养殖废水中9种大环内酯及林可酰胺类抗生素的同时测定及分析方法研究

采用固相萃取-超高效液相色谱三重四极杆质谱联用法,建立了同时测定养殖废水中9种大环内酯及林可酰胺类抗生素的方法,并对样品pH值、保存时间、洗脱溶剂、上样流速及过滤材质等进行了优化。测定结果表明,pH值为6,过滤材质为聚丙烯（GHP）,上样速度为5 mL/min时,9种抗生素的加标回收率最优,为71.4%～126%,相对标准偏差最小,为2.4%～7.1%,标准曲线的线性最好,相关系数为0.998 5～0.999 5,检出限为0.78～1.22 ng/L。该方法灵敏度高、检出限低、测定结果准确,能够广泛应用于养殖废水中大环内酯及林可酰胺类抗生素残留量的监测分析。     

原位铁氧化物载铁活性炭的制备及其对水中As(Ⅲ)的去除性能

针对水中三价砷As(Ⅲ)毒害大、难去除的问题,本研究采用FeSO4/K2FeO4组合处理方式以恒温浸润法对活性炭进行改性,制备获得原位铁氧化物载铁活性炭(AFPAC),利用负载的铁氧化物的吸附性能,耦合活性炭的吸附和有效的固液分离功能,实现了As(Ⅲ)的高效去除.结果表明,当AFPAC投加量1g·L-1时,对初始质量浓...     

WRF模式中城市冠层参数化方案在重庆气象环境模拟中的性能比较

目前,耦合在WRF模式中的城市冠层方案包括单层冠层方案（UCM）、多层冠层方案(BEP)以及考虑室内外大气能量交换的多层冠层方案(BEP+BEM)。以2006年高温伏旱天气为背景,典型的拥有高密建筑物的山地城市重庆为研究对象,采用高分辨率的GIS数据替换USGS地形数据,对WRF中的3种城市冠层方案进行了两天的模拟。结果表明：（1）在不采用城市冠层方案时模拟的气温场和风场效果较差,2 m气温模拟值与观测值的均方差达到32℃;（2）在10个城市站点2 m气温的模拟中,BEP+BEM、BEP、UCM方案与观测值的模拟值与观测值的均方差为13℃、14℃、21℃,UCM方案相对较差,BEP+BEM方案最好;（3）在10 m风速的模拟中,单层方案结果偏大,两种多层方案与观测值有较好的一致性,二者差别较小。3种方案都能模拟出大致的风向     

Local Area Quotas for Industrial Emissions along Reaches of the Pearl River in Guangdong

Abstract

There is an obvious departure from the regional equilibrium of developments between the upper and lower reaches of the Pearl River in Guangdong, which resulted in “the effects of contra-geography-grads development”. It is mainly because the upriver mountainous areas have been deeply stuck in industrialization delay and marginalization plights, so that nearly 40 million local people have conceived a dream to get rid of “the vicious circle of poverty” by speeding up industrial development. But the problem is that such industrialization efforts on a large scale in mountainous areas are encountering the bottleneck of environmental capacity that strictly limits industrial emissions along the upper reaches of any water system. As a solution, an institutional arrangement called “the Local Area Quotas for Industrial Emis-sions along the Pearl River” is put forward supposed to give corresponding compensation to the rights of industrial development yielded by some areas with lower environmental capacity through the distribution and trading of IDQs.     

Mg-La-Fe/沸石复合材料的制备及其处理低浓度含磷废水的性能

以沸石为载体,选用镁、镧和铁为改性剂,采用水热法制备了一种新型高效且易于磁性分离回用的载镧磁性沸石吸附剂（MLFZ）.等温吸附和动力学研究结果表明,其吸附行为符合Langmuir等温模型和准二级动力学模型,MLFZ饱和吸附量为13.46 mg·g^-1; MLFZ在pH为3～9范围内均表现出良好的吸附性能,共存离子条件下对磷酸根具有特异吸附能力,通过磁性吸附重复使用5次后,MLFZ对磷酸盐去除率维持在90%左右,突显了其易于回收再利用的优点;FTIR、 XPS和Zeta电位表征显示,表面沉积、静电吸附作用和镧与磷酸盐通过配体交换形成内层络合物在吸附过程中为主要作用.将MLFZ用于处理自然池塘污水,结果显示磷酸盐浓度由0.86 mg·L^-1降低到0.013 mg·L^-1,表明该吸附剂具有良好的实际应用前景.     

