Cytotoxicity induced by the mixture components of nickel and poly aromatic hydrocarbons

Environmental Geochemistry and Health - Although particulate matter (PM) is composed of various chemicals, investigations regarding the toxicity that results from mixing the substances in PM are...     

A PROPOSED APPROACH TO COORDINATION OF WATER RESOURCE DEVELOPMENT AND ENVIRONMENTAL REGULATIONS1

ABSTRACT: The planning and developing of water resources to meet the country's needs for water supply, flood control, hydroelectric power, irrigation, and navigation now needs to take more account of environmental needs and regulations. Water resource development is often beneficial to the environment, but may also be harmful, as in cases involving salmon and various other endangered species. As a national objective, the environment must be preserved and in some cases restored; but how can this be done consistent with other national objectives, relating to life and welfare of human beings? This problem has aroused the concern of many engineers and water scientists. As a result, a national conference on this subject was held in Chicago in June 1998, as an integral part of ASCE's Annual Conference on Water Resources Planning and Management and the Annual Conference on Environmental Engineering. At the conclusion of that conference, a post-conference meeting was held by a group of prominent water resource practitioners. It was concluded at this meeting that action should be taken by our government to establish a new form of interagency approach, involving the states, as a means of coordination in cases of national importance.     

Consequence of altered nitrogen cycles in the coupled human and ecological system under changing climate: The need for long-term and site-based research

Anthropogenically derived nitrogen (N) has a central role in global environmental changes, including climate change, biodiversity loss, air pollution, greenhouse gas emission, water pollution, as well as food production and human health. Current understanding of the biogeochemical processes that govern the N cycle in coupled human–ecological systems around the globe is drawn largely from the long-term ecological monitoring and experimental studies. Here, we review spatial and temporal patterns and trends in reactive N emissions, and the interactions between N and other important elements that dictate their delivery from terrestrial to aquatic ecosystems, and the impacts of N on biodiversity and human society. Integrated international and long-term collaborative studies covering research gaps will reduce uncertainties and promote further understanding of the nitrogen cycle in various ecosystems.     

Modeling groundwater flow and its associated environmental problem in a lowland coastal plain: a first step towards a sustainable development plan

Groundwater is an important resource in the alluvial coastal lowland plains. In the Shiroishi lowland plain, southwestern Kyushu Island of Japan, land subsidence due to groundwater development has long been recognized as an environmental issue. Land subsidence can have several negative economic and social implications. In this study, an integrated numerical groundwater and land subsidence model, which combines a three-dimensional numerical groundwater flow model and a one-dimensional soil consolidation model, was used to simulate the dynamic groundwater flow and ground subsidence due to pumping. On the other hand, a groundwater optimization model was also formulated to search for an optimal safe yield of groundwater pumping without violating physical, environmental, social-economic constraints. The model results reveal that groundwater levels in the aquifers greatly vary from season to season in response to varying climatic and pumping conditions. Consequently, land subsidence has rapidly occurred throughout the area with the central prone in Shiroishi plain. The study also proposes a countermeasure against subsiding process in the area by means of numerical models. The optimization model result suggests that pumping can be increased in the northern part of the study area without leading to significant land subsidence.     

Combined toxicity of copper and phenol derivatives to Daphnia magna: effect of complexation reaction

The complexation of Cu with phenol was investigated in aqueous solution to find the changes in toxicity toward Daphnia magna in mixtures of copper and phenol derivatives and determine an appropriate prediction model for the toxicity of these mixtures. In the titration experiment, the results showed that phenol played an important role in the remarkable reduction of the Cu(2+) concentration, due to its complexation with Cu, with the subsequent reduction in the toxicity of aqueous mixtures containing both Cu and phenol. As a result, it was clearly demonstrated that Cu-phenol formed a non-toxic complex toward D. magna as the mortality declined, despite the addition of phenol to a fixed Cu concentration. Meanwhile, prediction of the combined toxicity for binary mixtures of Cu and 11 phenol derivatives more accurately followed an independent action model (p = 0.143, df = 124, and t = -1.475 in t-test) than an effect summation model (p approximately 0, df = 134, and t = 7.528 in t-test) due to the dissimilar modes of action and the complexation reactions between Cu and each of the phenolic compounds. Consequently, this study supports the importance of considering complexation reactions in assessing the combined toxicity for the formulation of water quality in mixtures of heavy metals and organic compounds, and in these cases, an independent action model was found to be appropriate.     

Low levels of persistent organic pollutants (POPs) in New Zealand eels reflect isolation from atmospheric sources

Polychlorinated biphenyls (PCBs) and organic pesticides (i.e., DDTs) were measured in long finned eels (Anguilla dieffenbachii) in 17 streams on the west coast of South Island, New Zealand. Very low levels of PCBs and low levels of ppDDE were found. The concentrations of PCBs and ppDDE were not correlated within sites indicating that different processes determined the levels of the two pollutants in New Zealand eels. The PCBs probably originate from atmospheric transport, ppDDE levels are determined by land use and are higher in agriculture areas. The low contamination level of these aquatic systems seems to be a function of a low input from both long and short-range transport as well as few local point sources. No correlation could be found between lipid content and persistent organic pollutants (POPs) concentration (as shown in previous studies) in the eels which could be explained by low and irregular intake of the pollutants.     

