The infiltration of vehicle emissions into a house from the attached garage was studied for 16 homes of differing designs using the same extensively characterized vehicle at each home. Before the in-home measurement program, the cold-start and hot-start tailpipe emissions and hot-soak evaporative emissions from a 1993 Buick Regal were measured using standard vehicle emissions measurement methods. The emissions were chemically characterized for methane, nonmethane hydrocarbons (NMHC), and carbonyl compounds. The in-home measurements occurred over two winter seasons (1997-1998 and 1998-1999) in Ottawa, Ontario, Canada. Samples of indoor air and garage atmosphere were characterized for carbon monoxide, carbon dioxide, methane, NMHC, and carbonyl compounds. During the second year, real-time measurements of carbon, carbon dioxide, and total hydrocarbons were made to determine when and for how long the emissions plume infiltrates the house. Chemical mass balance modeling results using 31 NMHC species suggest that between 9 and 71% of the concentrations measured in the house during the hot-soak test and between 13 and 85% of the concentrations measured in the house during the cold-start test could be attributed to vehicle emissions infiltrating from the garage. In contrast, increases in carbonyl compound concentrations caused by the vehicle were difficult to detect above the already significant levels found in the houses. 相似文献
The need for statistical methodology in environmental and ecological applications has grown dramatically over the past few decades, to where targeted and/or specialized courses in environmental statistics are necessary at both the undergraduate and graduate levels. We discuss here the construction of such courses, and pose questions on the course development process for the statistical and environmental community. Our exposition is based upon our own experience with the design of a graduate environmental statistics course. 相似文献
Process representations critical to the phytoplankton and zooplankton submodels are described. These include constructs for: light- and nutrient-limitations and their interaction, temperature, consumption, and population-age structure. Values for key parameters are documented with reference to the literature on aquatic ecology and ecological modelling. Time-course relationships of the processes affecting the phytoplankton, zooplankton, phosphorus and nitrogen compartments are presented and discussed. These serve as additional documentation and are an important result of modelling synthesis. 相似文献
In this study, we investigated cadmium toxicity created by adsorption kinetics in several mixtures containing two types of multi-walled carbon nanotubes (COOH-MWCNT and NH2-MWCNT) and natural kaolinite. Characteristics of two types of MWCNTs were measured by zeta potential and ATR FT-IR graphs and TEM images. The solution of CNTs and kaolinite was tested to study Cd adsorption kinetics and mechanisms of differentiation-associated toxicity using Daphnia magna in a binary system (Cd–MWCNTs and Cd–kaolinite) and a ternary system (Cd–MWCNTs–kaolinite). In the binary system, Cd removal efficiency was nearly 100% and 40% for MWCNTs and kaolinite because of surface charge, respectively, with increasing sorbent concentration. In the ternary system, the trend of adsorption rate was similar to that of binary system. In comparison with percent mortality in the binary system, the solution in the ternary system showed higher toxicity due to the interaction of MWCNTs–kaolinite coagulated particles, thereby decreasing Cd adsorption onto CNTs and kaolinites. Overall, kaolinite can affect the adsorption process of Cd on MWCNTs in negative ways, depending on adsorption state. In conclusion, our studies suggest that kaolinite differs with adsorption ability of Cd by MWCNTs, and toxicity is likely to be produced by multivariable regression in the adsorption state.
Plant responses to abiotic stress can alter their response to biotic stress. We examined changes in the activity of several
defense proteins in response to powdery mildew infection of garlic mustard (Alliaria petiolata) in the greenhouse and in the field. Second, we examined the effects of water limitation on the same defense protein responses,
as well as on total soluble protein and glucose concentration, plant growth, and powdery mildew disease development. Similar
increases in the activity of peroxidase, chitinase, and β-1-3-glucanase were observed in leaves of plants with substantial
powdery mildew disease in both greenhouse- and field-grown plants. In the greenhouse, activities of chitinase and peroxidase
as well as total soluble protein and glucose concentrations generally increased with the degree of water limitation. In turn,
leaf growth and powdery mildew symptom development decreased as the degree of water limitation increased. This study revealed
that plant chemical responses to water limitation and powdery mildew disease can overlap to a large extent, which, in addition
to changing microenvironmental conditions and other indicators of plant quality, may underlie the ability of water limitation
to inhibit powdery mildew disease symptom development in this wild plant pathosystem. 相似文献
In this paper, a brief overview is presented of natural gas as a fuel resource with subsequent carbon capture and re-use as a means to facilitate reduction and eventual elimination of man-made carbon emissions. A particular focus is shale gas and, to a lesser extent, methane hydrates, with the former believed to provide the most reasonable alternative as a transitional fuel toward a low-carbon future. An emphasis is placed on the gradual elimination of fossil resource usage as a fuel over the coming 35 to 85 years and its eventual replacement with renewable resources and nuclear power. Furthermore, it is proposed that synthesis of chemical feedstocks from recycled carbon dioxide and hydrogen-rich materials should be undertaken for specific applications in the transport sector which require access to high energy density fuels. To achieve the latter, carbon dioxide capture is imperative and possible synthetic routes for chemical feedstock production are briefly reviewed. 相似文献
ABSTRACT: A mathematical solution based on porous media flow is developed for solute travel time to a well as affected by a leak around the upper part of the casing. Consider a well of radius 0.2 meters (m) penetrating, fully, a semiconfined aquifer of thickness 6 m with impermeable casing length of 4.5 m, and screened casing length 1.5 m. Around the upper 1.5 m of the impermeable casing length, there is a highly permeable region (a leak). The radius of influence of the well is 10 m. The porous flow medium has a hydraulic conductivity of 10 m/day and a porosity of 0.25. Between the water table and the water level in the well, there is a steady state pumped down head difference of 0.3 m. Solute travel time from a point at the bottom of the leak to the well is 2.33 days. If the leak is sealed (grouted), the travel time is 6.24 days. Examples of six different geometries are given. Laboratory studies verify the theory. The computations should be useful in the design and protection of water wells from solutes, such as from agriculture, industry, strip mines, or sanitary landfills. 相似文献