First continuous shipboard δ18O and δD measurements in sea water by diffusion sampling—cavity ring-down spectrometry

Combined measurements of salinity and the oxygen/hydrogen stable isotope composition of marine waters can characterise processes such as freshwater mixing, evaporation, precipitation and sea-ice formation. However, stable isotope data with high spatial and temporal resolution are necessary for a detailed understanding of mixed water bodies with multiple inputs. So far analysis of ??¹⁸O and ??D values in water has been a relatively expensive, laboratory-based technique requiring collection of discrete samples. This has greatly limited the scope and scale of field research that can be undertaken using stable isotope analysis. Here, we report the first continuous shipboard measurements of ??¹⁸O and ??D values in water by diffusion sampling-cavity ring-down spectrometry. Combined with continuous salinity recordings, a data set of nearly 6,000 measurements was made at 30-s intervals during a 3-day voyage through the Great Barrier Reef Lagoon. Our results show that continuous shipboard measurement of ??¹⁸O/??D values provides additional discriminatory power for assessing water mass formation processes and histories. Precise identification of river plumes within the Great Barrier Reef Lagoon was only possible because unique ??¹⁸O/??D?Csalinity relationships of individual plumes were measured at high spatial and temporal resolution. The main advantage of this new technique is the ability to collect continuous, real-time isotope data at a small fraction of the cost of traditional isotope analysi s of discrete samples. Water ??¹⁸O and ??D values measured by diffusion sampling-cavity ring-down spectrometry and laboratory-based isotope ratio mass spectrometry have similar accuracy and precision.     

DEVELOPMENT OF FEDERAL RESERVE RIGHTS1

ABSTRACT: The concept that has been termed “Indian Rights to Water” is one manifestation of the area of federal reserved rights that is a major concern of states in arid regions. The federal reserved rights are those that are reserved in fact or by implication in federal actions, acts, reservations, and treaties. Federal actions include such things as navigation improvement and flood control projects. The Federal Court System, since the Civil War has been promulgating, developing, and protecting federal reserved water rights. The development of those rights can be traced from early cases through the landmark cases such as U.S. v. Rio Grande and Irrigation Co. (1899); Winters v. U.S. (1908) with the origin of the Winters' Doctrine of Indian Rights; Federal Power Commission v. Oregon, commonly called the Pelton Dam Case (1955); Arizona v. California (1963); U.S. v. District Court for Eagle County (1971); to existing suits on surface water sources such as that on appeal in regard to reserved federal water rights on the Truckee River. It can be shown that the federal position has been consistent through all the years in that the federal rights have been protected, expanded, developed, and preserved in a more or less predictable manner.     

Light quality effects on carbon metabolism and allocation in Gracilaria verrucosa

Under conditions of new nitrogen availability and low light intensities, light quality (blue, green, or red light) was not found to affect carbon fixation patterns into major metabolic fractions (total ethanol soluble, carbohydrate, and protein) in preconditioned nitrogen enriched or limited apical tips of Gracilaria verrucosa Papenfuss. Within the ethanol soluble fractions of both nitrogen enriched and limited tips, blue light treatment led to a greater percentage of ¹⁴ carbon in amino acids as compared to non-ninhydrin reactive metabolites. A lesser effect was observed with red light, and green light did not appear to stimulate amino acid synthesis appreciably. The low intensity blue light effect in G. verrucosa appears to be an enhancement of nonphotosynthetic carbon incorporation into amino acids, possibly through some form of the urea-ornithine cycle.Harbor Branch Foundation Contribution No. 237     

Changing patterns in aluminium production costs

The average cost of producing aluminium fell slightly in nominal terms between 1982 and 1992, and there has thus been a sharp fall in real terms. The average cost also shows a marked cyclical fluctuation during individual years, partly as a result of the feedback effect from final metal prices to the cost curve. Between 1985 and 1992, exchange rate fluctuations produced a sharp change in the relative position of US and European smelters. During the next eight years, costs are likely to rise gradually in real terms, reversing the historical trend, and unless the higher cost European smelters can cut costs significantly, they may face a bleak future.     

Use of in vivo phycocyanin fluorescence to monitor potential microcystin-producing cyanobacterial biovolume in a drinking water source

The source water of a drinking water treatment plant prone to blooms, dominated by potential microcystin-producing cyanobacteria, was monitored for two seasons in 2007-2008. In the 2008 season, the median value for potential microcystin-producing cyanobacterial biovolume was 87% of the total phytoplankton biovolume in the untreated water of the plant. Depth profiles taken above the plant's intake identified three sampling days at high risk for the contamination of the plant's raw water with potentially toxic cyanobacteria. Chlorophyceae and Bacillariophyceae caused false positive values to be generated by the phycocyanin probe when cyanobacteria represented a small fraction of the total phytoplanktonic biovolume present. However, there was little interference with the phycocyanin probe readings by other algal species when potential microcystin-producing cyanobacteria dominated the phytoplankton of the plant's untreated water. A two-tiered method for source water monitoring, using in vivo phycocyanin fluorescence, is proposed based on (1) a significant relationship between in vivo phycocyanin fluorescence and cyanobacterial biovolume and (2) the calculated maximum potential microcystin concentration produced by dominant Microcystis sp. biovolume. This method monitors locally-generated threshold values for cyanobacterial biovolume and microcystin concentrations using in vivo phycocyanin fluorescence.     