The effects of multiple beneficial management practices on hydrology and nutrient losses in a small watershed in the Canadian prairies

Most beneficial management practices (BMPs) recommended for reducing nutrient losses from agricultural land have been established and tested in temperate and humid regions. Previous studies on the effects of these BMPs in cold-climate regions, especially at the small watershed scale, are rare. In this study, runoff and water quality were monitored from 1999 to 2008 at the outlets of two subwatersheds in the South Tobacco Creek watershed in Manitoba, Canada. Five BMPs-a holding pond below a beef cattle overwintering feedlot, riparian zone and grassed waterway management, grazing restriction, perennial forage conversion, and nutrient management-were implemented in one of these two subwatersheds beginning in 2005. We determined that >80% of the N and P in runoff at the outlets of the two subwatersheds were lost in dissolved forms, ≈ 50% during snowmelt events and ≈ 33% during rainfall events. When all snowmelt- and rainfall-induced runoff events were considered, the five BMPs collectively decreased total N (TN) and total P (TP) exports in runoff at the treatment subwatershed outlet by 41 and 38%, respectively. The corresponding reductions in flow-weighted mean concentrations (FWMCs) were 43% for TN and 32% for TP. In most cases, similar reductions in exports and FWMCs were measured for both dissolved and particulate forms of N and P, and during both rainfall and snowmelt-induced runoff events. Indirect assessment suggests that retention of nutrients in the holding pond could account for as much as 63 and 57%, respectively, of the BMP-induced reductions in TN and TP exports at the treatment subwatershed outlet. The nutrient management BMP was estimated to have reduced N and P inputs on land by 36 and 59%, respectively, in part due to the lower rates of nutrient application to fields converted from annual crop to perennial forage. Overall, even though the proportional contributions of individual BMPs were not directly measured in this study, the collective reduction of nutrient losses from the five BMPs was substantial.     

What have we known so far for fluorescence staining and quantification of microplastics: A tutorial review

• Fluorescence staining provides a fast and easy method to quantify microplastics. • Factors that influence staining are summarized to obtain an optimum staining effect. • Natural organic matter can be stained by dye and interfere with quantification. • Fluorescence staining is applied in both field and laboratory studies. • Future work involves developing new dyes and automated image-analysis methods. Understanding the fate and toxicity of microplastics (MPs,<5 mm plastic particles) is limited by quantification methods. This paper summarizes the methods in use and presents new ones. First, sampling and pretreatment processes of MPs, including sample collection, digestion, density separation, and quality control are reviewed. Then the promising and convenient staining procedures and quantification methods for MPs using fluorescence dyes are reviewed. The factors that influence the staining of MPs, including their physicochemical properties, are summarized to provide an optimal operation procedure. In general, the digestion step is crucial to eliminate natural organic matter (NOM) to avoid interference in quantification. Chloroform was reported to be the most appropriate solvent, and 10–20 μg/mL are recommended as optimal dye concentrations. In addition, a heating and cooling procedure is recommended to maintain the fluorescence intensity of MPs for two months. After staining, a fluorescence microscope is usually used to characterize the morphology, mass, or number of MPs, but compositional analysis cannot be determined with it. These fluorescence staining methods have been implemented to study MP abundance, transport, and toxicity and have been combined with other chemical characterization techniques, such as Fourier transform infrared spectroscopy and Raman spectroscopy. More studies are needed to focus on the synthesis of novel dyes to avoid NOM’s interference. They need to be combined with other spectroscopic techniques to characterize plastic composition and to develop image-analysis methods. The stability of stained MPs needs to be improved.     

Thermochemical conversion of municipal solid waste into energy and hydrogen: a review

The rising global population is inducing a fast increase in the amount of municipal waste and, in turn, issues of rising cost and environmental pollution. Therefore, alternative treatments such as waste-to-energy should be developed in the context of the circular economy. Here, we review the conversion of municipal solid waste into energy using thermochemical methods such as gasification, combustion, pyrolysis and torrefaction. Energy yield depends on operating conditions and feedstock composition. For instance, torrefaction of municipal waste at 200 °C generates a heating value of 33.01 MJ/kg, while the co-pyrolysis of cereals and peanut waste yields a heating value of 31.44 MJ/kg at 540 °C. Gasification at 800 °C shows higher carbon conversion for plastics, of 94.48%, than for waste wood and grass pellets, of 70–75%. Integrating two or more thermochemical treatments is actually gaining high momentum due to higher energy yield. We also review reforming catalysts to enhance dihydrogen production, such as nickel on support materials such as CaTiO₃, SrTiO₃, BaTiO₃, Al₂O₃, TiO₃, MgO, ZrO₂. Techno-economic analysis, sensitivity analysis and life cycle assessment are discussed.