Remediation of BTEX and trichloroethene

The widespread use of industrial chemicals in our highly industrialized society has often caused contamination of large terrestrial and marine areas due to the deliberate and accidental release of organic pollutants into the soil and groundwater. In this review, environmental problems arising from the use of chlorinated solvents and BTEX compounds are described, and an overview about active management strategies for remediation with special emphasis on phytoremediation are presented to achieve a reduction of the total mass of chlorinated solvents and BTEX compounds in contaminated areas. Phytoremediation has been proposed as an efficient, low-cost remediation technique to restore areas contaminated with chlorinated solvents and BTEX compounds. The feasibility of phytoremediation as a remediation tool for these compounds is discussed with particular reference to the uptake and metabolism of these compounds, and a future perspective on the use of phytoremediation for the removal of chlorinated solvents and BTEX compounds is given.     

The contribution from shipping emissions to air quality and acid deposition in Europe

A global three-dimensional Lagrangian chemistry-transport model STOCHEM is used to describe the European regional acid deposition and ozone air quality impacts along the Atlantic Ocean seaboard of Europe, from the SO2, NOx, VOCs and CO emissions from international shipping under conditions appropriate to the year 2000. Model-derived total sulfur deposition from international shipping reaches over 200 mg S m(-2) yr(-1) over the southwestern approaches to the British Isles and Brittany. The contribution from international shipping to surface ozone concentrations during the summertime, peaks at about 6 ppb over Ireland, Brittany and Portugal. Shipping emissions act as an external influence on acid deposition and ozone air quality within Europe and may require control actions in the future if strict deposition and air quality targets are to be met.     

Paying for information: partial loads in central place foragers

Information about food sources can be crucial to the success of a foraging animal. We predict that this will influence foraging decisions by group-living foragers, which may sacrifice short-term foraging efficiency to collect information more frequently. This result emerges from a model of a central-place forager that can potentially receive information on newly available superior food sources at the central place. Such foragers are expected to return early from food sources, even with just partial loads, if information about the presence of sufficiently valuable food sources is likely to become available. Returning with an incomplete load implies that the forager is at that point not achieving the maximum possible food delivery rate. However, such partial loading can be more than compensated for by an earlier exploitation of a superior food source. Our model does not assume cooperative foraging and could thus be used to investigate this effect for any social central-place forager. We illustrate the approach using numerical calculations for honeybees and leafcutter ants, which do forage cooperatively. For these examples, however, our results indicate that reducing load confers minimal benefits in terms of receiving information. Moreover, the hypothesis that foragers reduce load to give information more quickly (rather than to receive it) fits empirical data from social insects better. Thus, we can conclude that in these two cases of social-insect foraging, efficient distribution of information by successful foragers may be more important than efficient collection of information by unsuccessful ones.     

PROBLEMS IN WEIGHTING OF HYETOGRAPHS1

ABSTRACT: It was found that the conventional weighting factor application to hyetograph ordinates results in artificially attenuated storm patterns. A modified weighting procedure is suggested which allows adjustments in the storm timing, peak intensity, and volume but conserves the storm pattern observed at the raingage nearest to the watershed point of interest. The systematic underestimation of peak flood flows, which result from conventional hyetograph weighting, can be avoided by conserving the hyetograph shape from the raingage nearest to any subarea of a modeled watershed and merely applying weighting factors to the rainfall volumes and temporal center of gravity of several hyetographs.     

Determination of solid-liquid partition coefficients (Kd) for the herbicides isoproturon and trifluralin in five UK agricultural soils

Isoproturon and trifluralin are herbicides of contrasting chemical characters and modes of action. Standard batch sorption procedures were carried out to investigate the individual sorption behaviour of 14C-isoproturon and 14C-trifluralin in five agricultural soils (1.8-4.2% OC), and the soil solid-liquid partition coefficients (Kd values) were determined. Trifluralin exhibited strong partitioning to the soil solid phase (Kd range 106-294) and low desorption potential, thus should not pose a threat to sensitive waters via leaching, although particle erosion and preferential flow pathways may facilitate transport. For isoproturon, soil adsorption was low (Kd range 1.96-5.75) and desorption was high, suggesting a high leaching potential, consistent with isoproturon being the most frequently found pesticide in UK surface waters. Soil partitioning was directly related to soil organic carbon (OC) content. Accumulation isotherms were modelled using a dual-phase adsorption model to estimate adsorption and desorption rate coefficients. Associations between herbicides and soil humic substances were also shown using gel filtration chromatography.     

