Sorption, desorption, and degradation of (4-chloro-2-methylphenoxy)acetic acid in representative soils of the Danubian Lowland, Slovakia

Herbicide leaching through soil into groundwater greatly depends upon sorption-desorption and degradation phenomena. Batch adsorption, desorption and degradation experiments were performed with acidic herbicide MCPA and three soil types collected from their respective soil horizons. MCPA was found to be weakly sorbed by the soils with Freundlich coefficient values ranging from 0.37 to 1.03 mg^1−1/n kg⁻¹ L^1/n. It was shown that MCPA sorption positively correlated with soil organic carbon content, humic and fulvic acid carbon contents, and negatively with soil pH. The importance of soil organic matter in MCPA sorption by soils was also confirmed by performing sorption experiments after soil organic matter removal. MCPA sorption in these treated soils decreased by 37-100% compared to the original soils. A relatively large part of the sorbed MCPA was released from soils into aqueous solution after four successive desorption steps, although some hysteresis occurred during desorption of MCPA from all soils. Both sorption and desorption were depth-dependent, the A soil horizons exhibited higher retention capacity of the herbicide than B or C soil horizons. Generally, MCPA sorption decreased in the presence of phosphate and low molecular weight organic acids. Degradation of MCPA was faster in the A soil horizons than the corresponding B or C soil horizons with half-life values ranging from 4.9 to 9.6 d in topsoils and from 11.6 to 23.4 d in subsoils.     

Approaches to correct for double counting in tiered hybrid life cycle inventories

This paper presents an approach for inventory compilation and adjustment of double counting in tiered hybrid life cycle inventories (LCIs). The combination of input–output and physical inventory data on coefficient level is a convenient way of constructing a hybrid LCI that has both good detail and completeness. The proposed approach formalizes how to deal with partially overlapping data in inventory compilation. This particular approach requires that the issue of double counting is resolved in a consistent manner. Algorithms for identifying and adjusting for double counting are developed. Identification is performed based on a structural path analysis (SPA). Two algorithms for adjustment are presented. The first method is relatively simple to implement but has limitations to its applicability when performing a detailed assessment. The second method is more complex to implement but provides results that allow for more comprehensive structural inventory analysis. Numerical examples are provided in Appendix.     

The role of weekly high‐activated positive mood,context, and personality in innovative work behavior: A multilevel and interactional model

This article proposed and tested a multilevel and interactional model of individual innovation in which weekly moods represent a core construct between context, personality, and innovative work behavior. Adopting the circumplex model of affect, innovative work behavior is proposed as resulting from weekly positive and high‐activated mood. Furthermore, drawing on the Big Five model of personality and cognitive appraisal theory, openness to experience and support for innovation are proposed as individual and contextual variables, respectively, which interplay in this process. Openness to experience interacts with support for innovation leading to high‐activated positive mood. Furthermore, openness interacts with these feelings leading to greater levels of innovative work behavior. Overall, the model entails a moderated mediation process where weekly high‐activated positive mood represents a crucial variable for transforming contextual and individual resources into innovative outcomes. These propositions were tested and supported using a diary methodology and multilevel structural equation modeling, on the basis of 893 observations of innovative work behavior and moods nested in 10 weekly waves of data. This information was collected from 92 individuals of diverse occupations employed in 73 distinct companies. Theoretical and practical implications are discussed. Copyright © 2013 John Wiley & Sons, Ltd.     

Air infiltration measurements in a home using a convenient perfluorocarbon tracer technique

Using miniature perfluorocarbon tracer (PFT) sources and miniature passive samplers, both about the size of a cigarette, tests conducted in the laboratory and in a typical home successfully demonstrated the utility of the PFT kit as a means for implementing wide-scale infiltration measurements in homes. The PFT diffusion plug source, an elastomer containing a dissolved perfluorocarbon compound, was shown to emit vapors at the rate of about 0.1 to 5 nL/min, providing steady-state concentrations in a home of about 1 to 10 pL/L, i.e., parts per trillion by volume, when one source is deployed for each 300–500 ft² (28–46 m²) of living space. The emission rate from the diffusion source was predictable, but its dependence on both temperature and time suggested the development of alternative approaches. One such alternative, a liquid PFT permeation source, had emission rates which could be tailored over the range 10–20 nL/min, were independent of age for as long as the liquid remained ( 5 yr), and had significantly lower temperature dependence. A number of passive adsorption tube samplers performed reproducibly and identically (to within ±2%–3%) in laboratory tests. Together with a programmable tracer sampler, the miniature diffusion sources and samplers were deployed in a typical home; six PFT sources were uniformly deployed, three on each level of a two-story house. Multiple location sampling, as well as sampling in rooms with and without a miniature source, demonstrated that even in a house without forced-air circulation, a well-mixed modeling approach is justified. Analyses of the tracer samplers were performed back in the laboratory with an automatic electron-capture gas-chromatography system. The effects of the inside/outside temperature differential, as well as that of an open fireplace compared with a wood-burning stove, on the measured air infiltration rates were clearly demonstrated. Comparisons of the PFT tracer method with that of the SF₆ tracer decay approach showed the results of the two methods to be identical within experimental precision. With this miniature source and sampling tracer kit, infiltration rates in the range 0.2–5 air changes per hour can be measured over time-averaged periods of as little as 1 day up to several years.     

