Remedial options for chlorinated volatile organics in a partially anaerobic aquifer

A laboratory study was conducted for the selection of appropriate remedial technologies for a partially anaerobic aquifer contaminated with chlorinated volatile organics (VOCs). Evaluation of in situ bioremediation demonstrated that the addition of electron donors to anaerobic microcosms enhanced biological reductive dechlorination of tetrachloroethene (PCE), trichloroethene (TCE), and 1,1,1‐trichloroethane (1,1,1‐TCA) with half‐lives of 20, 22, and 41 days, respectively. Nearly complete reductions of PCE, TCE, 1,1,1‐TCA, and the derivative cis‐dichloroethene were accompanied by a corresponding increase in chloride concentrations. Accumulation of vinyl chloride, ethene, and ethane was not observed; however, elevated levels of ¹⁴CO₂ (from ¹⁴C‐TCE spiked) were recovered, indicating the occurrence of anaerobic oxidation. In contrast, very little degradation of 1,2‐dichloropropane (1,2‐DCP) and 1,1‐dichlorethane (1,1‐DCA) was observed in the anaerobic microcosms, but nutrient addition enhanced their degradation in the aerobic biotic microcosms. The aerobic degradation half‐lives for 1,2‐DCP and 1,1‐DCA were 63 and 56 days, respectively. Evaluation of in situ chemical oxidation (ISCO) demonstrated that chelate‐modified Fenton's reagent was effective in degrading aqueous‐phase PCE, TCE, 1,1,1‐TCA, 1,2‐DCP, etc.; however, this approach had minimal effects on solid‐phase contaminants. The observed oxidant demand was 16 g‐H₂O₂/L‐groundwater. The oxidation reaction rates were not highly sensitive to the molar ratio of H₂O₂:Fe²⁺:citrate. A ratio of 60:1:1 resulted in slightly faster removal of chemicals of concern (COCs) than those of 12:1:1 and 300:1:1. This treatment resulted in increases in dissolved metals (Ca, Cr, Mg, K, and Mn) and a minor increase of vinyl chloride. Treatment with zero‐valent iron (ZVI) resulted in complete dechlorination of PCE, and TCE to ethene and ethane. ZVI treatment reduced 1,1,1‐TCA only to 1,1‐DCA and chloroethane (CA) but had little effect on reducing the levels of 1,2‐DCP, 1,1‐DCA, and CA. The longevity test showed that one gram of 325‐mesh iron powder was exhausted in reaction with > 22 mL of groundwater. The short life of ZVI may be a barrier to implementation. The ZVI surface reaction rates (k_sa) were 1.2 × 10^?2 Lm^?2h^?1, 2 × 10^?3 Lm^?2h^?1, and 1.2 × 10^?3 Lm^?2h^?1 for 1,1,1‐TCA, TCE, and PCE, respectively. Based upon the results of this study, in situ bioremediation appeared to be more suitable than ISCO and ZVI for effectively treating the groundwater contamination at the site. © 2004 Wiley Periodicals, Inc.     

Carbon-14 transfer into rice plants from a continuous atmospheric source: observations and model predictions

Carbon-14 ((14)C) is one of the most important radionuclides from the perspective of dose estimation due to the nuclear fuel cycle. Ten years of monitoring data on (14)C in airborne emissions, in atmospheric CO(2) and in rice grain collected around the Tokai reprocessing plant (TRP) showed an insignificant radiological effect of the TRP-derived (14)C on the public, but suggested a minor contribution of the TRP-derived (14)C to atmospheric (14)C concentrations, and an influence on (14)C concentrations in rice grain at harvest. This paper also summarizes a modelling exercise (the so-called rice scenario of the IAEA's EMRAS program) in which (14)C concentrations in air and rice predicted with various models using information on (14)C discharge rates, meteorological conditions and so on were compared with observed concentrations. The modelling results showed that simple Gaussian plume models with different assumptions predict monthly averaged (14)C concentrations in air well, even for near-field receptors, and also that specific activity and dynamic models were equally good for the prediction of inter-annual changes in (14)C concentrations in rice grain. The scenario, however, offered little opportunity for comparing the predictive capabilities of these two types of models because the scenario involved a near-chronic release to the atmosphere. A scenario based on an episodic release and short-term, time-dependent observations is needed to establish the overall confidence in the predictions of environmental (14)C models.     

