全文获取类型
收费全文 | 12261篇 |
免费 | 116篇 |
国内免费 | 432篇 |
专业分类
安全科学 | 332篇 |
废物处理 | 566篇 |
环保管理 | 1525篇 |
综合类 | 2940篇 |
基础理论 | 2695篇 |
环境理论 | 5篇 |
污染及防治 | 3313篇 |
评价与监测 | 730篇 |
社会与环境 | 612篇 |
灾害及防治 | 91篇 |
出版年
2022年 | 135篇 |
2021年 | 132篇 |
2020年 | 83篇 |
2019年 | 102篇 |
2018年 | 194篇 |
2017年 | 174篇 |
2016年 | 277篇 |
2015年 | 223篇 |
2014年 | 301篇 |
2013年 | 913篇 |
2012年 | 369篇 |
2011年 | 513篇 |
2010年 | 403篇 |
2009年 | 450篇 |
2008年 | 484篇 |
2007年 | 550篇 |
2006年 | 477篇 |
2005年 | 397篇 |
2004年 | 396篇 |
2003年 | 404篇 |
2002年 | 363篇 |
2001年 | 448篇 |
2000年 | 349篇 |
1999年 | 229篇 |
1998年 | 142篇 |
1997年 | 149篇 |
1996年 | 132篇 |
1995年 | 167篇 |
1994年 | 163篇 |
1993年 | 129篇 |
1992年 | 142篇 |
1991年 | 160篇 |
1990年 | 134篇 |
1989年 | 131篇 |
1988年 | 134篇 |
1987年 | 116篇 |
1986年 | 86篇 |
1985年 | 102篇 |
1984年 | 126篇 |
1983年 | 126篇 |
1982年 | 124篇 |
1981年 | 97篇 |
1980年 | 93篇 |
1979年 | 106篇 |
1978年 | 89篇 |
1977年 | 84篇 |
1976年 | 78篇 |
1975年 | 90篇 |
1974年 | 101篇 |
1965年 | 74篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
Carlos Alberto A. de Almeida Carla G.B. Brenner Luciane Minetto Carlos A. Mallmann Ayrton F. Martins 《Chemosphere》2013
In this study, an analytical methodology was developed for the determination of psycho-active drugs in the treated effluent of the University Hospital at the Federal University of Santa Maria, RS – Brazil. Samples were collected from point A (Emergency) and point B (General effluent). The adopted methodology included a pre-concentration procedure involving the use of solid phase extraction and determination by liquid chromatography coupled to mass spectrometry. The limit of detection for bromazepam and lorazepam was 4.9 ± 1.0 ng L−1 and, for carbamazepine, clonazepam and diazepam was 6.1 ± 1.5 ng L−1. The limit of quantification was 30.0 ± 1.1 ng L−1, for bromazepam, clonazepam and lorazepam; for carbamazepine was 50.0 ± 1.8 ng L−1 and was 40.0 ± 1.0 ng L−1 for diazepam. The mean concentrations in the Emergency and General effluent treated currents were as follows: for bromazepam, 195 ± 6 ng L−1 and 137 ± 7 ng L−1; for carbamazepine, 590 ± 6 ng L−1 and 461 ± 10 ng L−1; for diazepam, 645 ± 1 ng L−1 and 571 ± 10 ng L−1; for lorazepam, 96 ± 7 ng L−1 and 42 ± 4 ng L−1; and for clonazepam, 134 ± 10 ng L−1 and 57 ± 10 ng L−1. A preliminary risk assessment was conducted: carbamazepine and diazepam require considerable attention owing to their environmental toxicity. The occurrence of these psychoactive-drugs and the environmental risks that they pose demonstrated the need for a more efficient treatment system. As far we are aware, there have been no comparable studies to this on the hazards of hospital effluents in Brazil, and very few that have carried out a risk assessment of psycho-active drugs in hospital effluent in general. 相似文献
992.
