Evaluation of a sustainable remediation option: Beneficial reuse of petroleum-contaminated sediment as an energy source

The characteristics of petroleum-contaminated sediment (PCS) have been evaluated to assess whether the practice of its beneficial reuse as a sole or supplemental energy source is sustainable relative to other sediment remediation options such as monitored natural recovery (MNR), capping, or off-site disposal. Some of these remediation options for PCS are energy-intensive and/or require land utilization. The energy and compositional analysis results indicate a low carbon content (15–17%(wt)) and corresponding low energy values of 5,200 kJ/kg (2,200 Btu/lb) to 5,600 kJ/kg (2,400 Btu/lb). However, given other decision-making criteria, the sediment may contain enough value to be added as a supplemental fuel given that it is normally considered a waste product and is readily available.

The thermogravimetric profiles obtained under both combustion and pyrolytic conditions showed that the sulfur contents were comparable to typical low sulfur bituminous or lignite coals found in the United States, and most of the volatiles could be vaporized below 750°C. The heavy metal concentrations determined before and after combustion of the PCS indicated that further engineering controls may be required for mercury, arsenic, and lead. Due to the potential for reduction of public health and environmental threats, potential economic savings, and conservation of natural resources (petroleum and land), removal of PCS by dredging and beneficial reuse as a supplemental fuel clearly has merit to be considered as a sustainable remediation option.

Implications: This study will provide a logical evaluation process to determine whether petroleum-contaminated sediment can be reused as an energy source. The energy and emissions values were determined and evaluated whether the sediment could be combusted for viable and sustainable use, considering several factors pertinent to evaluate in the remediation decision process. Various analysis methods were employed to determine elemental compositions, heating values, thermal and emission characteristics. This evaluation process may be used as a general methodology for the determination of petroleum-contaminated sediment as a supplemental fuel that may have merit to be considered as a sustainable remediation option.     

Removal of manganese and zinc from Kahrizak landfill leachate using daily cover soil and lime

The possibility of in situ removal of heavy metals found in leachate generated at municipal solid waste landfills was studied through amendment of daily cover soil. Kahrizak landfill, which receives the waste generated at Tehran, was selected as the source of leachate and soil samples. Manganese and zinc were selected in this study. The soil sample taken from the Kahrizak site contained about 17% clay, which was presumed to have significant capability for removing manganese and zinc. This capability was assumed to be enhanced further through the addition of lime and consequently to improve the potential for chemical precipitation of the selected metals. The in situ removal experiment was accomplished through a set of seven columns filled with the sampled soil with varying contents of lime (i.e., from 0% to 6% by dry weight). Fresh leachate of low pH was added to the columns on a daily basis. Concentrations of manganese and zinc were measured in the influent and effluent during 40 days when biological clogging resulted in a condition of almost no outflow in the columns. The results indicated a substantial increase in removal efficiency through the addition of lime to the daily cover soil. Desorption resulting from the low pH of fresh leachate occurs at later stages compared to the column with no lime addition.     

Characterization of particulate matter and gaseous emissions of a C-130H aircraft

The gaseous and nonvolatile particulate matter (PM) emissions of two T56-A-15 turboprop engines of a C-130H aircraft stationed at the 123rd Airlift Wing in the Kentucky Air National Guard were characterized. The emissions campaign supports the Strategic Environmental Research and Development Program (SERDP) project WP-1401 to determine emissions factors from military aircraft. The purpose of the project is to develop a comprehensive emissions measurement program using both conventional and advanced techniques to determine emissions factors of pollutants, and to investigate the spatial and temporal evolutions of the exhaust plumes from fixed and rotating wing military aircraft. Standard practices for the measurement of gaseous emissions from aircraft have been well established; however, there is no certified methodology for the measurement of aircraft PM emissions. In this study, several conventional instruments were used to physically characterize and quantify the PM emissions from the two turboprop engines. Emissions samples were extracted from the engine exit plane and transported to the analytical instrumentation via heated lines. Multiple sampling probes were used to assess the spatial variation and obtain a representative average of the engine emissions. Particle concentrations, size distributions, and mass emissions were measured using commercially available aerosol instruments. Engine smoke numbers were determined using established Society of Automotive Engineers (SAE) practices, and gaseous species were quantified via a Fourier-transform infrared-based gas analyzer. The engines were tested at five power settings, from idle to take-off power, to cover a wide range of operating conditions. Average corrected particle numbers (PNs) of (6.4-14.3) x 10(7) particles per cm3 and PN emission indices (EI) from 3.5 x 10(15) to 10.0 x 10(15) particles per kg-fuel were observed. The highest PN EI were observed for the idle power conditions. The mean particle diameter varied between 50 nm at idle to 70 nm at maximum engine power. PM mass EI ranged from 1.6 to 3.5 g/kg-fuel for the conditions tested, which are in agreement with previous T56 engine measurements using other techniques. Additional PM data, smoke numbers, and gaseous emissions will be presented and discussed.     