Consistency and comparability of estimation and accounting of removal by sinks in afforestation/reforestation activities

The Kyoto Protocol accounting system and its market mechanisms, Clean Development Mechanism (CDM) and Joint Implementation (JI), are built on the key principle that emission and emission reduction units generated by afforestation/reforestation activities under national systems and projects are fully comparable, no matter their origin. Lack of consistency in the quality of emission and emission reduction units can undermine the environmental integrity of the climate stabilization actions. Therefore, it is the ambition that units generated in the land-use, land-use change and forestry (LULUCF) sector are of similar quality with those from non-LULUCF sectors. In this paper, the authors pose the question of whether there is full estimation and accounting consistency between Annex I Party’s national GHG systems and CDM projects methodologies in the LULUCF sector, in terms accuracy, completeness, levels of uncertainty and permanence risk. We focus on methodological aspects related to the applicability and practicability of using approved afforestation/reforestation CDM methodologies; estimation, reporting and accounting rules; the small pools and sources issue, uncertainty of removal estimate; leakage and handling of non-permanence risk. We conclude that there is significant scope for improving the consistency of greenhouse gas emission accounting from land use activities in the post-2012 climate change agreement, between Annex I domestic and project activities. As well, we conclude that the preparation and implementation of project activities has to be made simpler by a project framework guideline, which is then adapted to any project circumstances.     

Development of Indicators to Assess Economic Vulnerabilities to Changes in Ecosystem Services: Case Study of Counties in Maryland,USA

We develop indicators showing the relative environmental burdens that human activities place on locales for a given level of economic benefits. The main purpose is to develop tools that allow us to examine the potential vulnerabilities within economies to changes in resource conditions. The indicators of pollution emission or resource consumption per job can be used to identify potential challenges to resource and industry managers and to compare areas in terms of their ability to adapt to change. For example, if a large number of area jobs are dependent on abundant water, this indicates a vulnerability to a reduction in water availability for industrial use. We develop a case study for 23 counties and 1 city in Maryland to examine the usefulness and limitations of the indicators. Our case study demonstrates that the indicators provide an informative view into patterns of local economic activity and use of an area’s environmental goods and services. In contrast to patterns for total environmental burdens (e.g., total SO₂ emissions) that are typically reported, the rates of environmental burden per job are not simply correlated with high or low economic output. Thus, the indicators represent distinct patterns of environmental burdens per job that reflect reliance on environmental services. The indicators have some limitations when used at this fine scale because they can misrepresent conditions in counties in which economic sectors are dominated by one or a few businesses. For this reason, the indicators are best used as a regional screening tool.     

High diurnal variation in dissolved inorganic C, δ13C values and surface efflux of CO2 in a seasonal tropical floodplain

Diurnal variations in aquatic systems may be a major factor influencing carbon cycling. However, few studies have examined diurnal variation on floodplains and wetlands, especially in the tropics. Stable isotope analysis of dissolved inorganic carbon (δ¹³C_DIC) provides insight into the driving factors behind diurnal physio-chemical variability, but to date, the manual collection of large sample numbers at high temporal frequency has been prohibitive. Here, we report one of the first, high-resolution isotopic studies of δ¹³C_DIC on a tropical floodplain using acidification-interface cavity ring-down spectrometry. Water samples were analysed for δ¹³C_DIC and other water quality parameters at 15-min intervals for 24 h. Our results show significant diurnal variation in both DIC concentration and δ¹³C_DIC. Maximum DIC concentration, recorded overnight, was approximately 100 % greater than during the day. Maximum DIC concentration coincided with minimum δ¹³C_DIC as a result of shifting autotrophic/heterotrophic balance. Changes were significant over small time scales and showed CO₂ gas evasion estimates could vary by as much as 50 % based on measurements taken less than 5 h apart. These data show that to accurately evaluate the role of tropical floodplains in global carbon dynamics, a comprehensive understanding of diurnal variation will be essential.     

To what extent are hepatic concentrations of heavy metals in Anguilla anguilla at a site in a contaminated estuary related to body size and age and reflected in the metallothionein concentrations?

We explored how hepatic [metal]s in Anguilla anguilla at a contaminated estuarine site are influenced by body size, age and season, and the extent that [Cu], [Cd] and [Zn]s are reflected in [metallothionein (MT)]s. Although each [metal] and [MT] increased significantly with length, weight and age, those biotic variables explained <10% of the variation in each [metal] and only 11-16% for [MT]. Seasonal changes in [Cu] and [Cd] were paralleled by [MT]. The variation in [MT] explained by Cu (42%) was greater than by Zn (16%) and Cd (13%), and seasonally lay between 43 and 69% for those metals collectively. Thus, hepatic [MT] in eels is closely correlated with hepatic [heavy metal]s. However, the great variability among [MT]s for eels of similar sizes and ages, which reflects marked variability in hepatic [heavy metal]s, means that this variable reflects imprecisely the contamination level at a particular site.