Comparison of particle light scattering and fine particulate matter mass in central California 总被引:2,自引:0,他引:2
Chow JC Watson JG Park K Lowenthal DH Robinson NF Park K Magliano KA 《Journal of the Air & Waste Management Association (1995)》2006,56(4):398-410
Particle light scattering (Bsp) from nephelometers and fine particulate matter (PM2.5) mass determined by filter samplers are compared for summer and winter at 35 locations in and around California's San Joaquin Valley from December 2, 1999 to February 3, 2001. The relationship is described using particle mass scattering efficiency (sigmasp) derived from linear regression of Bsp on PM2.5 that can be applied to estimated PM2.5 from nephelometer data within the 24-hr filter sampling periods and between the every-6th-day sampling frequency. An average of sigmaSp = 4.9 m2/g was found for all of the sites and seasons; however, sigmasp averaged by site type and season provided better PM2.5 estimates. On average, the sigmasp was lower in summer than winter, consistent with lower relative humidities, lower fractions of hygroscopic ammonium nitrate, and higher contributions from fugitive dust. Winter average sigmasp were similar at non-source-dominated sites, ranging from 4.8 m2/g to 5.9 m2/g. The sigmasp was 2.3 m2/g at the roadside, 3.7 m2/g at a dairy farm, and 4.1 m2/g in the Kern County oilfields. Comparison of Bsp from nephelometers with and without a PM2.5 inlet at the Fresno Supersite showed that coarse particles contributed minor amounts to light scattering. This was confirmed by poorer correlations between Bsp and coarse particulate matter measured during a fall sampling period. 相似文献
993.
F. Frasca A. M. Siani G. R. Casale M. Pedone Ł. Bratasz M. Strojecki A. Mleczkowska 《Environmental science and pollution research international》2017,24(16):13895-13907
The microclimatic monitoring of the historic church of Mogi?a Abbey (Kraków, Poland) was carried out to study the impact of the environmental parameters on the organic and hygroscopic artworks. Specific indexes were proposed to objectively assess the quality of time series of temperature (T), relative humidity (RH), and carbon dioxide (CO2) before applying the exploratory data analysis. The series were used to define the historic environmental conditions as stated in the European Standard EN 15757:2010 and with the use of the climate evaluation chart (CEC). It was found that the percentage of time in which T and RH values are within the allowable limits of the ASHRAE (2011) Class B is more than 85 %. This means that, for about 15 % of the time, there is a high risk of mechanical damage to highly vulnerable objects mainly due to the RH variability. The environment at the chancel resulted moister than that at the cornice, and the fungal growth is possible. In addition, the time-weighted preservation index (TWPI) is computed to evaluate the life expectancy of the objects, taking into account the environmental conditions of the site under study. The method of analogues, developed to predict the evolution of a system given observations of the past and without the knowledge of any equation among variables, was proposed and applied to the time series of temperature, relative humidity, and carbon dioxide with a 1-h sampling time to avoid the influence of the autocorrelation. 相似文献
994.
The human health risk assessment is supported by methodology for utilizing toxic effects in animals consisting of carcinogenic and noncarcinogenic responses as a result of chronic, subchronic and acute exposures. One of the initial steps in a risk assessment activity involves the estimation of exposure levels. These estimates are typically based on either direct environmental measurements or predictions obtained from fate and transport models. The decision to develop assessment of risk from chronic exposure based on a nonthreshold model is made if a chemical demonstrates carcinogenic activity in animal bioassays and/or in human epidemiological studies. In the absence of any positive human epidemiologic data, it is assumed that a substance which induces a statistically significant carcinogenic response in animals has the probability to cause cancer in humans. The carcinogenic potential of 2,3,7,8-TCDD has been established based on chronic exposure in rodents. In addition, 2,3,7,8-TCDD has also been shown to be a liver cancer promoter in rodents. In the risk assessment on dioxins based on chronic exposure in experimental animals, 2,3,7,8-TCDD is regarded as a carcinogenic substance. Carcinogenic data from animal bioassays are utilized for the assessment of risk for the purpose of estimating the likelihood of 2,3,7,8-TCDD being carcinogenic for humans and to determine the magnitude of the potential impact on public health. 相似文献
995.
J Rivas E Rodríguez F J Beltrán J F García-Araya P Alvarez 《Journal of environmental science and health. Part. B》2001,36(3):317-330
Simazine, [2-chloro, 4,6-bis(ethylamino)-1,3,5-s-triazine], a common herbicide typically found in surface and ground water was ozonised by using catalytic amounts of Mn(II) and Fe(II). An optimum value for metal concentration was found in the process. Some inhibition of the simazine degradation rate was observed when these metals were added above the optimum concentration. The pH of the reaction media played a significant role in the simazine oxidation rate. Thus, an increase in simazine conversion was observed when the pH was raised from 5 to 9. However, the catalytic effect of added manganese was negligible at the highest pH used in this study (pH 9). The beneficial influence of Fe(II) was also observed when utilising the combination of ozone and hydrogen peroxide. Contrarily, Mn(II) presented a negative influence on simazine conversion when using this oxidation technology. 相似文献
996.