Eco-labelling: success or failure?

Eco-labelling was identified in Agenda 21 as a way of encouraging consumers to alter their consumption patterns and to make wiser use of resources and energy in the drive for sustainable development into the next century. A European-wide eco-labelling scheme was introduced by the European Commission (EC) in 1992 as part of its fifth and most recent Environmental Action Plan, the focus of which is also sustainability. The EC eco-labelling scheme aims to promote products with reduced environmental impacts throughout their life cycle and to provide consumers with better information about the environmental impact of products. This paper assesses whether eco-labelling is an effective means of improving the environment, using the eco-labelling of paper products as a case study. Paper products are examined because the development of their ecolabelling criteria has been a particularly complex and contentious issue. Moreover, although criteria have now been adopted for three groups of paper products, controversy has dominated the criteria-setting process and debate continues about the relevance of the selected criteria. It is concluded that while the concept of eco-labelling is good, the practical application of the concept is not straightforward. Furthermore, at present, there is little evidence of eco-labelling benefitting the environment.     

Channel change,sediment transport,and fish habitat in a coastal stream: Effects of an extreme event

A study on sediment transport and channel change was conducted on Zayante Creek and the lower San Lorenzo River in Santa Cruz County, California. A rainstorm with a recurrence interval locally in excess of 150 years occurred during the study year, 1982 WY. Stream surveys indicated that significant aggradation occurred during and after the peak flood. Upper study reaches were substantially recovered after high flows of early April, but the lower study reaches still had significant filling of pools and burial of riffles by sand. Increases in width-depth ratio were minor and localized in upper reaches, but were significant in lower reaches. Large inputs of sand, primarily from landsliding, altered the sediment transport regime. A higher proportion of the bedload is now transported by lower flows than before the January event. Roads and sand quarries contributed significantly to sediment input to the stream. A proposed dam may alter the sediment transport regime of Zayante Creek. Mitigating the effects of this dam on downstream fish habitat may require occasional bankfull discharges.     

Environmental influences on the distribution of the incidence of cholera: a case study in quelimane, mozambique

Cholera continues to cause widespread suffering in many parts of the world. Previous research has mainly described modes of transmission and has correctly indicated the role of predisposing socio-economic conditions in affected areas. Little field research has been carried out, however, in endemic zones, on the contribution of physical characteristics in environmental reservoirs which prolong the survival time or increase the toxigeneity of Vibrio cholerae 01, despite substantial indication of their significance at laboratory scale. A study carried out in Quelimane, Mozambique, to test for such environmental influences on the spatial and temporal distribution of cholera incidence, is described. The role of population displacement in this relationship is also discussed. The practical implications of the results for prevention of primary infection and subsequent reinfection are outlined.     

Climatic Variation and Solute Concentration and Flux in Meltwaters Draining from an Alpine Glacier

Measurements of electrical conductivity and discharge ofmeltwaters in the Gornera, which drains from the 83%glacierised basin containing Gornergletscher, PennineAlps, Switzerland, were undertaken between May andSeptember in both 1979 and 1998. Discharge in theGornera was 43% higher in 1998, average air temperatureduring the ablation season being 2.1 °C warmer andpreceding winter precipitation 28% lower than in 1979. Mean electrical conductivity of meltwater in 1998 wasreduced by 40%. In the same 60 day period in 1998,however, solute flux was augmented by only 2% bycomparison with 1979. Year-to-year climatic variations,reflected in discharge variability, strongly affectsolute concentration in glacial meltwaters, but havelimited impact on solute flux. Climatic conditionstranslate into meltwater quality through inter-relationships between mineral reaction rates, subglacialresidence time in contact with sediment, and discharge. Annual variability in solute flux depends on the extentto which volume of flow can offset decline in soluteconcentration brought about by reducing residence time.