Variability in the content and composition of alkaloid found in Canadian ergot. iii. triticale and barley∗

Abstract

The total alkaloid content and individual alkaloid composition were determined by colorimetry and high performance liquid chromatography, respectively, for Canadian triticale and barley ergot (Claviceps purpurea). The total alkaloid content was highly variable between individual sclerotia from the same or different sources and ranged from 0.042 to 0.752% for triticale and from 0.082 to 1.04% for barley; average values were 0.239% for Ottawa triticale, 0.289% for Prairie triticale, and 0.264% for barley. Ergocristine and its isomer ergocristinine were the major constituents in both grains. On average, Canadian ergot pooled from rye, wheat, triticale, and barley consists of ergocristine (31%), ergocristinine (13%), ergocristinine (13%), ergotamine (17%), ergotaminine (8%), ergocryptine (5%), ergocryptinine (3%), ergo‐metrine (5%), ergometrinine (2%), ergosine (4%), ergosinine (2%), ergocornine (4%), ergocorninine (2%), and unidentified alkaloids (3%) and an average total alkaloid content of 0.236%. With the exception of rye and barley ergot from the maritime regions, Canadian rye, wheat, triticale, and barley ergot is fairly uniform in individual alkaloid composition.     

Impoundments and the Decline of Freshwater Mussels: a Case Study of an Extinction Gradient

Abstract: One major factor leading to the imperilment of freshwater mussels ( Bivalvia, Unionidae) has been the large-scale impoundment of rivers. We examined the distribution and abundance of mussels at 37 sites along a 240-km length of the Little River in southeastern Oklahoma, U.S.A., which is affected by both mainstem and tributary reservoirs. We observed a mussel extinction gradient downstream from impoundments in this river: with increasing distance from the mainstem reservoir there was a gradual, linear increase in mussel species richness and abundance. Mussel species distributions were significantly nested, with only sites furthest from the impoundment containing relatively rare species. Below the confluence with the inflow from the second reservoir these same trends were apparent but much weaker, and overall mussel abundance was greatly reduced. Our results suggest that considerable stream lengths are necessary to overcome the effects of impoundment on mussel populations, and such information should be considered in conservation and management plans.     

Environmental Impact Assessment in Victoria: Australian Discretion Rules EA!

Victoria enacted EIA legislation in 1978, before any other state in Australia. The current EIA system, which is administered by the state government, is based upon non-mandatory guidelines which are far more comprehensive than the provisions of the law they elaborate. As it has matured, Victoria's EIA system has developed requirements for the consideration of alternatives, screening, scoping (with project-specific outlines), EIA report-quality checks, proponent response to public comment and the preparation of a ministerial assessment report containing recommendations. The use of consultative committees to advise on scoping and EIA report preparation is one of several public participation provisions. EIA system evaluation criteria are advanced and used to help in reviewing the largely discretionary Victorian system, elements of which could serve as an example to other jurisdictions with incomplete EIA legislative requirements, such as the U.K.     

The Effect of Hydroxyl Radical Generation on Free-Radical Activation of TMP Fibers

The purpose of this work was to study the mechanisms involved in free radical activation of thermal mechanical pulp (TMP) fibers with the ultimate goal of developing methods for bonding wood fiber without the use of traditional adhesives. The generation of hydroxyl radicals in a mediated Fenton system was studied using electron spin resonance (ESR) spin-trapping techniques and indirectly through chemiluminescence measurement. The activation of TMP fibers was also evaluated by ESR measurement of free phenoxy radical generation on solid fibers. The results indicate that low molecular weight chelators can improve Fenton reactions, thus in turn stimulating the free radical activation of TMP fibers. However, it was also shown that excessive and prolonged free radical treatment may cause the destruction of fiber phenoxy radicals. In conclusion, this study demonstrates the potential for application, but also the complexity of free radical chemistry in biological materials, especially with regard to the chelation of transition metals and the interaction between free radicals.     

Darwin's Fox: A Distinct Endangered Species in a Vanishing Habitat

The temperate rain forest of Chiloé Island, Chile, is inhabited by an endemic fox ( Dusicyon fulvipes ) first described by Charles Darwin and now designated Darwin's fox. Despite morphological differences, Darwin's fox has been considered only an insular subspecies of the mainland chilla fox ( D. griseus ). This follows the assumption that the island population, with an estimated population of less than 500, has been separated from the mainland chilla fox for only about 15,000 years and may have received occasional immigrants from the mainland. Consequently, this island population has not been protected as endangered or bred in captivity. Recently, a population of Darwin's fox was discovered on the Chilean mainland 600 km north of Chiloé Island. This population exists in sympatry with chilla and possibly culpeo ( D. culpaeus ) foxes, which suggests that Darwin's fox may be reproductively isolated. To clarify the phylogenetic position of Darwin's fox, we analyzed 344 bp of mitochondrial DNA control-region sequence of the three species of Chilean foxes. Darwin's foxes from the island and mainland populations compose a monophyletic group distinct from the two other Chilean fox species. This indicates that Darwin's fox was probably an early inhabitant of central Chile, and that its present distribution on the mainland may be a relict of a once much wider distribution. Our results highlight the ability of molecular genetic techniques to uncover historical relationships masked by recent events, such as local extinctions. The "rediscovery" of Darwin's fox as a distinct species implies that greater significance should be given to the protection of this species and its unique habitat and to documenting the extent of its mainland distribution.     

Nitrous oxide (N2O) emissions from waste and biomass to energy plants.

Following the Kyoto protocol with respect to reducing emissions of greenhouse gases emissions, and EU energy policy and sustainability in waste management, there has been an increased interest in the reduction of emissions from waste disposal operations. From the point of view of nitrous oxide (N2O) emissions, waste incineration and waste co-combustion are very acceptable methods for waste disposal. In order to achieve very low N2O emissions from waste incineration, particularly for waste with higher nitrogen content (e.g. sewage sludge), two factors are important: temperature of incineration over 900 degrees C and avoiding the selective non-catalytic reduction (SNCR) de-NO(X) method based on urea or ammonia treatments. The more modern selective catalytic reduction (SCR) systems for de-NO(X) give rise to negligible sources of N2O.     

Tennessee Valley Authority's Clean Water Initiative: Building Partnerships for Watershed Improvement

River Action Teams at the Tennessee Valley Authority are working with other government agencies, universities, landowners, and businesses and industries - by watersheds and often across state boundaries - to clean up the Tennessee River system. Teams collect data about water resource conditions and develop co-operative projects to protect unique resources and solve high priority pollution problems.