Chemical mass balance source apportionment for combined PM2.5 measurements from U.S. non-urban and urban long-term networks

The Minnesota Particulate Matter 2.5 (PM_2.5) Source Apportionment Study was undertaken to explore the utility of PM_2.5 mass, element, ion, and carbon measurements from long-term speciation networks for pollution source attribution. Ambient monitoring data at eight sites across the state were retrieved from the archives of the Interagency Monitoring of Protected Visual Environments (IMPROVE) and the Speciation Trends Network (STN; part of the Chemical Speciation Network [CSN]) and analyzed by an Effective Variance – Chemical Mass Balance (EV-CMB) receptor model with region-specific geological source profiles developed in this study. PM_2.5 was apportioned into contributions of fugitive soil dust, calcium-rich dust, taconite (low grade iron ore) dust, road salt, motor vehicle exhaust, biomass burning, coal-fired utility, and secondary aerosol. Secondary sulfate and nitrate contributed strongly (49–71% of PM_2.5) across all sites and was dominant (≥60%) at IMPROVE sites. Vehicle exhausts accounted for 20–70% of the primary PM_2.5 contribution, largely exceeding the proportion in the primary PM_2.5 emission inventory. The diesel exhaust contribution was separable from the gasoline engine exhaust contribution at the STN sites. Higher detection limits for several marker elements in the STN resulted in non-detectable coal-fired boiler contributions which were detected in the IMPROVE data. Despite the different measured variables, analytical methods, and detection limits, EV-CMB results from a nearby IMPROVE-STN non-urban/urban sites showed similar contributions from regional sources – including fugitive dust and secondary aerosol. Seasonal variations of source contributions were examined and extreme PM_2.5 episodes were explained by both local and regional pollution events.     

Overcoming latecomer disadvantage through learning processes: Taiwan’s venture into wind power development

Research into national innovation systems (NISs) has received extensive academic and policy attention, and is especially relevant with latecomer countries seeking to innovate in challenging industrial environments. In playing catch up with their early industrializing counterparts, methods of learning take on increased importance in determining industrial success for latecomers. The wind turbine technology innovation system is one that is highly dependent on both the extent of the national learning processes and the strength of the national social-institutional setting. This research investigates the case of Taiwan, a country which has embarked on a program to build its national innovative capacity in wind turbine technologies with specific emphasis on Taiwan’s social sector. Within this system, the spotlight will be on four types of learning processes that interplay during wind turbine development: learning by searching, learning by doing, learning by using, and learning by interacting. Through a case study of the emergence of Taiwan’s burgeoning large-scale wind power technology initiatives, the paper aims to add to the understanding on how methods of learning impact upon the success of innovation systems. The findings show that the industry’s future prospects are constrained because of the limited learning by interacting processes between turbine component producers, turbine owners, and researchers and because of weaknesses in the institutional framework. This research also recognizes the importance that culture has on dominant forms of learning.     

Sex-specific predation on two lizard species by kestrels

Sex-biased predation is thought to have important implications for sexual selection, sex allocation, and population dynamics (Magnhagen, 1991; Le-Galliard et al., 2005 for an example in lizards). Most studies found that males are subjected to higher predation pressure than females during the reproductive season (Korpimäki, 1985; Lodé et al., 2004; Christe et al., 2006; Costantini et al., 2007). In that period, males are very mobile, emit acoustic signals and exhibit brilliant colourations, which are needed to attract females but may make them more visible to predators. With regard to lizards, a recent study provided the first evidence that males of a lizard species may be preyed on more than females (Costantini et al., 2007). In the present study, we investigated whether there is sex-biased predation on two small lacertid species, the common wall lizard Podarcis muralis (Laurenti, 1768) and the Italian wall lizard Podarcis sicula (Rafinesque-Schmaltz, 1810), by Eurasian kestrels (Falco tinnunculus) during the reproductive season. We also examined whether (1) the rate of predation differed between species and (2) the rate of predation differed across years or among hunting habitats for each species.     

Compositional changes of crude oil SARA fractions due to biodegradation and adsorption on colloidal support such as clays using Iatroscan

The compositional changes of saturates, aromatics, resins and asphaltenes (SARA) fractions in aqueous clay/oil microcosm experiments with a hydrocarbon-degrading microorganism community were analysed using Iatroscan. The clay mineral samples used in this study were organomontmorillonite, acid-activated montmorillonite and K, Ca, Zn and Cr montmorillonites produced by modifying the original montmorillonite sample. The evaluation and quantification of biodegradation and adsorption were carried out using a combination of the Iatroscan and gravimetric analysis. The SARA compositions in the presence of organomontmorillonite and acid-activated montmorillonite after incubation follow the same pattern in which the aromatic fraction is higher than the other fractions unlike in the presence of unmodified, K, Ca and Zn montmorillonites, where the saturates fraction is higher than the other fractions. Changes in SARA fractions due to biodegradation seemed to occur most in the presence of unmodified and calcium montmorillonites; hence, the removal of SARA fractions due to biodegradation was significant and enhanced in the presence of these two clay samples. However, biodegradation in the presence of organomontmorillonite and acid-activated and Cr montmorillonites was hindered. The study indicated that Cr montmorillonite adsorbed resins most, whereas Zn and K montmorillonites adsorbed aromatics most after incubation.     

