Merit pay raises and organization‐based self‐esteem

We developed and tested a theory of the relationship between merit pay raises and organization‐based self‐esteem (OBSE) in a longitudinal study of hospital employees. We predicted that the positive relationship between merit pay raise size and OBSE would be stronger when pay‐for‐performance (PFP) perceptions were high and predicted further that this interaction would be stronger among older employees. As predicted, merit pay raises were not related to OBSE levels for younger employees, but, among older employees, larger merit raises increased OBSE when PFP perceptions were high and decreased OBSE when PFP perceptions were low. Implications of the study for merit pay theory and practice are addressed. Copyright © 2008 John Wiley & Sons, Ltd.     

Greenhouse gas balance for composting operations

The greenhouse gas (GHG) impact of composting a range of potential feedstocks was evaluated through a review of the existing literature with a focus on methane (CH(4)) avoidance by composting and GHG emissions during composting. The primary carbon credits associated with composting are through CH(4) avoidance when feedstocks are composted instead of landfilled (municipal solid waste and biosolids) or lagooned (animal manures). Methane generation potential is given based on total volatile solids, expected volatile solids destruction, and CH(4) generation from lab and field incubations. For example, a facility that composts an equal mixture of manure, newsprint, and food waste could conserve the equivalent of 3.1 Mg CO(2) per 1 dry Mg of feedstocks composted if feedstocks were diverted from anaerobic storage lagoons and landfills with no gas collection mechanisms. The composting process is a source of GHG emissions from the use of electricity and fossil fuels and through GHG emissions during composting. Greenhouse gas emissions during composting are highest for high-nitrogen materials with high moisture contents. These debits are minimal in comparison to avoidance credits and can be further minimized through the use of higher carbon:nitrogen feedstock mixtures and lower-moisture-content mixtures. Compost end use has the potential to generate carbon credits through avoidance and sequestration of carbon; however, these are highly project specific and need to be quantified on an individual project basis.     

Reducing Nonpoint Source Pollution Through Collaboration: Policies and Programs Across the U.S. States

Nonpoint source (NPS) pollution has emerged as the largest threat to water quality in the United States, influencing policy makers and resource managers to direct more attention toward NPS prevention and remediation. In response, the United States Environmental Protection Agency (USEPA) spent more than $204 million in fiscal year (FY) 2006 on the Clean Water Act’s Section 319 program to combat NPS pollution, much of it on the development and implementation of watershed-based plans. State governments have also increasingly allocated financial and technical resources to collaborative watershed efforts within their own borders to fight NPS pollution. With increased collaboration among the federal government, states, and citizens to combat NPS pollution, more information is needed to understand how public resources are being used, by whom, and for what, and what policy changes might improve effectiveness. Analysis from a 50-state study suggests that, in addition to the average 35% of all Section 319 funds per state that are passed on to collaborative watershed groups, 35 states have provided financial assistance beyond Section 319 funding to support collaborative watershed initiatives. State programs frequently provide technical assistance and training, in addition to financial resources, to encourage collaborative partnerships. Such assistance is typically granted in exchange for requirements to generate a watershed action plan and/or follow a mutually agreed upon work plan to address NPS pollution. Program managers indicated a need for greater fiscal resources and flexibility to achieve water quality goals.     

Characterization of methane emissions from five cold heavy oil production with sands (CHOPS) facilities

Cold heavy oil production with sands (CHOPS) is a common oil extraction method in the Canadian provinces of Alberta and Saskatchewan that can result in significant methane emissions due to annular venting. Little is known about the magnitude of these emissions, nor their contributions to the regional methane budget. Here the authors present the results of field measurements of methane emissions from CHOPS wells and compare them with self-reported venting rates. The tracer ratio method was used not only to analyze total site emissions but at one site it was also used to locate primary emission sources and quantify their contributions to the facility-wide emission rate, revealing the annular vent to be a dominant source. Emissions measured from five different CHOPS sites in Alberta showed large discrepancies between the measured and reported rates, with emissions being mainly underreported. These methane emission rates are placed in the context of current reporting procedures and the role that gas-oil ratio (GOR) measurements play in vented volume estimates. In addition to methane, emissions of higher hydrocarbons were also measured; a chemical “fingerprint” associated with CHOPS wells in this region reveals very low emission ratios of ethane, propane, and aromatics versus methane. The results of this study may inform future studies of CHOPS sites and aid in developing policy to mitigate regional methane emissions.

Implications: Methane measurements from cold heavy oil production with sand (CHOPS) sites identify annular venting to be a potentially major source of emissions at these facilities. The measured emission rates are generally larger than reported by operators, with uncertainty in the gas-oil ratio (GOR) possibly playing a large role in this discrepancy. These results have potential policy implications for reducing methane emissions in Alberta in order to achieve the Canadian government’s goal of reducing methane emissions by 40–45% below 2012 levels within 8 yr.     

