Hydrobiogeochemical Controls on Riparian Nutrient and Greenhouse Gas Dynamics: 10 Years Post‐Restoration

Little is known about the impact of agricultural legacy on subsurface biogeochemical processes in the years following restoration of riparian wetlands (WLs). More knowledge is also needed on the relative importance of seasons, precipitation events, and inputs of water and nutrients driving nitrogen (N), phosphorus (P), sulfur (S), and greenhouse gas (GHG) (N₂O, CO₂, CH₄) dynamics in these systems. This investigation of a riparian zone comprising a restored WL area and a nonrestored well‐drained alluvium (AL) area in the United States Midwest revealed that despite successful hydrological restoration a decade earlier, biogeochemical conditions in the WL area remained less anoxic than in natural WLs, and not significantly different from those in the AL area. No significant differences in N, P, S, and C compound concentrations or fluxes were observed between the AL and WL areas. Over the duration of the study, nitrate (NO₃^?) and soluble reactive phosphorus appeared to be primarily driven by hillslope contributions. Ammonium (NH₄⁺), sulfate (SO₄^2?), and CO₂ responded strongly to seasonal changes in biogeochemical conditions in the riparian zone, while N₂O and CH₄ fluxes were most influenced by large rewetting events. Overall, our results challenge overly simplistic assumptions derived from direct interpretation of redox thermodynamics, and show complex patterns of solutes and GHGs at the riparian zone scale.     

On‐Site Exposure to Treated Wastewater Effluent Has Subtle Effects on Male Fathead Minnows and Pronounced Effects on Carp

This study tested the hypotheses that (1) exposure to treated Water Reclamation Plant (WRP) effluent will induce biological effects in exposed fish that are consistent with environmental estrogen (EE) exposure; and (2) seasonal differences in effluent composition will moderate biological effects. We conducted seven on‐site exposures using a mobile laboratory. Total estrogenicity of effluents was 10‐ to 20‐fold higher during spring than in fall. Common EEs including steroid estrogens, alkylphenols, and bisphenol‐A were ubiquitous. An unusual spike in total estrogenicity identified a combined sewer overflow event. Fathead minnows (Pimephales promelas) responded to exposure with subtle changes in vitellogenin concentrations and secondary sex characteristics. An opportunity to assess a common carp (Cyprinus carpio) population permanently sustained inside the Stickney WRP revealed pronounced exposure effects, but also the resilience of biological organisms even under long‐term exposure. In contrast to other studies, no histopathological changes were found. The mobile exposure laboratory proved capable of maintaining U.S. Environmental Protection Agency‐recommended exposure conditions while providing flexibility for rapid deployment at multiple sites with minimal operational disruption. Further studies using this platform hold promise to resolve the convoluted interactions between complex effluents and inherent biological complexity.     

Economic use value of the Belize marine ecosystem: Potential risks and benefits from offshore oil exploration

The announcement of plans for exploratory oil drilling at a number of offshore sites in Belize raised concerns about the risks associated with drilling, particularly given the socio‐economic importance of the marine ecosystem. The current economic value of fisheries and marine ecotourism is estimated, along with the potential revenue from offshore oil and potential economic losses stemming from oil pollution, under various assumptions on risk and uncertainty. Marine fisheries and ecotourism are estimated to generate around US$ 183 million per year. Single‐year estimated maximum revenue is higher for oil extraction initially but quickly declines; during a 50 year (two generation) period, total discounted benefits from marine fisheries and ecotourism are estimated at US$ 5.1 billion, compared to US$ 3.2 billion from offshore oil revenue. Following a hypothetical oil spill, discounted losses in marine fisheries and ecotourism due to perception and ecological impacts are estimated at US$ 912 million, with clean‐up costs and capital losses of US$ 6.1‐10.4 billion. Considering the short extraction life of oil resources compared to fisheries and ecotourism, the difference in benefits increases substantially in favour of the latter with a longer time horizon. A recent public referendum resulted in a 98% vote against oil exploration and a subsequent annulment of oil concessions pending environmental impact assessments.     

An empirical assessment of the loose–tight leadership model: quantitative and qualitative analyses

Using questionnaire and interview data, this study attempted to find out whether the organizational loose (participative) and tight (directive) practices are compatible with or contradict each other. Using the theoretical framework of Sagie's ( 1997 ) loose–tight leadership approach, our hypotheses concerned the effects of both practices on the employee's work‐related attitudes, and the mediating role of two variables, cognitive (information sharing) and motivational (exerting effort), in these effects. Data were analysed using two methodological approaches, quantitative and qualitative. Based on a quantitative analysis of the questionnaires given to 101 professional employees of a textile company, partial support was provided for the study hypotheses. A qualitative analysis of in‐depth, semi‐structured interviews with all the employees (n = 20) in one of the company divisions led to similar conclusions. Specifically, we found that although the loose and tight practices affected work attitudes, the interviewees attributed more impact to the tight practice. In addition, none of the study variables mediated the loose impact on attitudes, whereas information sharing (but not exerting effort) mediated the influence of tight practice. Finally, the qualitative analysis revealed a deeper insight into the nature of both leader practices and their possible integration in the decision‐making processes in organizations. Copyright © 2002 John Wiley & Sons, Ltd.     

