SEASONAL PUMPING VARIATION EFFECTS ON WELLHEAD PROTECTION AREA DELINEATION1

ABSTRACT: Delineation of a welihead protection area (WHPA) is the key element in welihead protection programs for drinking water supplies. WHPAs are often delineated under idealized conditions using simple steady-state assumptions, which lead to an incorrect estimation of area and geometry. In this paper, we compare the results from a simple steady-state procedure commonly employed in WHPA delineation with a more complex transient approach that allows consideration of seasonal variation in pumping rates. We also introduce a transient procedure to delineate time-related capture zones using a numerical ground water flow and transport model. Welihead delineation is examined for two municipal wells in Tipton, Oklahoma, using a ten-year time-of-travel criterion. In the steady-state procedure, where we assumed constant pumping rates, we used GPTRAC, a semi-analytical model, and MOC, a numerical model. The capture zone delineated by GPTRAC is comparable in shape with the capture zone delineated by MOC but not in size due to the differences in solution schemes. In the transient procedure, we used MOC and considered the seasonal variation in pumping rates. The capture zones delineated in this procedure were larger than the capture zones delineated by the steady-state procedure using the same model. Further analysis showed that a higher drawdown was predicted in the transient procedure than in the steady-state procedure, which is the reason for larger capture zones.     

SO2排污权交易在中国的发展与挑战

回顾了大气污染物排放总量控制和排污权交易在中国发展的历程.通过对美国SO2排放总量控制和排污权交易核心要素的分析,揭示了目前中国在排污权交易政策方面的欠缺.指出了排污权交易政策是帮助中国完成"十一五"计划环境目标的有效手段.     

UN/ECE ICP Materials Dose-response Functions for the Multi-pollutant Situation

A “multi-pollutant exposure programme” reflecting the new pollution situation where SO₂ is no longer the dominating pollutant has been performed by the International Co-operative Programme on Effects on Materials, including Historic and Cultural Monuments (ICP Materials) within the activities of the Convention on Long-range Transboundary Air Pollution. The main results obtained in the period 1997–2003 are summarised. Dose-response functions are presented for carbon steel, zinc, copper, bronze and limestone. Parameters involved in the functions include besides SO₂ and pH, which were included in the previously developed functions from ICP Materials, also the effect of particulate matter and HNO₃.     

硝酸及氯离子对高温硝酸铵水溶液热危险性的影响研究

国内外学者对硝酸铵的危险性进行了大量的研究,而对其水溶液的危险性至今开展不多。笔者采用差示扫描量热仪(DSC)及全自动反应量热仪(RC1e)对高温状态下的硝酸铵水溶液的热分解危险性、杂质离子对其稳定性的影响进行了研究。纯硝酸铵和90%硝酸铵水溶液的DSC实验表明,90%硝酸铵溶液和分析纯硝酸铵具有相似的热爆炸危险;90%硝酸铵水溶液在140~180℃之间的RC1e试验表明:硝酸或氯离子单独存在时,对硝酸铵分解都有不同程度的抑制作用,而同时存在时则大大降低体系的热稳定性。该结果对保障硝酸铵在生产、使用过程中的安全具有重要的参考价值。     

A phytoremediation study: Selection of tropical and other vascular plants for decolorization of Poly R‐478 dye

Peroxidases and other lignin‐degrading enzymes and chemicals can potentially degrade persistent pollutants. Fifty vascular plant species were hydroponically tested for the capability of decolorization of Poly R‐478, a lignolytic indicator dye. The top six species that had less than 50 percent of control color at the end of the experiments were Pennisetum purpureum, Rumex crispus, Fimbristylis cymosa, Eleocharis calva, Hibiscus furcellatus, and Cyperus javanicus, in an order from high to low decolorization activity. F. cymosa, E. calva, and C. javanicus are in the Cyperaceae family. Extracellular peroxidase activity was found in vascular plants and correlated to decolorization of polymeric dyes. The plant R. crispus provided the highest guaiacol peroxidase enzyme activity among four of the top six plant species. The Poly R‐478 decolorization could be used as a fast screening technique for vascular plants that may have phytoremediation capability. © 2006 Wiley Periodicals, Inc.     

Organophosphate flame retardants and plasticizers in indoor air

Analytical methods were developed for a broad range of organophosphate flame retardants and plasticizers in indoor air. Screening was performed of various indoor environments at 12 locations in and around Zurich, Switzerland. Method recoveries ranged from 62% for triphenyl phosphate to 100% for tris(2-ethylhexyl) phosphate. Tris(2-chloro-isopropyl) phosphate was found in the highest concentration (260 ng/m(3)) mainly in cars and furniture stores. Tris(2-ethylhexyl) phosphate and triphenyl phosphate, both up to 3.4 ng/m(3), were also detected in quantifiable concentrations at several sites. Tris(1,3-dichloroisopropyl) phosphate, tricresyl phosphate and tri(2-butoxyethyl) phosphate were below the limit of quantification in all samples. The results of the risk assessment indicate that the observed concentrations are below the predicted threshold for human health effects.     

Measuring visual opacity using digital imaging technology

The U.S. Environmental Protection Agency (EPA) Reference Method 9 (Method 9) is the preferred enforcement approach for verifying facility compliance with federal visible opacity standards. Supporters of Method 9 have cited its flexibility and low cost as important technological and economic advantages of the methodology. The Digital Opacity Compliance System (DOCS), an innovative technology that employs digital imaging technology for quantifying visible opacity, has been proposed as a technically defensible and economically competitive alternative to Method 9. Results from the field application of the DOCS at EPA-approved Method 9 smoke schools located in Ogden, UT, Augusta, GA, and Columbus, OH, demonstrated that, under clear sky conditions, the DOCS consistently met the opacity error rate established under Method 9. Application of hypothesis testing on the smoke school data set confirmed that the DOCS was equivalent to Method 9 under clear sky conditions. Under overcast sky conditions, human observers seemed to be more accurate than the DOCS in measuring opacity. However, within the smoke school environment, human observers routinely employ backgrounds other than sky (e.g., trees, telephone poles, billboards) to quantify opacity on overcast days. Under conditions that compel the use of sky as plume background (e.g., emission stacks having heights above the tree line), the DOCS appears to be a more accurate methodology for quantifying opacity than are human observers.