The EU sustainable energy policy indicators framework

The article deals with indicators framework to monitor implementation of the main EU (European Union) directives and other policy documents targeting sustainable energy development. The main EU directives which have impact on sustainable energy development are directives promoting energy efficiency and use of renewable energy sources, directives implementing greenhouse gas mitigation and atmospheric pollution reduction policies and other policy documents and strategies targeting energy sector. Promotion of use of renewable energy sources and energy efficiency improvements are among priorities of EU energy policy because the use of renewable energy sources and energy efficiency improvements has positive impact on energy security and climate change mitigation. The framework of indicators can be developed to establish the main targets set by EU energy and environmental policies allowing to connect indicators via chain of mutual impacts and to define policies and measures necessary to achieve established targets based on assessment of their impact on the targeted indicators representing sustainable energy development aims. The article discusses the application of indicators framework for EU sustainable energy policy analysis and presents the case study of this policy tool application for Baltic States. The article also discusses the use of biomass in Baltic States and future considerations in this field.     

Ecotoxicological risk assessment of pentachlorophenol,an emerging DBP to plants: evaluation of oxidative stress and antioxidant responses

Environmental Science and Pollution Research - Chlorophenols are not only noticed in an effluvium of industries but also can emerge from the water treatment plants for domestic supply which poses a...     

‘Effortless Perfection:’ Do Chinese cities manipulate air pollution data?

This paper uses unique data on daily air pollution concentrations over the period 2001–2010 to test for manipulation in self-reported data by Chinese cities. First, we employ a discontinuity test to detect evidence consistent with data manipulation. Then, we propose a panel matching approach to identify the conditions under which irregularities may occur. We find that about 50% of cities reported dubious PM₁₀ pollution levels that led to a discontinuity at the cut-off. Suspicious data reporting tends to occur on days when the anomaly is least detectable. Our findings indicate that the official daily air pollution data are not well behaved, which provides suggestive evidence of manipulation.     

Effect of hydrogen sulfide in comparison to atorvastatin on endothelial damage in cholesterol-fed rabbits

Hydrogen sulfide (H₂S) is an endogenous gaseous molecule, functioning as a physiological regulator. This study aimed to investigate the role of H₂S in atherosclerosis. Rabbits receiving high cholesterol were given atorvastatin (10 mg/kg/day, orally) or sodium sulfide (1.1 mg/kg/day, intramuscular) 2 weeks after commencement of high-cholesterol diet and continued for 4 weeks. Serum lipid profiles, lipid peroxidation indexed as malondialdehyde, glutathione, superoxide dismutase, the vascular adhesion molecule-1, and aortic vascular endothelial growth factor were determined. Rabbits receiving a high-cholesterol diet showed elevated levels of total serum cholesterol, triglycerides, low-density lipoprotein cholesterol, malondialdehyde and vascular adhesion molecule-1, and aortic vascular endothelial growth factor expression and lower levels of high-density lipoprotein cholesterol, glutathione, and superoxide dismutase. Treatment with atorvastatin and sodium sulfide has beneficial effects on serum lipid profile, oxidative damage, vascular adhesion molecule-1, and aortic expression of vascular endothelial growth factor.     

Morphological,physiological, and genotoxic effects of heavy metal bioaccumulation in Prosopis laevigata reveal its potential for phytoremediation

Environmental Science and Pollution Research - Mining industry generates large volumes of waste known as mine tailings, which contain heavy metals (HMs) that generate a risk to environmental...     

Changes in precipitation chemistry in Lithuania for 1981-2004

This paper considers the spatial and temporal variability in concentrations of the potentially acidifying ions in precipitation in Lithuania during the 1981-2004 period. Chemical analysis of precipitation included measurements of pH, conductivity, sulfate (SO4(2-)), nitrate (NO3-), chloride (Cl-), ammonium (NH4+), sodium (Na+), potassium (K+), and calcium (Ca2+). Temporal trends in the potentially acidifying ion concentrations in precipitation and wet deposition were evaluated using the non-parametric Mann-Kendall test and Sen's slope estimator. A statistically significant decline was observed in non-sea salt sulfate (nssSO4(2-)) and hydrogen (H+) ions concentrations (82% and 79%, respectively) and wet depositions (88% and 74%, respectively). Temporal trends both in concentration and wet deposition of nitrate and ammonium were not as pronounced as trends in sulfate concentration. Analysis of air mass backward trajectories was applied to reveal the influence of air mass originating in different regions on wet deposition of acidifying species in Lithuania. Sector analysis clearly showed that wet deposition of sulfur and nitrogen in Lithuania is to a large extent anthropogenic and the main source regions of acidifying species contributing to wet deposition in Lithuania are in South and Central Europe.     

Single drop microextraction and gas chromatography–mass spectrometry for the determination of diflufenican, mepanipyrim, fipronil, and pretilachlor in water samples

An analytical method for the determination of diflufenican, mepanipyrim, pretilachlor, and fipronil in water samples was developed using single drop microextraction in the direct immersion mode and gas chromatography–mass spectrometry. A factorial fractionated design of type 2^6–1 at two levels was performed, to study the influence of experimental variables such as ionic strength, pH, agitation speed, extraction time, drop volume, and sample volume. To establish the optimal conditions for the variables that were significant, a Doehlert design was performed. The optimum conditions of extraction were 1 μL of heptane immersed in 4.0 mL of sample with continuous agitation at 500 rpm for 30 min at room temperature. The developed method proved to have good linearity for the range studied. The detection limits were 0.07 μg L^?1 for diflufenican, 0.03 μg L^?1 for mepanipyrim, 0.08 μg L^?1 for pretilachlor, and 1.39 μg L^?1 for fipronil. The method was validated on river water samples, showing the absence of matrix effect and recoveries ranged from 90.1 to 107.8 %. The results show that the method developed is accurate, sensitive, rapid, simple, and low cost, so it is recommended for application in the analysis of these different classes of pesticides in water samples.     

Constant light exposure and/or pinealectomy increases susceptibility to trichloroethylene-induced hepatotoxicity and liver cancer in male mice

Environmental Science and Pollution Research - Exposure to light at night, pineal gland impairment, and the environmental pollutant trichloroethylene (TCE) have serious implications for health and...     

Sulfonated cross-linked polyethylenimine for selective removal of mercury from aqueous solutions

Polymeric materials are among the most promising, effective, and increasingly important adsorbents for the removal of toxic metals from wastewater. This study was dedicated to the development of an insoluble, modified chelating polymer for use as an adsorbent for abstraction of Hg from aqueous solutions. Cross-linked polyethylenimine (CPEI) was sulfonated by 3-chloropropanesulfonyl chloride for selective removal of Hg. The binding affinity of the sulfonated CPEI (SCPEI) to Hg was assessed as well as its ability to be regenerated for reuse. It exhibited high removal percentage for Hg up to 87% in synthetic solutions, with high selectivity even in the presence of competing ions: “Mn, Ni, Fe, Pb, Zn, and Cr.” The removal mechanism followed was observed to be adsorption and precipitation at pH 3 and 8, respectively. High adsorption capacities were also observed for wastewater to which the polymer was applied. The Freundlich isotherm was found to be the best fit describing the adsorption process of Hg onto the SCPEI. The pseudo second-order equation was found to better explain the adsorption kinetics, implying chemisorption. The thermodynamic study of the adsorption revealed high activation energies which confirmed the chemisorption as the mechanism of adsorption. The polymer exhibited up to 72% removal efficiency after regeneration, thus showing potential for re-use.