Characterization of hydrocarbon pollutant burdens in petrochemical and refinery process streams

This paper describes techniques which provide for both qualitative and quantitative identification of major components in a process stream. The techniques and instrumentation have been deliberately chosen so as to be within the technical and financial reach of all but the smallecompany laboratory. The sample preparation steps consist of an initial series of extractions which isolate compounds into organic acid, base, and neutral compounds and a totally water soluble phase. Each fraction is then concentrated and subjected to thin-layer chromatography, gas chromatography, infrared spectroscopy or ultraviolet spectroscopy as appropriate. Results are given for laboratory samples, one a mixture of aniline, phenol, benzoic acid, m-nitrobenzaldehyde, 1-butanol, 2-hexanone, nonane, and cyclohexane, and the other a mixture of benzene, ethylbenzene, and styrene. Also, a qualitative analysis of a petroleum refinery desalter water is presented.     

Federalism and environmental politics: An Australian overview

Summary This overview paper examines past Australian conservation controversies and experiences to identify prospective means of ameliorating environmental conflict in the future. Since all community disputes should be resolved by means of political and administrative actions, emphasis is placed on federalism and intergovernmental relations, and measures are suggested which might improve environmental policy and practices in the future.Dr Bruce W. Davis is currently Head of the Department of Political Science, Dean of the Faculty of Arts, and member of the Council of the University of Tasmania. He possesses qualifications and professional experience in engineering, economics and administration. He has numerous publications within the fields of public sector planning and natural resources management, and acts in an advisory and consulting capacity to State and Federal agencies involved in national parks administration, heritage conservation and land-use planning.In addition to University commitments, Dr Davis holds the following appointments: Commissioner, Australian Heritage Commission; Member, Australian National Commission for UNESCO, Man and Biosphere Program; Trustee, World Wildlife Fund Australia; Councillor, Australian Conservation Foundation; and Consultant to IUCN, Gland, Switzerland.     

Siro‐plan: improving the acceptability of a practical planning method

The SIRO‐Plan method was evolved in the CSIRO Division of Water and Land Resources, Canberra, in response to what was seen as an absence in literature of a procedural theory calling for the use of both systematically acquired resource inventory data and expressions of community demands. The paper records a selection of insights accumulated and lessons learned during six years of effort to improve the usefulness of the method.     

HYDROLOGIC ENGINEERING CENTER PLANNING MODELS1

ABSTRACT: The U.S. Army Corps of Engineers has broad, nationwide water resources planning and management responsibilities. In response to the needs of Corps professionals, the Hydrologic Engineering Center (HEC) has developed and supports a family of computer programs designed to aid them in their work. These programs include catchment, channel, alluvial, and statistical process models, system operation models, plan evaluation models, and data management programs. These models individually and collectively have been used throughout the Corps in a wide range of water resources planning studies.     

MEASURING IMPACTS OF URBAN WATER DEVELOPMENT1

ABSTRACT The role of water resources in the urban economic and social environment, particularly in the inner city, has never been established to the degree necessary for making informed decisions on investments in urban waterway and shoreline improvements. The basic tools for measuring psychological and social impacts of waterway and shoreline developments in the inner city have not been fully developed and utilized to date. However, through a detailed analysis of the water resources in the urban core area of Cleveland, it appears that deliberate development of water-based recreation and other environmental resources can lead to improvement in some of the social problems of the inner city. In recreation analysis, there is currently a great gap between methodologies that are conceptually sound and those that have been applied by urban and water-resources planning agencies. New tools and methodologies can only be used successfully when public agencies are given the institutional and policy means for using them equitably in light of social needs. Present urban-water planning practices have been found to be biased against the inner city, often unintentionally.     