The process of burnout in white‐collar and blue‐collar jobs: eight‐year prospective study of exhaustion

This study tested three contrasting theories about the sequential process of the three dimensions of burnout (i.e., exhaustion, cynicism and professional efficacy) as measured by the Maslach Burnout Inventory—General Survey (MBI‐GS). The causal order of the burnout components was investigated by including job stressors as antecedents of burnout in structural equation models (LISREL). The predictive effect of exhaustion on burnout dimensions eight years later was also investigated. The longitudinal models were then tested in two occupational subgroups. The participants were 713 Finnish employees (415 white‐collar and 298 blue‐collar workers) from an international industry enterprise. The best fitting model of the associations between the three burnout dimensions was obtained by a path model where exhaustion predicted cynicism, and cynicism in turn predicted lack of professional efficacy. The symptoms of exhaustion were persistent over time. There were no differences between the two occupational groups in the process of burnout. Also the work‐related antecedents of burnout (job stressors) were very similar in both groups. Copyright © 2002 John Wiley & Sons, Ltd.     

Predicted Climate‐Driven Bird Distribution Changes and Forecasted Conservation Conflicts in a Neotropical Savanna

Abstract: Climate‐change scenarios project significant temperature changes for most of South America. We studied the potential impacts of predicted climate‐driven change on the distribution and conservation of 26 broad‐range birds from South America Cerrado biome (a savanna that also encompass tracts of grasslands and forests). We used 12 temperature or precipitation‐related bioclimatic variables, nine niche modeling techniques, three general circulation models, and two climate scenarios (for 2030, 2065, 2099) for each species to model distribution ranges. To reach a consensus scenario, we used an ensemble‐forecasting approach to obtain an average distribution for each species at each time interval. We estimated the range extent and shift of each species. Changes in range size varied across species and according to habitat dependency; future predicted range extent was negatively correlated with current predicted range extent in all scenarios. Evolution of range size under full or null dispersal scenarios varied among species from a 5% increase to an 80% decrease. The mean expected range shifts under null and full‐dispersal scenarios were 175 and 200 km, respectively (range 15–399 km), and the shift was usually toward southeastern Brazil. We predicted larger range contractions and longer range shifts for forest‐ and grassland‐dependent species than for savanna‐dependent birds. A negative correlation between current range extent and predicted range loss revealed that geographically restricted species may face stronger threat and become even rarer. The predicted southeasterly direction of range changes is cause for concern because ranges are predicted to shift to the most developed and populated region of Brazil. Also, southeastern Brazil is the least likely region to contain significant dispersal corridors, to allow expansion of Cerrado vegetation types, or to accommodate creation of new reserves.     

PREDICTIVE REAL TIME CONTROL OF SURCHARGED INTERCEPTORS: IMPACT OF SEVERAL CONTROL PARAMETERS1

ABSTRACT: A global predictive real time control strategy minimizing overflow volumes from combined sewers during rainfall was applied to control flows entering the Marigot interceptor (Laval, Canada) for 23 rain events that occurred in this urban area during the summer of 1989. Different surcharge intensities were allowed in the sewer. The duration of the control horizon as well as the location and number of control regulators were varied to assess the impact of these parameters on total overflow volumes and on control safety. Due to the high propagation speed of flow waves in pressurized conduits, it was found that five‐ minute control horizons were sufficient to ensure control performance and safety when important surcharges were permitted in the interceptor and when the controlled regulators were located where pressurized flow occurred. It was also found that it is possible to reduce the number of controlled regulators by placing them at locations intercepting the largest volumes of water during rain periods.     

Role of iron chemistry in controlling the release of pollutants from resuspended sediments

Aquatic sediments often contain a large number of chemical contaminants that are potential pollutants. It is often presumed that such contaminants are released to the water column during sediment resuspension and, in there, adversely impact aquatic life and other beneficial uses of the water. However, extensive laboratory and field studies of about 100 contaminated sediments from across the United States that specifically addressed this type of release showed that of about 30 common heavy metals, organic compounds, and other potential pollutants, only manganese II and ammonia were released to then remain in the water column after sediment resuspension. These results indicated that the chemistry of aqueous iron controls the availability of many contaminants in resuspended sediment. The formation of ferric hydroxide during sediment suspension into the water column, as a result of the reaction between ferrous iron in the sediments and dissolved oxygen in the water column, leads to rapid scavenging of many contaminants in the Fe(OH)₃ precipitate. The scavenged contaminants are redeposited in the sediments. This article reviews the role of the aqueous chemistry of iron as it relates to controlling the release of potential pollutants from resuspended sediments. © 2005 Wiley Periodicals, Inc.