Evaluation of the Design Features of Interactive Sea-Level Rise Viewers for Risk Communication

Interactive sea-level rise viewers (ISLRVs) are digital tools used to communicate about impacts of sea-level rise (SLR) and support decision-making. This study characterizes how ISLRVs communicate about SLR-related risks and provide decision-making support. It identifies key themes about fostering accurate mental models of SLR processes, informing about inundation likelihood, communicating about related social and ecological risks, and providing features users can apply to specific tasks. We present a framework for understanding this type of communication tool that designers can use to develop robust ISLRVs that can support audiences’ understanding and decision-making needs, and contribute to enhancement of coastal resiliency.     

Effect of Interfacial Modifiers on Mechanical and Physical Properties of the PHB Composite with High Wood Flour Content

To explore the commercial viability of Polyhydroxybutyrate (PHB)/wood flour (WF) composites, systems were produced at industry-standard levels of fiber loading. Further, four interfacial modifiers were selected to improve the mechanical properties of PHB/WF composites, including maleated PHB (PHB-g-MA), a low molecular weight epoxy, a low molecular weight polyester, and polymethylene-diphenyl-diisocyante (pMDI). Results showed that all modifiers resulted in improvements in tensile strength and modulus, however, pMDI showed the highest improvements. The pMDI modifier also improved water uptake of the composites. Study of the fracture surfaces showed signs of improved fiber bonding, as did morphological studies by dynamic mechanical analysis (DMA), and differential scanning calorimetry (DSC). Interpretation of the DSC and DMA results indicate possible reactions with lubricant, and interactions between PHB and wood fibers with the addition of pMDI.     

Exploring the origins of ‘social license to operate’ in the mining sector: Perspectives from governance and sustainability theories

In the mining sector, local communities have emerged as particularly important governance actors. Conventional approaches to mineral development no longer suffice for these communities, which have demanded a greater share of benefits and increased involvement in decision making. These trends have been spurred by the growth of the sustainable development paradigm and governance shifts that have increasingly transferred governing authority towards non-state actors. Accordingly, there is now widespread recognition that mineral developers need to gain a ‘social license to operate’ (SLO) from local communities in order to avoid potentially costly conflict and exposure to social risks. A social license can be considered to exist when a mining project is seen as having the ongoing approval and broad acceptance of society to conduct its activities. Due to the concept's relatively recent emergence, however, only a limited body of scholarship has developed around SLO. Drawing on examples from northern Canada, this paper uses governance and sustainability theories to conceptualize the origins of SLO in the mining sector and describe some of the associated implications. Further research is needed to determine governance arrangements which help facilitate establishment of SLO in different mineral development contexts.     

Implications of cation exchange on clay release and colloid-facilitated transport in porous media

Column experiments were conducted to study chemical factors that influence the release of clay (kaolinite and quartz minerals) from saturated Ottawa sand of different sizes (710,360, and 240 microm). A relatively minor enhancement of clay release occurred when the pH was increased (5.8 to 10) or the ionic strength (IS) was decreased to deionized (DI) water. In contrast, clay release was dramatically enhanced when monovalent Na+ was exchanged for multivalent cations (e.g., Ca2+ and Mg2+) on the clay and sand and then the solution IS was reduced to DI water. This solution chemistry sequence decreased the adhesive force acting on the clay as a result of an increase in the magnitude of the clay and sand zeta potential with cation exchange, and expansion of the double layer thickness with a decrease in IS to DI water. The amount of clay release was directly dependent on the Na+ concentration of the exchanging solution and on the initial clay content of the sand (0.026-0.054% of the total mass). These results clearly demonstrated the importance of the order and magnitude of the solution chemistry sequence on clay release. Column results and scanning electron microscope (SEM) images also indicated that the clay was reversibly retained on the sand, despite predictions of irreversible interaction in the primary minimum. One plausible explanation is that adsorbed cations increased the separation distance between the clay-solid interfaces as a result of repulsive hydration forces. A cleaning procedure was subsequently developed to remove clay via cation exchange and IS reduction; SEM images demonstrated the effectiveness of this approach. The transport of Cu2+ was then shown to be dramatically enhanced by an order of magnitude in peak concentration by adsorption on clays that were released following cation exchange and IS reduction.     

Understanding vulnerability in southern Africa: comparative findings using a multiple-stressor approach in South Africa and Malawi

Within southern Africa, many households are facing increasing pressures as they deal with multiple challenges such as low employment, high levels of disease, environmental resources under pressure and changing political landscapes. To respond to the needs of different individuals and households, it is important to define the nature of their vulnerability. An increasing amount of theoretical and empirical work on the concept of ‘vulnerability’ has led to a range of definitions, indicators and measurement tools, which have come to characterise this field of study. As a result, there is no one general consensus. This paper presents the results from the latest in a series of applied studies conducted since 2004 by a network of scientists working in southern Africa, aimed at refining the definition and application of the concept of vulnerability. The study employed a recently developed multiple-stressor model to guide the collection and analysis of data from three sites in South Africa and Malawi. In this paper, we identify and explore five key ‘symptoms’ of vulnerability emerging from our multi-country data and reflect on the usefulness of the model employed.