Observations of mercury wet deposition in Mexico

We provide a longer-term record of Hg wet deposition at two tropical latitude monitoring sites in Mexico, selected to provide regionally representative data. Weekly wet deposition samples were collected over 2 years, from September 2003 to November 2005. Based on this data set, we discuss the magnitude and seasonal variation of Hg in wet deposition and compare the results to other measurement sites and to several model estimates. With precipitation-weighted mean (PWM) concentrations of 8.2 and 7.9 ng L^?1, respectively, during the sampling period from Sep 30 2003 to Oct 11 2005, and median weekly concentrations of 9.4?±?1 ng L^?1 for both sites, the wet Hg concentrations and deposition at HD01 were much lower than those observed at the US Gulf Coast MDN sites while the wet Hg deposition at OA02 was much lower than most MDN sites, but somewhat similar to US MDN sites along the Pacific Coast. Based on the limited available data, we conclude that the approximately 30 % higher average precipitation at HD01 and roughly equal PWM concentrations lead to the higher deposition at HD01 versus OA02. We believe that these observations may offer scientists and modelers additional understanding of the depositional fluxes in the lower latitudes of North America.     

Conceptual and Numerical Modeling of Radionuclide Transport and Retention in Near-Surface Systems

Scenarios of barrier failure and radionuclide release to the near-surface environment are important to consider within performance and safety assessments of repositories for nuclear waste. A geological repository for spent nuclear fuel is planned at Forsmark, Sweden. Conceptual and numerical reactive transport models were developed in order to assess the retention capacity of the Quaternary till and clay deposits for selected radionuclides, in the event of an activity release from the repository. The elements considered were carbon (C), chlorine (Cl), cesium (Cs), iodine (I), molybdenum (Mo), niobium (Nb), nickel (Ni), radium (Ra), selenium (Se), strontium (Sr), technetium (Tc), thorium (Th), and uranium (U). According to the numerical predictions, the repository-derived nuclides that would be most significantly retained are Th, Ni, and Cs, mainly through sorption onto clays, followed by U, C, Sr, and Ra, trapped by sorption and/or incorporation into mineral phases.     

Insights into the dissolution and the three-dimensional structure of insensitive munitions formulations

Two compounds, 2,4-dinitroanisole (DNAN) and 3-nitro-1,2,4-triazol-5-one (NTO) are the main ingredients in a suite of explosive formulations that are being, or soon will be, fielded at military training ranges. We aim to understand the dissolution characteristics of DNAN and NTO and three insensitive muntions (IM) formulations that contain them. This information is needed to accurately predict the environmental fate of IM constituents, some of which may be toxic to people and the environment. We used Raman spectroscopy to identify the different constituents in the IM formulations and micro computed tomography to image their three-dimensional structure. These are the first three-dimensional images of detonated explosive particles.     

Carbon Monoxide and Lead-An Environmental Appraisal

Because of the common source, lead and CO values in the atmosphere tend to behave in a similar manner. Thus, diurnal variations in these two pollutants show a pattern related to motor vehicle traffic flow. Also, the exposure to both vary by orders of magnitude with the highest being on the road (in the car) thus setting up special dosage situations. Community sources seem to affect background level at least based on fall-off with distance. There may be a relatively wider exposure of the general population to lead and CO. While the lead levels may not be increasing in the downtown portion of the central city proper, typical central city levels of several years ago may be more diffuse and spread out, thus occurring over increasingly large portions of the community. Similarly, there may be a wider exposure of the population to CO as the levels become more nearly uniformly high over a larger area. In addition, there may be problems of a shorter term exposure to high levels of CO in commuter traffic. This may be of consequence to selected types of drivers or passengers. Finally, it should also be noted that during air pollution episodes, CO levels appear to rise with no data currently available on changes in concomitant ambient lead levels.     

Forecasting COH Levels at Six Outlying Sampling Stations in Allegheny County Using Statistical Correlations Derived from the Downtown Station

Verification of forecasts of COH levels at the Downtown Sampling Station using our objective forecast method developed in conjunction with the Allegheny County Bureau of Air Pollution Control gave excellent results. The next step was to expand the area of forecast coverage.

COH data taken from July 1968 through June 1969 from six sampling stations located roughly in a large concentric arc around the Downtown Station were studied. Three of the stations are located in river valleys near large industrial plants and the other three are located on higher terrain in suburban areas.

COH levels of Low, Moderate, High, and Very High (where Low = 0–0.9, Moderate = 1.0–1.9, High = 2.0–3.0, and Very High = >3.0) were used.

The total number of occurrences of High and Very High COHS at the Downtown Station was 10.7% of the total data sample. This was more than twice the frequency of any of the outlying stations.

An evaluation of the statistical frequencies indicate the Downtown Station can safely be used as a “control station” in forecasting Low or Moderate COH levels for the six surrounding stations. However, the occurrence of High or Very High COH levels at the six outlying stations do not occur with a high enough statistical consistency to be predicted by using the forecast value of the Downtown Station.

The valley stations exhibit the characteristics of separate sub air basins particularly during a period in which morning inversions occur for two or more consecutive days and the average daily wind speed does not exceed 4 m/sec.

The results show it is possible to forecast only Low or Moderate COH levels for each of the six outlying stations by using statistical correlations derived from the Downtown Station. Separate objective forecasts which relate the pollution buildup in each valley sub air basin must be used when High or Very High COHS are forecast at the Downtown Station.     

Tracer Study In an Urban Valley

Results of a series of nighttime tracer experiments conducted during the Autumn of 1966 in the industrialized valley of Johnstown, Pa., are discussed. Quite atypical meteorology and dispersion occur within a classical drainage flow framework. An urban heat island effect is observed creating uniform temperature and wind structures within a layer of air flowing through the valley. Dispersion in the valley at night is comparable to that of neutral conditions over open country.