UV-VIS spectroscopy of 2,4,6-trinitrotoluene-hydroxide reaction

Contamination of groundwater, surface water and soil by explosives has occurred at military sites throughout the world as a result of manufacture of explosive compounds, assembly of munitions, and deployment of explosives containing devices. Due to the adverse effects of explosives on humans and other natural receptors, a low cost means of decontaminating these areas of contamination is needed. Base-induced transformation of explosives has shown promise as a rapid, low cost, and minimally resource-intensive technology for detoxifying explosives in soil and water. In order to understand the reaction mechanism, a reaction mixture of 2:1:1 (water:2,4,6-trinitrotoluene (TNT):1 N KOH) was analyzed by UV/VIS spectrometry from 190 to 1,100 nm. Time course measurements were conducted at 25, 20, 15, and 12 degrees C. A factor analysis program was used to analyze the spectral data. Principal component analysis indicated that six principal components explained the spectra to within experimental error, with four factors explaining the majority of the variance. Test spectral vectors for four components were developed, including TNT, two intermediates, and the final product, and were tested against the abstract vectors. Two possible reaction mechanisms were suggested and tested to explain the spectral data.     

PM2.5 assessment in 21 European study centers of ECRHS II: Method and first winter results

The follow-up of a cohort of adults from 29 European centers of the former European Community Respiratory Health Survey (ECRHS) I (1989-1992) will examine the long-term effects of exposure to ambient air pollution on the incidence, course, and prognosis of respiratory diseases, in particular asthma and decline in lung function. The purpose of this article is to describe the methodology and the European-wide quality control program for the collection of particles with 50% cut-off size of 2.5 microm aerodynamic diameter (PM2.5) in the ECRHS II and to present the PM2.5 results from the winter period 2000-2001. Because PM2.5 is not routinely monitored in Europe, we measured PM2.5 mass concentrations in 21 participating centers to estimate background exposure in these cities. A standardized protocol was developed using identical equipment in each center (U.S. Environmental Protection Agency Well Impactor Ninety-Six [WINS] and PQ167 from BGI, Inc.). Filters were weighed in a single central laboratory. Sampling was conducted for 7 days per month for a year. Winter mean PM2.5 mass concentrations (November 2000-February 2001) varied substantially, with Iceland reporting the lowest value (5 microg/m3) and northern Italy the highest (69 microg/m3). A standardized procedure appropriate for PM2.5 exposure assessment in a multicenter study was developed. We expect ECRHS II to have sufficient variation in exposure to assess long-term effects of air pollution in this cohort. Any bias caused by variation in the characteristics of the chosen monitoring location (e.g., proximity to traffic sources) will be addressed in later analyses. Given the homogenous spatial distribution of PM2.5, however, concentrations measured near traffic are not expected to differ substantially from those measured at urban background sites.     

RESEARCH: Triage Law Enforcement: Societal Impacts on National Forests in the West

/ Uses of outdoor natural areas, like National Forests in the United States, have been undergoing change. Some changes, including criminal activities and domestic terrorism, may have quite important impacts to outdoor enthusiasts and managers. Activities include some relatively traditional management challenges, like arson and thefts, and newer challenges, such as domestic violence and murder. To better understand the prevalence and impacts of these activities, selected managers in the western United States were interviewed in summer and fall 1998. Results indicate criminal activities and domestic terrorism are found in both urban-interface and rural sites. The most prevalent challenges were arson, criminal damage, domestic violence, dumping of household trash and landscape materials, marijuana cultivation, satanic cult activity, and thefts. Not as prevalent but found in almost all study sites were body dumping, extremist group activity, gang activity, murders, and suicides. Managers felt that most outdoor recreationists were unaffected by the activities. Most managers noted the increasing prevalence and the costs to management in time, personnel, and in other ways. They noted that their job had ceased being one of natural resources law enforcement and became one of "city" law enforcement. The findings of the study raise serious issues that require additional research.     

A quantitative succession model for nine montana forest communities

A quantitative succession model was developed both to meet resource management needs in Montana's Lewis and Clark National Forest and to develop a modeling methodology. It builds upon previous concepts and incudes three new features: quantitative prediction of all tree species and seedlings; quantitative predictions of important understory species; and successional pathways determined by fire intensity and scorch height. The method is described and demonstrated for selected Montana habitat (community) types. It is also available in managerial guidelines and has been programmed as a new module in theforplan simulator. Weaknesses of this and other models are discussed. Conclusions relate succession modeling to resource management needs.