COAL ASH BASIN EFFECTS (PARTICULATES,METALS, ACIDIC pH) UPON AQUATIC BIOTA: AN EIGHT-YEAR EVALUATION1

ABSTRACT Coal ash effluent effects including particulates, acidic pH excursions, elemental concentrations and bioconcentration in selected organisms have been studied as changes in water quality and densities of benthic macroinvertebrate and mosquitofish (Gambusia affinis) populations in a swamp drainage system over an eight-year period. Three changes in the ash basin settling system were made between mid- 1973 and January 1982. Initial density of the aquatic biota was altered severely by heavy ash siltation, followed by acidic pH excursions and perhaps overall by elemental concentrations and bioaccumulation. Heavy ash siltation, followed by acidic Ph excursions (mean of 5.5, extreme of 3.5) after the addition of fly ash to the original settling basin system, had the most profound effect on biota. Dipterans (chironomids) and some odonates (Plathemis lydia and Libellula spp.) were resistant to heavy ash siltation, while mosquitofish, which showed no discernible responses to ash siltation, were absent at acidic pH, along with the few previously surviving invertebrate populations. Elemental concentrations of arsenic, cadmium, chromium, copper, selenium, and zinc did not appear to limit aquatic flora and fauna on a short-term, acute basis. Long, chronic elemental exposures may have been instrumental in retarding the recovery of all forms of aquatic life in the receiving system. Elemental concentrations (except for arsenic and selenium) in the receiving system were generally one to two orders of magnitude higher than the Water Quality Criteria set by the U.S. Environmental Protection Agency (1980) for protection of aquatic life for the minimum and 24-hour mean values. From collective elemental exposures in the receiving system, bioconcentration factors in macrophytes, invertebrates and fish were generally lower than those reported in the literature for laboratory, single elemental concentrations. By 1978, when the new settling basin systems were operating effectively, invertebrate populations were largely recovered, and mosquitofish populations recovered within one year afterward.     

Environmental quality criteria: Some considerations

The physicochemical characteristics of the recipient environment into which chemical contaminants are deposited may influence their chemical speciation, mobility, bioavailability, and toxicity. In formulating Water Quality Criteria, the Environmental Protection Agency of the United States (EPA) considered the modifying effect of abiotic environmental factors on pollutant toxicity in an innovative regulatory approach. Scientific knowledge of the interactions and correlations between pollutant toxicity and abiotic factors remains limited. Recognition of the influence of the physicochemical characteristics of the recipient environment on pollutant toxicity has implications for the eventual formulation of regional, rather than uniform and national, criteria. In addition, in developing Water Quality Criteria that incorporate the effects of pollutants on aquatic life, EPA primarily focused on toxicity to aquatic animals and plants (including unicellular algae). The effects of pollutants on microbe-mediated ecological processes that are necessary for maintaining the state and quality of the ecosphere (such as biogeochemical cyclings, litter decomposition, and mineralization) were not included in the formulation of the Water Quality Criteria. To facilitate the recognition and quantification of adverse effects of pollutants on these ecological processes, the development of a computation, termed the ecological dosage 50% (EcD₅₀) is recommended. Such a formulation could also be applied to setting environmental quality criteria for terrestrial ecosystems.     

A planning-level model for estimating quantities of wastes generated by the demolition of structures during remediation

A model is presented to estimate quantities of wastes generated by the demolition of various types of industrial structures. It is intended to be used for preliminary planning purposes in the absence of any detailed structure-specific information. Detailed material quantity estimates compiled for structures at the U.S. Department of Energy's Fernald site in Ohio were used to develop the statistical relationships in the model. The model provides estimates of the total quantity of wastes, the quantities of waste concrete, and the quantities of wastes that originate from at-, below-, and above-grade portions of a structure.     

Potential exposure to diazinon during yard applications

Applicators applying diazinon to yards were monitored to determine potential exposures received while using this commonly available pesticide around the home. Diazinon was applied to lawns and shrubs using compressed air or hose-end sprayers. Even with minimal clothing, the largest mean exposure received during any of the applications was estimated to be less than 0.2% of a lethal dose per hour. Exposure to the hands accounted for 85% or more of the total exposure, so simply protecting the hands would have essentially eliminated exposure.