保护性耕作对玉米田土壤中除草剂残留的影响

保护性耕作能够显著提高土壤有机质,改善土壤质量,但是关于保护性耕作如何影响农药等污染物在土壤中残留的研究却较为匮乏,而土壤污染又与粮食安全息息相关.因此,选择7个实验地点,针对传统耕作与保护性耕作两种耕作方式下土壤中3种除草剂(乙草胺、阿特拉津和二甲四氯钠)残留特征进行了分析.结果表明,保护性耕作显著影响土壤的总有机碳含量、土壤含水率和土壤团聚体平均粒径等性质[使(2.1±0.1)%、(19.1±1.2)%和(82.2±3.0)μm分别增加至(2.9±0.3)%、(22.3±1.5)%和(97.2±4.2)μm].研究进一步发现,保护性耕作对不同除草剂在土壤中残留的影响存在差异性.例如,保护性耕作通过影响土壤总有机碳含量显著增加东丰试验田土壤中阿特拉津的含量[使(3.8±0.3)ng·g^-1增加至(17.7±3.0)ng·g^-1],通过影响土壤团聚体平均粒径显著降低德惠试验田土壤中乙草胺的含量[使(50.6±10.3)ng·g^-1降低至(9.2±2.5)ng·g^-1].然而,由于不同土壤性质对土壤中...     

Evaluating the effects of alternative forest management plans under various physiographic settings using historical records as a reference

Using historical General Land Office record as a reference, this study employed a landscape-scale disturbance and succession model to estimate the future cumulative effects of six alternative management plans on the tree species composition for various physiographic settings for the Mark Twain National Forest in Missouri. The results indicate that over a 200-year horizon, the relative abundance of black oak and pine species groups will decrease and the relative abundance of the white oak species group will increase, regardless of management strategy. General Land Office witness tree records provide a measure of tree species composition in the period from 1800 to 1850, prior to the large-scale influx of European settlers. Compared to the tree species composition described in the General Land Office records, the six contemporary management alternatives considered all would lead to a lower abundance of pine species, a higher abundance of red/black oak species, and a slightly higher abundance of white oak species after 200 years. Impacts of management on tree species composition varied with physiographic settings. The projected relative abundance of pine differed significantly across the five physiographic classes over the first 40 years of the simulation. In the medium term (simulation years 41-100) the projected relative pine abundance differed significantly among only four physiographic classes. In the long term (simulation years 100-200) the projected relative pine abundance differed for only one physiographic class. In contrast, differences among physiographic classes in the relative abundance of black oaks and white oaks increased over time. In general, the expected long-term differences in relative tree species abundance among six proposed alternative management plans are small compared to shifts in tree species composition that have occurred from 1850 to the present.     

岷江上游流域水电梯级开发的生态环境需水研究

本文通过分析岷江上游水电梯级开发对生态环境的主要影响,确定维持流域生态平衡的最小生态环境需水量测算方法。经测算,岷江上游的生态环境需水量占流域多年平均流量的6%～33%,越靠近源头,生态环境需水量所占比例越大。建议提高岷江上游生态环境需水量所占比例,将生态环境需水占比超过20%的茂县以上河段设为禁止开发区域,取消禁止开发区域内原规划的6级电站。同时在已建电站坝下和各县域出境断面设置生态流量监控断面,确保流域开发的环境生态平衡。     

探析模糊控制无线节点网路技术在石油化工安全中的应用

在石油化工领域,为了有效预防和控制易燃易爆有毒气体的泄漏燃烧爆炸,利用计算机技术和电信通讯网络,处理信息和传输信息,以监测探头、无线接收发模块、监控主计算机三部分构建一套安全预警监控系统。在化工厂或危险源区域的危险点,设置多处监测节点,接受信息传输到无线接收发模块,进行模糊化计算、推理,判断后输出结果到监控主计算机,监控主计算机向安全管理人员、现场工作人员等发出报警信息。     

作业疲劳测量方法对比研究

作业疲劳是导致生产效率下降、事故发生的重要原因之一。研究作业疲劳对提高生产效率、减少事故的发生,以及保护劳动者安全和健康具有重要意义。而作业疲劳测量方法是作业疲劳研究的前提和基础。因此,本文首先对作业疲劳的分类及其导致疲劳的原因进行了简单概述,并归纳总结了目前常用的几种作业疲劳测量方法,包括：主观感觉询问表评价法、生理参数测试法、生物化学测试法、心理学测试方法以及几种方法相结合的综合测试方法,并分析了上述几种作业疲劳测量方法的测量目的、适用范围、以及各自的优缺点,且针对不同研究目的提出了作业疲劳测量方法的选择和使用原则,并探讨了几个重点作业疲劳测量方法的研究方向,以及作业疲劳测量方法的完善方法。