Assessments of contaminant-related human and ecological risk require estimation of transport rates, but few data exist on wind-driven transport rates in nonagricultural systems, particularly in response to ecosystem disturbances such as forest wildfire and also relative to water-driven transport. The Cerro Grande wildfire in May of 2000 burned across ponderosa pine (Pinus ponderosa Douglas ex P.&C. Lawson var. scopulorum Englem.) forest within Los Alamos National Laboratory in northern New Mexico, where contaminant transport and associated post-fire inhalation risks are of concern. In response, the objectives of this study were to measure and compare wind-driven horizontal and vertical dust fluxes, metrics of transport related to wind erosion, for 3 yr for sites differentially affected by the Cerro Grande wildfire: unburned, moderately burned (fire mostly confined to ground vegetation), and severely burned (crown fire). Wind-driven dust flux was significantly greater in both types of burned areas relative to unburned areas, by more than one order of magnitude initially and by two to three times 1 yr after the fire. Unexpectedly, the elevated dust fluxes did not decrease during the second and third years in burned areas, apparently because ongoing drought delayed post-fire recovery. Our estimates enable assessment of amplification in contaminant-related risks following a major type of disturbance-wildfire, which is expected to increase in intensity and frequency due to climate change. More generally, our results highlight the importance of considering wind- as well as water-driven transport and erosion, particularly following disturbance, for ecosystem biogeochemistry in general and human and ecological risk assessment in particular. 相似文献
Fresh beef cattle (Bos taurus) manure has traditionally been applied to cropland in southern Alberta, but there has been an increase in application of composted manure to cropland in this region. However, the quality of runoff under fresh manure (FM) versus composted manure (CM) has not been investigated. Our objective was to compare runoff quality under increasing rates (0, 13, 42, 83 Mg ha(-1) dry wt.) of FM and CM applied for two consecutive years to a clay loam soil cropped to irrigated barley (Hordeum vulgare L.). We determined total phosphorus (TP), particulate phosphorus (PP), dissolved reactive phosphorus (DRP), total nitrogen (TN), NH4-N, and NO3-N concentrations and loads in runoff after one (1999) and two (2000) applications of FM and CM. We found significantly (P < or = 0.05) higher TP, DRP, and NH4-N concentrations, and higher DRP and TN loads under FM than CM after 2 yr of manure application. The TP loads were also higher under FM than CM at the 83 Mg ha(-1) rate in 2000, and DRP loads were higher for FM than CM at this high rate when averaged over both years. Application rate had a significant effect on TP and DRP concentrations in runoff. In addition, the slope values of the regressions between TP and DRP in runoff versus application rate were considerably higher for FM in 2000 than for FM in 1999, and CM in both 1999 and 2000. Significant positive relationships were found for TP and DRP in runoff versus soil Kelowna-extractable P and soil water-extractable P for FM and CM in 2000, indicating that interaction of runoff with the soil controlled the release of P. Total P and DRP were the variables most affected by the treatments. Overall, our study found that application of CM rather than FM to cropland may lower certain forms of P and N in surface runoff, but this is dependent on the interaction with year, application rate, or both. 相似文献
Contamination by bacteria is a leading cause of impairment in U.S. waters, particularly in areas of livestock agriculture. We evaluated the effectiveness of several practices in reducing Escherichia coli levels in runoff from fields receiving liquid dairy (Bos taurus) manure. Runoff trials were conducted on replicated hay and silage corn (Zea mays L.) plots using simulated rainfall. Levels of E. coli in runoff were approximately 10(4) to 10(6) organisms per 100 mL, representing a significant pollution potential. Practices tested were: manure storage, delay between manure application and rainfall, manure incorporation by tillage, and increased hayland vegetation height. Storage of manure for 30 d or more consistently and dramatically lowered E. coli counts in our experiments, with longer storage providing greater reductions. Manure E. coli declined by > 99% after approximately 90 d of storage. On average, levels of E. coli in runoff were 97% lower from plots receiving 30-d-old and > 99% lower from plots receiving 90-d-old manure than from plots where fresh manure was applied. Runoff from hayland and cornland plots where manure was applied 3 d before rainfall contained approximately 50% fewer E. coli than did runoff from plots that received manure 1 d before rainfall. Hayland vegetation height alone did not significantly affect E. coli levels in runoff, but interactions with rainfall delay and manure age were observed. Manure incorporation alone did not significantly affect E. coli levels in cornland plot runoff, but incorporation could reduce bacteria export by reducing field runoff and interaction with rainfall delay was observed. Extended storage that avoids additions of fresh manure, combined with application several days before runoff, incorporation on tilled land, and higher vegetation on hayland at application could substantially reduce microorganism loading from agricultural land. 相似文献
Various approaches are used to subdivide large areas into regions containing streams that have similar reference or background
water quality and that respond similarly to different factors. For many applications, such as establishing reference conditions,
it is preferable to use physical characteristics that are not affected by human activities to delineate these regions. However,
most approaches, such as ecoregion classifications, rely on land use to delineate regions or have difficulties compensating
for the effects of land use. Land use not only directly affects water quality, but it is often correlated with the factors
used to define the regions. In this article, we describe modifications to SPARTA (spatial regression-tree analysis), a relatively
new approach applied to water-quality and environmental characteristic data to delineate zones with similar factors affecting
water quality. In this modified approach, land-use-adjusted (residualized) water quality and environmental characteristics
are computed for each site. Regression-tree analysis is applied to the residualized data to determine the most statistically
important environmental characteristics describing the distribution of a specific water-quality constituent. Geographic information
for small basins throughout the study area is then used to subdivide the area into relatively homogeneous environmental water-quality
zones. For each zone, commonly used approaches are subsequently used to define its reference water quality and how its water