Registration of polymers in accordance with directive 67/548/EEC

This paper clarifies how polymers are dealt with under the Directive 67/548/EEC. Polymers are a particular group of substances under the Directive 67/548/EEC [1] and amendments [2,3] as they are not listed in the European INventory of Existing Commercial chemical Substances (EINECS [4]) which otherwise lists all substances which were on the European Community Market between 1 January 1971 and 18 September 1981, the ‘existing substances’. Instead, in EINECS polymers are registered under their ultimate building blocks. With the 6th amendment to the Directive [2] polymers became notifiable substances if containing 2% or more of new substance(s) (i.e. as a general rule substances not listed in EINECS), and the reporting criteria were used as definition. With the 7th amendment to the Directive [3] an exact definition was introduced and a special test package, given in Directive 93/105/EEC [5], was designed for polymers to take into account their particular properties. Changing the definition of polymers created a group of substances which under the 6th amendment had been defined as polymers, and could no longer be regarded as polymers under the 7th amendment, the No‐Longer‐Polymers.     

Air Particulates Associated with the Ash Whitefly

Unusual air particulates are linked to recent heavy infestations of the ash whitefly in California using high-performance liquid chromatography, scanning electron microscopy, optical and infrared microscopy, ion chromatography and X-ray fluorescence spectrometry. The unusual particles apparently are microdroplets of ash whitefly honeydew. Most of the suspended honeydew is in microdroplets with diameters between about two and twenty microns. The microdroplets were found to contain substantial amounts of sugars, primarily the oligosaccharides stachyose and raffinose. They also contain about 1 percent potassium, mainly as K⁺ The unusual microdroplets have been found in samples of air particulates taken in many areas of California after 1988.

Using a receptor model, the suspended honeydew was calculated to add as much as 40 microgm/M³ to PM₁₀ mass. The highest levels of suspended honeydew occurred between late August and early November.     

家庭运输和损耗:食物生命周期中与环境有关的家务活动

在对食物生产系统进行环境相关的系统分析中,消费者阶段(家庭运输、烹制、储存和损耗)是整个食物生命周期中对环境产生影响的一个重要因素.然而,家庭是食物链中调查最少的部分.对家庭信息的收集有很多困难,因为家庭数量庞大,同时与食物相关的活动通常会与其它家务劳动活动混合在一起.环境系统分析和消费者研究两领域研究人员相互合作,通过用问卷、日记和采访面谈的方式调查瑞典的家庭,收集了关于家庭食物运输和损耗的数据.每户每周的平均运输距离是28～63km不等,而这主要依靠怎样分配和其它差事相搭配的运输任务.调制食品时的损耗变化范围是0～34%,而不同类型的食品会有所不同.储存的损耗率为0～164%(因为有更多的食物被扔掉,如对食橱的清理,而不是消费).在调制和储存两阶段中奶制品因损耗少而得分最高.     

EVALUATION OF THE WORTH OF ADDITIONAL DATA1

ABSTRACT .Inherent in every decision process is a certain amount of uncertainty, which is reduced with information. Perfect knowledge yields no uncertainty for a process, but perfect knowledge for hydrologic and water resource systems would require a highly excessive investment. Therefore, it is the aim of this paper to delineate a procedure that places a value on this uncertainty so that it may be compared to a cost of further investment, which would provide a basis for deciding the time at which the value of additional data does not exceed the cost of that data. A decision theory approach is employed on a hydrologic problem to formalize the steps in making a decision. Examples are given.     

Characterization of hydrocarbon pollutant burdens in petrochemical and refinery process streams

This paper describes techniques which provide for both qualitative and quantitative identification of major components in a process stream. The techniques and instrumentation have been deliberately chosen so as to be within the technical and financial reach of all but the smallecompany laboratory. The sample preparation steps consist of an initial series of extractions which isolate compounds into organic acid, base, and neutral compounds and a totally water soluble phase. Each fraction is then concentrated and subjected to thin-layer chromatography, gas chromatography, infrared spectroscopy or ultraviolet spectroscopy as appropriate. Results are given for laboratory samples, one a mixture of aniline, phenol, benzoic acid, m-nitrobenzaldehyde, 1-butanol, 2-hexanone, nonane, and cyclohexane, and the other a mixture of benzene, ethylbenzene, and styrene. Also, a qualitative analysis of a petroleum refinery desalter water is presented.