Estimates of Particle Hygroscopicity during the Southeastern Aerosol and Visibility Study

ABSTRACT

Aerosol water content was determined from relative humidity controlled optical particle counter (ASASP-X) size distribution measurements made during the Southeastern Aerosol and Visibility Study (SEAVS) in the Great Smoky Mountains National Park during summer 1995. Since the scattering response function of the ASASP-X is sensitive to particle refractive index, a technique for calibrating the ASASP-X for any real refractive index was developed. A new iterative process was employed to calculate water mass concentration and wet refractive index as functions of relative humidity. Experimental water mass concentrations were compared to theoretically predicted values assuming only ammonium sulfate compounds were hygroscopic. These comparisons agreed within experimental uncertainty. Estimates of particle hygroscopicity using a rural aerosol model of refractive index as a function of relative humidity demonstrated no significant differences from those made with daily varying refractive index estimates. Although aerosol size parameters were affected by the assumed chemical composition, forming ratios of these parameters nearly canceled these effects.     

Are leaves that fall from imidacloprid-treated maple trees to control Asian longhorned beetles toxic to non-target decomposer organisms?

The systemic insecticide imidacloprid may be applied to deciduous trees for control of the Asian longhorned beetle, an invasive wood-boring insect. Senescent leaves falling from systemically treated trees contain imidacloprid concentrations that could pose a risk to natural decomposer organisms. We examined the effects of foliar imidacloprid concentrations on decomposer organisms by adding leaves from imidacloprid-treated sugar maple trees to aquatic and terrestrial microcosms under controlled laboratory conditions. Imidacloprid in maple leaves at realistic field concentrations (3-11 mg kg(-1)) did not affect survival of aquatic leaf-shredding insects or litter-dwelling earthworms. However, adverse sublethal effects at these concentrations were detected. Feeding rates by aquatic insects and earthworms were reduced, leaf decomposition (mass loss) was decreased, measurable weight losses occurred among earthworms, and aquatic and terrestrial microbial decomposition activity was significantly inhibited. Results of this study suggest that sugar maple trees systemically treated with imidacloprid to control Asian longhorned beetles may yield senescent leaves with residue levels sufficient to reduce natural decomposition processes in aquatic and terrestrial environments through adverse effects on non-target decomposer organisms.     

STREAM-CHANNEL INCISION FOLLOWING DRAINAGE-BASIN URBANIZATION1

ABSTRACT: Urbanization of a drainage basin results in pervasive hydrologic changes that in turn initiate long-term changes in stream channels. Increases in peak discharges and in durations of high flows result in either quasi-equilibrium channel expansion, where cross-section area increases in near-proportion to the discharge increase, or catastrophic channel incision, where changes occur far out of proportion to the discharge increases that initiated them. Field data and hydrologic modeling of rapidly urbanizing basins in King County, Washington, define conditions of flow, topography, geology, and channel roughness that identify streams susceptible to incision. Channel slope and geologic material are particularly critical; thus simple map overlays, nearly irrespective of contributing drainage area, provide a valuable planning tool for identification of susceptible terrain. Where such conditions exist, basal shear stress provides a quantifiable parameter for predicting likely problems, although knickpoints are typical in such settings and confound simple calculation of sediment-transport rates. Where urbanization proceeds in such areas, effective mitigation of the incision hazards requires a degree of stormwater control far in excess of standards typically applied to present development activity.     

Reviewing the carbon footprint analysis of hotels: Life Cycle Energy Analysis (LCEA) as a holistic method for carbon impact appraisal of tourist accommodation

This study discusses the potential for Life Cycle Assessment (LCA) to be utilized for the environmental assessment of tourism accommodation facilities, and their contribution to global carbon footprint. To demonstrate the viability of employing LCA in the hotel sector, its simplified derivative, Life Cycle Energy Analysis (LCEA), is applied to two tourism accommodation facilities in Poole, Dorset (UK) to quantify their CO₂ emissions. The results indicate that the reviewed hotels are less energy and carbon-intense than the tourism accommodation establishments reported in the literature. This may indirectly imply the continuous progress of hotel’s energy efficiency over time. The implications of the current energy use practices in the reviewed hotels are discussed and suggestions are made on how to further improve the energy performance and therefore cut the carbon footprint. Recommendations for hotel management and policy-making are developed to reduce the energy and carbon intensity of the hotel industry. A method for energy and carbon footprint analysis of outsourced laundries and breakfast services is also proposed.     

A time‐lagged investigation of the impact of coworker behavior on the effects of demographic dissimilarity

Although it is clear that coworker absenteeism, tardiness, and turnover can influence an employee's actions, scholars have yet to consider the impact of relational demography on the adoption of these behavioral norms. Inspired by social identity, situational strength, and attraction‐selection‐attrition theories, we proposed that individuals who differ from their coworkers in age, sex, or racioethnicity would feel threatened by their outnumbered status and subsequently motivated to be absent, tardy, or more likely to turnover. However, we expected coworker withdrawal behavior to moderate whether or not dissimilar personnel act on these desires. Results from hierarchical multilevel modeling analyses of data from 470 U.S. call center workers nested in 51 work groups revealed that racioethnic dissimilarity was positively related to time‐lagged changes in absenteeism and tardiness as well as heightened turnover likelihood. These effects emerged only among employees whose coworkers engaged in greater withdrawal behavior. Importantly, racioethnically dissimilar employees working in more permissive climates (i.e., those with high levels of coworker absenteeism, tardiness, or turnover) exhibited the greatest increases in absenteeism and tardiness over three months and had the highest supervisor‐rated turnover likelihood. Implications for diversity management are discussed. Copyright © 2015 John Wiley & Sons, Ltd.     

Development and Implementation of Strategic Frameworks for Air Quality Management in the UK and the European Community

The UK and the EC have recognized that the application of national and EC policies alone may not be cost effective in improving air quality in some areas, especially in traffic-congested urban centres and along major road transport corridors. Consequently both have introduced new strategic frameworksfor air quality management.This paper outlines and compares the UK National Air Quality Strategy (NAQS) and the EC approach, set out in the Air Quality Framework and Daughter Directives. Both frameworks shift responsibility for reviewing, assessing and managing air quality on to local authorities. The UK considers the NAQS will provide the principal means of carrying out its commitments under the new EC framework.Local authorities in the UK have begun the review and assessment phase of the NAQS. This paper examines the support that central government has had to provide to local authorities to ensure the NAQS will be effective. It offers insights into what other Member States are likely to face when implementing their interpretation of the EC air quality management framework. The paper highlights that many UK local authorities lacked even basic air quality management capabilities when the NAQS was being formulated. Consequently the UK Government has had to expand the national pollution monitoring networks (this was achieved primarily by affiliating the growing number of local authority funded sites), commission new detailed urban emissions inventories, and develop and validate a suite of air quality dispersion models. Training events in air quality assessment techniques have had to be offered and many detailed guidance notes issued to ensure an appropriate and consistent interpretation of the NAQS. Some government initiatives to support the implementation of the NAQS suffered delays which initially caused some unnecessary uncertainties and inconsistencies amongst local authorities conducting their review and assessment of air quality. This points to the importance of the Governmentensuring that the support for the management phase of the NAQS will be in place in time. This includes providing additional pollution-control powers and reformulating transport and planning policies in order to integrate air quality management more fully.