Culture as an environmental context for careers

Cultural factors influence career patterns in a variety of ways. Societal, occupational, and organizational cultures influence the structure of the external career, prestige associated with given careers, the legitimacy of certain motives underlying careers, success criteria, the clarity of the career concept itself, and the importance attached to career versus family and self development. How career occupants view their careers and the degree of variation in such views within given societies, occupations, and organizations is also culturally patterned. Both managers and career researchers must become more familiar with these cultural influences.     

National and global greenhouse gas dynamics of different forest management and wood use scenarios: a model-based assessment

An increased use of wood products and an adequate management of forests can help to mitigate climate change. However, planning horizons and response time to changes in forest management are usually long and the respective GHG effects related to the use of wood depend on the availability of harvested wood. Therefore, an integral long-term strategic approach is required to formulate the most effective forest and wood management strategies for mitigating climate change.The greenhouse gas (GHG) dynamics related to the production, use and disposal of wood products are manifold and show a complex time pattern. On the one hand, wood products can be considered as a carbon pool, as is the forest itself. On the other hand, an increased use of wood can lead to the substitution of usually more energy-intense materials and to the substitution of fossil fuels when the thermal energy of wood is recovered. Country-specific import/export flows of wood products and their alternative products as well as their processing stage have to be considered if substitution effects are assessed on a national basis.We present an integral model-based approach to evaluate the GHG impacts of various forest management and wood use scenarios. Our approach allows us to analyse the complex temporal and spatial patterns of GHG emissions and removals including trade-offs of different forest management and wood use strategies. This study shows that the contributions of the forestry and timber sector to mitigate climate change can be optimized with the following key recommendations: (1) the maximum possible, sustainable increment should be generated in the forest, taking into account biodiversity conservation as well as the long-term preservation of soil quality and growth performance; (2) this increment should be harvested continuously; (3) the harvested wood should be processed in accordance with the principle of cascade use, i.e. first be used as a material as long as possible, preferably in structural components; (4) waste wood that is not suitable for further use should be used to generate energy. Political strategies to solely increase the use of wood as a biofuel cannot be considered efficient from a climate perspective; (5) forest management strategies to enhance carbon sinks in forests via reduced harvesting are not only ineffective because of a compensatory increase in fossil fuel consumption for the production of non-wooden products and thermal energy but also because of the Kyoto-“cap” that limits the accountability of GHG removals by sinks under Article 3.3 and 3.4, at least for the first commitment period; (6) the effect of substitution through the material and energy use of wood is more significant and sustained as compared with the stock effects in wood products, which tend towards new steady-state flow equilibria with no further increase of C stocks; (7) from a global perspective, the effect of material substitution exceeds that of energy recovery from wood. In the Swiss context, however, the energy recovery from wood generates a greater substitution effect than material substitution.     

The case for consumption-based accounting of greenhouse gas emissions to promote local climate action

One of the challenges faced by local governments in the work with municipal climate action plans concerns accounting for the greenhouse gas (GHG) emissions—what emissions should be targeted, development of emissions over time, and how to effectively measure the success of local climate action. In this paper, we present challenges in developing a GHG emissions inventory related to the provision of municipal services. We argue that a consumption-based perspective, illustrated through the use of the carbon footprint (CF), rather than more conventional production-based inventory, provides a more useful and less misleading indicator. We present an analysis of the CF of municipal services provided by the city of Trondheim. The use of data directly from the city's accounting system ensures a reliable calculation of indirect emissions, and, with some minor modifications, also accurate data on direct emissions. Our analysis shows that approximately 93 percent of the total CF of municipal services is indirect emissions, located in upstream paths, underlining the need of introducing consumption-based indicators that takes into account upstream GHG emissions.