quality responds to changes in land use. SPARTA is used to delineate zones of similar reference concentrations of total phosphorus
and suspended sediment throughout the upper Midwestern part of the United States. 相似文献
Affirmative Action Programs (AAPs) are becoming increasingly common in the workplace. Typically their effectiveness has been assessed by the number of women and minorities hired and promoted. A neglected, but important measure of effectiveness is how AAPs are perceived by employees. When employees perceive that AAPs violate notions of fairness, negative attitudes and behaviors may occur and lead to decreased organizational performance. A model of perceived AAP fairness is presented using an organizational justice perspective. An initial (partial) test of the model is conducted and avenues for future research are discussed. 相似文献
In Brazil, specifically in the Doce River basin, there is still a great lack of studies on temporal and spatial trends in water quality, since the water quality in the monitoring campaigns is basically evaluated when it comes down to the concentrations of monitored variables. In this sense, the objective of this work was to perform a temporal and spatial trend analysis of water quality data in the Minas Gerais portion of the Doce River basin, Brazil. For this, the Mann–Kendall, seasonal Mann–Kendall and Spearman correlation tests were used in the temporal analysis and the cluster analysis in the spatial analysis. In the analysis of temporal trends, the analyses were performed using the values of the National Sanitation Foundation Water Quality Index (NSFWQI) and the variables that compose it. In the analysis of spatial trends, the stations were evaluated only based on the WQI. With the results of the analysis of temporal trend, it was identified that most stations did not present a statistically significant trend for the WQI. In the stations that presented trends of quality reduction, most of them are in densely populated areas, demonstrating the strong influence of the poor sanitary conditions of the municipalities to the water quality of the basin. When analyzing the variables that compose the WQI, the results found for nitrate demonstrated that water quality deterioration is also affected by the diffuse pollution originating from farming areas. The results for Escherichia coli reinforced the impact of the discharge of domestic effluents and demonstrated the absence of a significative trend is still of concern because it can represent the maintenance of a degradation state in the water bodies. In the spatial trend analysis, the CA grouped the monitoring stations into six clusters based on their similarity among the WQI values, and, together with the results of the other analyses, it was verified that the Caratinga River basin (UGRH5 Caratinga) presented the highest degree of pollution. It was also possible to identify five stations that can be reallocated or deactivated since they have similarities with other stations located in the same watercourse.
A growing literature has suggested that high performance goals can have unintended consequences within organizations as employees engage in unethical behavior to achieve outcomes associated with goal attainment. Extending research on the dark side of goal setting, we suggest that high performance goals not only create a desire to achieve a particular outcome but also alter moral reasoning processes related to goal attainment. Integrating goal-setting theory with motivated moral reasoning, we hypothesize an indirect effect of high performance goals on unethical behavior via state moral disengagement. We also examine goal commitment—which tends to amplify the relationship between high goals and performance—as a key boundary condition associated with this indirect effect. We build this conditional indirect effect model across three studies conducted in the field and the laboratory. Our results provide new insight into both when and why high goals can facilitate moral disengagement and unethical behavior within organizations. 相似文献
We apply predictive weather metrics and land model sensitivities to improve the Colorado State University Water Irrigation Scheduler for Efficient Application (WISE). WISE is an irrigation decision aid that integrates environmental and user information for optimizing water use. Rainfall forecasts and verification performance metrics are used to estimate predictive rainfall probabilities that are used as input data within the irrigation decision aid. These input data errors are also used within a land model sensitivity study to diagnose important prognostic water movement behaviors for irrigation tool development purposes simultaneously performing the analysis in space and time. Thus, important questions such as “how long can a crop water application be delayed while maintaining crop yield production?” are addressed by evaluating crop growth stage interactions as a function of soil depth (i.e., space), rainfall events (i.e., time), and their probabilistic uncertainties. Editor’s note: This paper is part of the featured series on Optimizing Ogallala Aquifer Water Use to Sustain Food Systems. See the February 2019 issue for the introduction and background to the series.相似文献
A statistical procedure is developed to adjust natural streamflows simulated by dynamical models in downstream reaches, to account for anthropogenic impairments to flow that are not considered in the model. The resulting normalized downstream flows are appropriate for use in assessments of future anthropogenically impaired flows in downstream reaches. The normalization is applied to assess the potential effects of climate change on future water availability on the Rio Grande at a gage just above the major storage reservoir on the river. Model‐simulated streamflow values were normalized using a statistical parameterization based on two constants that relate observed and simulated flows over a 50‐year historical baseline period (1964–2013). The first normalization constant is a ratio of the means, and the second constant is the ratio of interannual standard deviations between annual gaged and simulated flows. This procedure forces the gaged and simulated flows to have the same mean and variance over the baseline period. The normalization constants can be kept fixed for future flows, which effectively assumes that upstream water management does not change in the future, or projected management changes can be parameterized by adjusting the constants. At the gage considered in this study, the effect of the normalization is to reduce simulated historical flow values by an average of 72% over an ensemble of simulations, indicative of the large fraction of natural flow diverted from the river upstream from the gage. A weak tendency for declining flow emerges upon averaging over a large ensemble, with tremendous variability among the simulations. By the end of the 21st Century the higher‐emission scenarios show more pronounced declines in streamflow. 相似文献