored and then released in significantly large concentrations to the saturated zone. The dissipation half-life of atrazine in the 4x application was about 44 days. This study, in addition to others, suggested that atrazine may be less persistent in surface soil than has been generally reported.  相似文献   
84.
For resource reutilization, scrap tyres have long been investigated as an additive to concrete to form 'Rubcrete' for various applications and have shown promising results. However, the addition of rubber particles leads to the degradation of physical properties, particularly, the compressive strength of the concrete. In this study, a theoretical model was proposed to shed light on the mechanisms of decrease in compressive strength due to the addition of rubber particles as well as improvement in compressive strength through modification of particle surfaces. The literature suggests that the compressive strength can be improved by soaking the rubber particles in alkaline solution first to increase the inter-phase bonding between the rubber particles and cement. Instead, we discovered that the loss in compressive strength was due to local imperfections in the hydration of cement, induced by the addition of heterogeneous and hydrophobic rubber particles. Microscopic studies showed that the rubber particles disturbed the water transfer to create channels, which were prone to cracking and led to a loss in the compressive strength. Unexpectedly, no cracking was found along the surfaces of the rubber particles, indicating that the bonding strength between the rubber particles and cement phases was not the critical factor in determining the compressive strength. Therefore, a theoretical model was proposed to describe the water transfer in the Rubcrete specimens to explain the experimental data. In the model, the local water available for hydration (Q) is: Q = -A(slv)/6piv, where Q, A(slv), and v are mass flow rate (kg s(-1)), Hamaker constant (J), and dynamic viscosity (m2 s(-1)), respectively. By maximizing the quantity Q and, in turn, the Hamaker constant A(slv), the compressive strength could be improved. The Hamaker constant A(slv) for water film on rubber particle surfaces was smaller than that for the hydrated cement particles; the water transfer rate was lower in the presence of rubber particles because the Hamaker constant A(slv) for water film on rubber particle surfaces was smaller than that on the hydrated cement particles. Thus, the compressive strength of Rubcrete could be improved by increasing the Hamaker constant of the system. This was achieved by increasing the refractive indices of the solids (n(s)). The refractive indices of materials increase with increases in functional groups, such as OH and SH on the surface. The model provided a possible mechanism for the efficacy of treating rubber particles with NaOH in improving the compressive strength. By using NaOH solution treatment, an oxygen-containing OH group was formed on the rubber surface to increase the Hamaker constant of the system, leading to higher compressive strength. Based on this mechanism, a novel method for modification of the rubber particles was also proposed. In this process, the rubber particles were partially oxidized with hot air/steam in a fluidized bed reactor to produce the hydrophilic groups on the surface of the particles. Preliminary results obtained so far are promising in accordance with the theory.  相似文献   
85.
86.
Removal of cadmium ion from aqueous solution.   总被引:3,自引:0,他引:3  
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87.
Chou S  Liao CC  Perng SH  Chang SH 《Chemosphere》2004,54(7):859-866
Our previous work applied a novel supported iron oxyhydroxide (FeOOH) catalyst to effectively treat benzoic acid by hydrogen peroxide. The FeOOH catalyst was prepared via the oxidation of Fe2+ by H2O2 in the acidic condition using a fluidized-bed crystallization reactor. The major components coated on the surface were identified as amorphous FeOOH and gamma-FeOOH. In terms of the crystallization conditions of FeOOH, some parameters including the operational pH, superficial velocity, specific iron loading, and influent H2O2 concentration were investigated to quantify their effects on the crystallization efficiency. All these parameters were found to significantly influence the crystallization efficiency. Two types of FeOOH catalysts were synthesized: FeOOH I was prepared at pH 3.5, and FeOOH II was formed by aging FeOOH I at pH 13. The percentages of surface amorphous FeOOH reduced from 70% to 30% after aging. The FeOOH II catalyst presented a higher reactivity toward H2O2 but lower stoichiometric efficiency in oxidizing benzoic acid than FeOOH I, similar to the result of the commercial goethite. Therefore, it is concluded that the crystalline property significantly affects the performance of catalytic oxidation.  相似文献   
88.
In this study, measurements of elutriation rate were carried out in a bench scale bubbling fluidized bed incinerator, which was used to combust sludge cake. The particle size distribution and ignition loss were analyzed to study the elutriation characteristics of bubbling fluidized bed incineration. Drawn from the experimental data, the elutriation rate constant K(i)* for fine particles were obtained and correlated with parameters. It was found that most of the solid particles (about 95%) elutriated came from the fluidized medium (inorganic matters), but few came from unburned carbon particles or soot (about 5%). Finally, this paper lists a comparison of K(i)* between this study and the published prediction equations derived or studied in non-incineration modes of fluidized bed. A new and modified correlation is proposed here to estimate the elutriation rate of fine particles emitted from a bubbling fluidized bed incinerator. Primary operation variables (superficial gas velocity and incineration temperature) affecting the elutriation rate are also discussed in the paper.  相似文献   
89.
介绍了焊接作业中有害气体对作业人员身体的危害,同时论述了有害气体烟尘的来源、种类及危害情况,介绍了防护措施。  相似文献   
90.
格式栲天然林水源涵养功能的研究   总被引:27,自引:0,他引:27  
本文通过对三明莘口格式栲天然林与人工林的林冠层,林木植被层和林褥层及林下土壤层的持水量,土壤渗透性能差异等的研究。结果表明:格式栲天然林林分持水总量比格式持和楠木人工林分别增加 225.131t/ha 和 296.558t/ha;土壤稳渗值高达 8.09 mm/min,分别是格式栲和楠木人工林的3.3倍和25.3倍。格式栲天然林具有良好的水源涵养功能。  相似文献   
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