The Roles of Photooxidation and Biodegradation in Long-term Weathering of Crude and Heavy Fuel Oils

Although spilled oil is subject to a range of natural processes, only combustion, photooxidation and biodegradation destroy hydrocarbons and remove them from the biosphere. We present laboratory data that demonstrate the molecular preferences of these processes, and then examine some oil residues collected from previously documented releases to confirm the important roles that these processes play in removing spilled oil from both marine and terrestrial environments.     

Toxicity Evaluation with the Microtox Test to Assess the Impact of In Situ Oiled Shoreline Treatment Options: Natural Attenuation and Sediment Relocation

Changes in the toxicity levels of beach sediment, nearshore water, and bottom sediment samples were monitored with the Microtox^® Test to evaluate the two in situ oil spill treatment options of natural attenuation (natural recovery--no treatment) and sediment relocation (surf washing). During a series of field trials, IF-30 fuel oil was intentionally sprayed onto the surface of three mixed sediment (pebble and sand) beaches on the island of Spitsbergen, Svalbard, Norway (78°56^′ N, 16°45^′ E). At a low wave-energy site (Site 1 with a 3-km wind fetch), where oil was stranded within the zone of normal wave action, residual oil concentrations and beach sediment toxicity levels were significantly reduced by both options in less than five days. At Site 3, a higher wave-energy site with a 40-km wind fetch, oil was intentionally stranded on the beach face in the upper intertidal/supratidal zones, above the level of normal wave activity. At this site under these experimental conditions, sediment relocation was effective in accelerating the removal of the oil from the sediments and reducing the Microtox^® Test toxicity response to background levels. In the untreated (natural attenuation) plot at this site, the fraction of residual oil remaining within the beach sediments after one year (70%) continued to generate a toxic response. Chemical and toxicological analyses of nearshore sediment and sediment-trap samples at both sites confirmed that oil and suspended mineral fines were effectively dispersed into the surrounding environment by the in situ treatments. In terms of secondary potential detrimental effects from the release of stranded oil from the beaches, the toxicity level (Microtox^® Test) of adjacent nearshore sediment samples did not exceed the Canadian regulatory limit for dredged spoils destined for ocean disposal.     

SPATIALLY EXPLICIT HYDROLOGIC MODELING OF LAND USE CHANGE1

ABSTRACT: Using a Geographic Information System (GIS), a method is presented to develop a spatially explicit time series of land use in an urbanizing watershed. The method is prefaced on the existence of independent observations of land use at different times and data that describes the spatial‐temporal land use transition characteristics of the watershed between these two points in time. A method is then presented to generalize the TR‐55 graphical method, a common lumped hydrologic model for estimating peak discharge, for use in a spatially explicit scheme. This scheme predicts peak discharge throughout a watershed, rather than at a single selected watershed outlet. Coupling these two methods allows the engineer to model both the temporal and spatial evolution of peak discharge for the watershed. An illustrative watershed in a suburban area of Washington, DC is selected to demonstrate the methods. The model results from these analyses are presented graphically to highlight the complex features in peak discharge behavior that exist both spatially, as a function of position within the watershed drainage network, and temporally, as the watershed undergoes urbanization. These features are not commonly noted in most hydrologic analyses but are captured in these analyses because of the high spatial and temporal resolution of the methods presented. The physical implications of the modeled results are discussed in the context of the information content of a stream gauge located at the overall outlet of the illustrative watershed. This work shows that the common practice of transposition of gauge information to locations internal to the watershed would neglect internal variability in peak discharge behavior, and could potentially lead to the determination of inappropriate design discharges.     

HYDROLOGICAL AND GEOCHEMICAL TRENDS AND PATTERNS IN THE UPPER RIO GRANDE, 1975 TO 19991

ABSTRACT: Hydrological and geochemical spatial patterns and temporal trends were analyzed using U.S. Geological Survey (USGS) water quality data collected from 1975 to 1999 along the uppermost 600 km of the Rio Grande in Colorado and New Mexico. Data on discharge, specific conductivity (SC), total dissolved solids (TDS), pH, Ca²⁺, Na⁺, Mg²⁺, K⁺, HCO₃^?, SO₄^2‐, Cl^?, F^?, and SiO₂ came from six USGS stations ranging from the Colorado‐New Mexico border to below Albuquerque, New Mexico. Linear regression, Kendall's S, and Seasonal Kendall's S’ were used to detect trends, and ANOVA was used to analyze spatial differences between stations. Statistically significant increasing trends occurred in SC, TDS, Ca²⁺, Na⁺, Mg²⁺, K⁺, Cl^?, and F^?in the uppermost reaches, and significant decreasing trends of SC, TDS, Ca²⁺, Mg²⁺, K⁺, HCO₃^?, and SO₄^2‐occurred at the lower stations around Albuquerque. Both fluoride concentrations and pH values increased at and below Albuquerque over the study period. Discharge data show an increasing trend across all stations. Spatially, data for dissolved substances show generally linear upstream to downstream increases in concentrations in the upper four stations, with several notable nonlinear increases at and below Albuquerque (SC, TDS, Na⁺, Cl^?). Significant increases in pH appear at and below Albuquerque, relative to upstream stations, probably due to improved sewage treatment.     