OBJECTIVE: To determine the characteristics of speeders, defined as drivers of vehicles traveling at least 15 mph above the posted speed limit and relatively faster than surrounding vehicles. METHODS: Vehicle speeds were recorded on 13 roads in Virginia with speed limits ranging from 40 to 55 mph. Speeders were compared with slower drivers, defined as drivers of adjacent vehicles traveling no more than 5 mph above the speed limit. License plates were used to identify vehicle owners; owners were inferred to have been driving if observed gender and estimated age matched those of the registered owner. For these drivers, information on exact driver age and gender, vehicle make and model, and driving record was obtained from the Virginia Department of Motor Vehicles. RESULTS: Five percent of the vehicles observed were traveling at least 15 mph above the limit, and 3% qualified as speeders, as defined in this study. Speeders were younger than drivers in the comparison group, drove newer vehicles, and had more speeding violations and other moving violations on their records. They also had 60% more crashes. DISCUSSION: Speeders are a high-risk group. Their speeding behavior is not likely to be controlled without vigorous, consistent enforcement, including the use of automated technology. 相似文献
997.
998.
Physical resuspension and vertical mixing of sediments on a high energy continental margin (Sydney, Australia) 总被引:2,自引:0,他引:2
Four sediment cores from the continental margin adjacent to Sydney were analyzed for 210Pb, 137Cs, trace metals (Ag, Cd, Co, Cu, Mn, Ni, Pb, Zn), iron, dry bulk density, mud and moisture content. The concentrations of trace metals in the total sediment are low at all sites, although slightly elevated concentrations of Ag, Cu, Pb and Zn are present in the fine fraction of sediment (< 62.5 microns) near a major ocean outfall. Concentrations of trace metals in the fine fraction of sediment are similar in the upper 10-15 cm, indicating strong vertical mixing of the sediments, whereas an upward coarsening grain size in the upper 1-3 cm of sediment supports physical resuspension during storms. Sediment accumulation rates on the middle shelf adjacent to Sydney were estimated from downcore profiles of 210Pb and 137Cs and range between 0.2 and 0.4 cm yr-1. Although the mass fluxes of Cu, Pb and Zn within a distance of 2 km from the outfall (up to 36.1, 30.8 and 86.2 micrograms cm-2 yr-1, respectively) are greater than 20 km north of the outfall (< 23.5 micrograms cm-2 yr-1), the low concentrations of trace metals in sediments near the outfall support an efficient dispersal of anthropogenic contaminants on this continental margin. 相似文献
999.
M. L. Cocks L. Bangay K. F. Wiersum A. P. Dold 《Environment, Development and Sustainability》2006,8(4):519-533
There is a growing wealth of data capturing the direct-use values of the environment and recognition of forests and wild resources as representing “the poor manȁ9s overcoat”. This focus has however resulted in an emphasis on the utilitarian values of wild resources for rural livelihoods and has for the most part overlooked their cultural values. In tangent to these developments within the field of anthropology there has been increased attention directed towards the relationship between biodiversity and human diversity over the past decade. This has resulted in the recognition of what the Declaration of Belem calls an ȁ8inextricable linkȁ9 between biological and cultural diversity. The term bio-cultural diversity has been introduced as a concept denoting this link. Consequently there is a need for more elaborate assessments of the various ways in which different groups of people find value in biodiversity. The aim of this paper is to demonstrate the cultural significance of wild harvested plant resources for the maintenance of two gender specific cultural artefacts for amaXhosa people in South Africa, to assess the persistence of these practices in rapidly modernizing communities. We demonstrate the endurance of these ancient cultural artefacts in present-day peri-urban communities and suggest that they point to the need for improved understanding of the significance of bio-cultural diversity. The findings of the study should not be interpreted as illustrating stagnation in the traditional past, but rather as pointing at the need for improved understanding of the significance of bio-cultural diversity in a dynamic sense. 相似文献
1000.