Evaluation of uptake of the cytostatic methotrexate in Elliptio complanata mussels by LC–MS/MS

Environmental Science and Pollution Research - Aquatic organisms are continuously exposed to emerging contaminants coming from urban effluents of wastewater treatment plants. The contamination of...     

Effects of water viscosity upon ventilation and metabolism of a flatfish,the common sole <Emphasis Type="Italic">Solea solea</Emphasis> (L.)

The French Atlantic coast contains large highly productive intertidal mudflats that are colonised by juveniles of numerous flatfish species, including the common sole (Solea solea, L.). These ecosystems are also heavily exploited by the shellfish farming industry. Intensive bivalve culture is associated with substantial biodeposition (1–6 t-dw ha⁻¹ day⁻¹), which directly or indirectly contributes to increase exopolysaccharide (EPS) concentrations at the interface between water column and seabed. EPS are long-chain molecules organised into colloids, which influence rheological properties of water, particularly viscosity. Increased water viscosity had consequences for ventilatory activity of juvenile flatfish, whereby the minimal pressure required to ventilate the medium increases directly with EPS concentration. Moreover, the critical EPS concentration ([EPS]_crit) at which water was no longer able to flow through the branchial basket ranged from almost nil to over 30 mg l⁻¹, depending on species and size. [EPS]_crit was lower in small individuals and individuals from species with high metabolic rates (turbot and plaice). These differences may depend upon gill and bucco-branchial cavity morphometrics. The ventilatory workload of sole increased with viscosity to a maximum at 2 mg EPS l⁻¹. Viscosity might, therefore, be a limiting factor for flatfish post larvae, which colonise the intertidal mudflats, depending upon their size and species. EPS concentrations in the field can reach 15 mg l⁻¹. A selective effect is conceivable but remains to be estimated in the field.     

Local or global food markets: A comparison of energy use for transport

This study compares energy use for food transport to a farmers' market in Sweden with energy use for transport in the conventional food system. The farmers' market was investigated through data sampling from on-site investigations. The conventional food system was studied with the aid of life cycle assessments reported in the literature. Overall, the study found no significant differences in levels of energy use for transport to the farmers' market compared with the conventional food system. For certain products, such as fresh fruits and vegetables, transport-related energy use was much lower in the local system although the season in Sweden for this kind of product is restricted to two or three months at the end of the summer. However, there is considerable potential to increase energy efficiency in local food systems by organizing the selling in new ways and by using more energy efficient vehicles.     

Mineralogical study and leaching behavior of a stabilized harbor sediment with hydraulic binder

The environmental assessment of potential effects of contaminated harbor sediments stabilized with hydraulic binders and the determination of remediation endpoints require the determination of pollutants leaching potentials. Moreover, little information about the speciation and mobility of inorganic contaminants in these specific solid matrices is available in the literature. The objective of this paper is to investigate the relationship between mineralogy and leachability of contaminants (copper, lead, and zinc) present in a French harbor sediment stabilized with quicklime and Portland cement. Batch equilibrium leaching tests at various pH, chemical analysis of leachates, and mineralogical studies (X-ray diffraction, scanning electron microscopy–energy dispersive spectroscopy, and diffuse reflectance infrared Fourier transform) have been combined in the present investigation. The acid neutralization capacity of the stabilized matrix studied is first controlled by the dissolution of portlandite (pH?~12), followed by the dissolution of C–S–H (pH?~11) and the dissolution of ettringite (pH?~10). Finally, a very high buffering capacity of this stabilized sediment is observed for pH values around 6. This equilibrium is mainly controlled by the dissolution of iron sulfides and carbonate minerals. Consequently, the mobilization of inorganic contaminants as a function of pH remains very low (<0.1 wt%) for pH values above 6 and significantly increases for pH below these values. This research confirms the importance of a combined methodology for the intrinsic characterization of potential mobilization of contaminants in a stabilized sediment and for a better understanding of geochemical processes that affect contaminant fate, transformation, and transport in the subsurface environment.     

A Laboratory Assessment of an Innovative Technology for the Detection of DNAPLs

A promising new technology for the detection of dense nonaqueous phase liquids, or DNAPLs, is cosolvent injection/extraction. Cosolvents, such as alcohols, are injected into the subsurface and interact with DNAPLs to increase their aqueous solubility, which increases recovery of the chemicals. A laboratory assessment was performed to determine if incorporating this technology with cone penetrometers could provide a useful sampling tool for DNAPL detection. A cone penetrometer was modeled in the laboratory by injecting and extracting small quantities of ethanol and propylene glycol at low concentrations into a homogeneous sand reactor contaminated with a residual saturation of tetrachloroethene (PCE). Experimental test results show that this technology is extremely sensitive to the vertical placement of the sampler, but is capable of enhancing PCE solubility while recovering most of the alcohol injected. Field testing of this technology will provide the next step in determining the feasibility of this technology for DNAPL detection.