A test and refinement of the equity sensitivity construct

This paper reports results from two studies that test a refinement of the equity sensitivity construct first in an experimental setting and second in a field setting. Results from Study 1 show that benevolents express tolerance for both overreward and underreward relative to entitleds and equity sensitives and that benevolents report relatively high levels of satisfaction regardless of reward condition. Study 1 results also show that manipulation of outcomes produce a more dramatic effect on satisfaction than does manipulation of inputs. Results from Study 2 reveal significantly different exchange ideologies for benevolents and entitleds and show that entitleds place more importance on pay whereas benevolents place more importance on the work itself. For both benevolents and entitleds, there is a positive correlation between assessments of distributive justice and job satisfaction. Implication of the findings both for equity theory research and the practice of management are discussed.     

Costs and benefits of urban erosion and sediment control: The North Carolina experience

The EPA’s new nonpoint source pollution control requirements will soon institutionalize urban erosion and sediment pollution control practices nationwide. The public and private sector costs and social benefits associated with North Carolina’s program (one of the strongest programs in the country in terms of implementation authority, staffing levels, and comprehensiveness of coverage) are examined to provide general policy guidance on questions relating to the likely burden the new best management practices will have on the development industry, the likely costs and benefits of such a program, and the feasibility of running a program on a cost recovery basis. We found that urban erosion and sediment control requirements were not particularly burdensome to the development industry (adding about 4% on average to development costs). Public-sector program costs ranged between $2.4 and $4.8 million in fiscal year 1989. Our contingent valuation survey suggests that urban households in North Carolina are willing to pay somewhere between $7.1 and $14.2 million a year to maintain current levels of sediment pollution control. Our benefit-cost analysis suggests that the overall ratio is likely to be positive, although a definitive figure is elusive. Lastly, we found that several North Carolina localities have cost recovery fee systems that are at least partially self-financing. This article is based on research by the authors for the North Carolina Department of Environment, Health and Natural Resources (DEHNR). The views are those of the research team and do not necessarily reflect the position of DEHNR.     

State wetlands and riparian area protection programs

The protection of wetlands and riparian areas has emerged as an important environmental planning issue. In the United States, several federal and state laws have been enacted to protect wetlands and riparian areas. Specifically, the federal Clean Water Act includes protection requirements in Sections 301 and 303 for state water quality standards, Section 401 for state certification of federal actions (projects, permits, and licenses), and Section 404 for dredge and fill permits. The Section 401 water quality state certification element has been called the “sleeping giant” of wetlands protection because it empowers state officials to veto or condition federally permitted or licensed activities that do not comply with state water quality standards. State officials have used this power infrequently. The purpose of this research was to analyze the effectiveness of state wetland and riparian programs. Contacts were established with officials in each state and in the national and regional offices of key federal agencies. Based on interviews and on a review of federal and state laws, state program effectiveness was analyzed. From this analysis, several problems and opportunities facing state wetland protection efforts are presented.     

The demand for site-specific recreational activities: A characteristics approach

A model of constrained utility maximizing behavior is developed to explain how a representative individual allocates his ski days among alternative sites. The physical characteristics of the ski areas and the individual's skiing ability are explicit arguments in the utility function; the budget allocation is given along with the parametric costs to ski (including travel costs, entrance fees, equipment costs, and the opportunity cost of his time). Shares (a site's share being the proportion of ski days that the individual spends at that site) are derived and assumed multinomially distributed, a stochastic specification which maintains the inherent properties of the shares. Maximum likelihood estimation confirms the basic hypothesis that costs, ability, and characteristics all are important determinants of the sites' shares. The model explains a large proportion of the skier's allocation of ski days. A multinomial logit model of skier behavior is also developed and maximum likelihood estimates of its parameters are obtained. Examination of the summary statistics from my model and the logit model indicates that my model predicts the skier's choice of sites better than the logit model.     

Sustainable oil-in-water analysis using a supercritical fluid carbon dioxide extraction system directly interfaced with infrared spectroscopy

A direct aqueous supercritical fluid extraction (SFE) system using carbon dioxide provides a sustainable means by which a vast range of industries may continue to depend on well established infrared (IR) techniques to determine oil-in-water. The SFE-IR method provides an environmentally friendly substitute for current national standard IR reference methods for measuring oil-in-water that rely on using increasingly restricted ozone depleting solvents whose manufacture is being phased out in accordance with international law. The SFE-IR analysis of a 500 mL water sample can be accomplished in 15 min. A rapid on-line SFE-IR calibration method has been implemented. With this calibration method, SFE-IR accuracy for determining diesel oil in 500 mL spiked water samples using single wave number measurement was 86.0%–98.8% with precision (RSD) ranging from 2.5%–7.0%. Using a general purpose calculation which involves measuring infrared absorbance values at three di erent wave numbers, SFE-IR method accuracy for determining diesel oil in 500 mL spiked water samples was 83.7%–92.2% with RSD 1.0%–9.3%. Data is presented that indicates current long established national standard IR reference methods involving three wave number calculations should be reviewed since, without careful consideration, the inclusion of calculated aromatic hydrocarbon species contributions to final oil-in-water concentration values may provide less accurate results.