Evaluation of in situ steam‐injection processes for reduction of petroleum compounds within an abandoned canal

A conceptual approach of a novel application of in‐situ thermal processes that would either use a steam injection process or a steam/surfactant injection process was considered to remediate petroleum contaminated sediment residing in an abandoned canal. Laboratory tests were conducted in an attempt to volatilize or mobilize contaminants of concern (selected polycyclic aromatic hydrocarbons [PAHs]) from the contaminated sediment into a phase that could be physically removed. The processes were operated above ambient temperature and pressure in an attempt to increase the removal of the contaminants of concern from the sediment. The ability of both the steam injection process and the steam/surfactant process to remove PAHs from the sediment was considered ineffective; as only two of the seventeen selected PAHs (naphthalene and C1 naphthalene) were associated with a percentage mass reduction greater than 34% for both treatments (four trials). The steam/surfactant injection process generally resulted in higher reductions than the steam injection process, but had larger variances within the two trials using the treatment type. This preliminary evaluation suggests that steam‐based injection processes for removing petroleum contamination from this canal sediment, using the surfactants selected, equipment set‐up, and operating conditions studied, would be considered ineffective. © 2010 Wiley Periodicals, Inc. *

1 This article is a U.S. Government work and, as such, is in the public domain of the United States of America.

     

Contrasting Lumped and Distributed Hydrology Models for Estimating Climate Change Impacts on California Watersheds1

Maurer, Edwin P., Levi D. Brekke, and Tom Pruitt, 2010. Contrasting Lumped and Distributed Hydrology Models for Estimating Climate Change Impacts on California Watersheds. Journal of the American Water Resources Association (JAWRA) 46(5):1024–1035. DOI: 10.1111/j.1752-1688.2010.00473.x Abstract: We compare the projected changes to streamflows for three Sierra Nevada rivers using statistically downscaled output from 22 global climate projections. The downscaled meteorological data are used to drive two hydrology models: the Sacramento Soil Moisture Accounting model and the variable infiltration capacity model. These two models differ in their spatial resolution, computational time step, and degree and objective of calibration, thus producing significantly different simulations of current and future streamflow. However, the projected percentage changes in monthly streamflows through mid-21st Century generally did not differ, with the exceptions of streamflow during low flow months, and extreme low flows. These findings suggest that for physically based hydrology models applied to snow-dominated basins in Mediterranean climate regimes like the Sierra Nevada, California, model formulation, resolution, and calibration are secondary factors for estimating projected changes in extreme flows (seasonal or daily). For low flows, hydrology model selection and calibration can be significant factors in assessing impacts of projected climate change.     

Current status of agricultural and rural non-point source Pollution assessment in China

Estimates of non-point source (NPS) contribution to total water pollution in China range up to 81% for nitrogen and to 93% for phosphorus. We believe these values are too high, reflecting (a) misuse of estimation techniques that were developed in America under very different conditions and (b) lack of specificity on what is included as NPS. We compare primary methods used for NPS estimation in China with their use in America. Two observations are especially notable: empirical research is limited and does not provide an adequate basis for calibrating models nor for deriving export coefficients; the Chinese agricultural situation is so different than that of the United States that empirical data produced in America, as a basis for applying estimation techniques to rural NPS in China, often do not apply. We propose a set of national research and policy initiatives for future NPS research in China.     

Effect of hydrogen addition on performance,emission, and combustion characteristics of Deccan hemp oil and its methyl ester–fuelled CI engine

Environmental Science and Pollution Research - A vegetable oil–fueled diesel engine operation is characterized by low brake thermal efficiency and relatively high smoke emission. Conversion...     

Toxicokinetic study of dioxins and furans in laying chickens

Since foodstuffs from animal origin and particularly poultry products have been pointed out several times as reservoir of dioxins and related compounds, notably in Belgium few years ago, food chain safety issues appeared. Although food chain contamination incidents occurred many times through contaminated feedstuffs consumption in commercial chicken farms, very few studies have been carried out on transfer of dioxins and related compounds from commercial feed to hens. The present work continues a preliminary study on dioxin transfer in laying chickens carried out in our lab and available on-line on November 2004 in Environment International. In this work, absorption of dioxins were not preferential for 2,3,7,8-substituted congeners, increase with increasing number of chlorines, and was not linearly dependent of the octanol/water partition. Only 2,3,7,8-congeners were found in all organs studied, and these latter showed the same congener profile and similar lipid-normalized concentration, except for the liver. Abdominal fat and liver seemed to be the major storage sites and the liver preferentially retained highly chlorinated congeners. Unfortunately in this previous trial, laying process stopped very early for unknown reason leading to a considerable lost of information. In the present toxicokinetic study, more complete gastrointestinal absorption, excretion in eggs and bioaccumulation of dioxins in different tissues were investigated in chickens fed for 14 weeks with a 9 ng TEQ/kg contaminated feed. Stable levels were reached after 7 weeks in excreta and 9 weeks in eggs. During the whole trial, gastrointestinal absorption ranged between 41% and 91% depending on the congener. At steady state conditions, excretion of 1,2,3,4,6,7,8-HpCDD, OCDD, 1,2,3,4,6,7,8-HpCDF and OCDF exceeded 100% demonstrating excretion from tissues of these congeners which were also the most abundant in feed. 1,2,3,7,8-PeCDD, 1,2,3,7,8-PeCDF, 2,3,4,7,8-PeCDF, 1,2,3,6,7,8-HxCDF, 1,2,3,7,8,9-HxCDF and 2,3,4,6,7,8-HxCDF seemed to be metabolized more efficiently. Lipid adjusted concentrations and pattern were unexpectedly similar in the abdominal fat and the liver. On the contrary, eggs and breast muscles showed different pattern with higher level for high chlorinated congeners. When extrapolating our results, we found that a feed containing 0.750 ng TEQ/kg of dioxins (European norm for feedstuff) would cause a level lower than the maximum threshold level of 3 pg TEQ/g fat for chicken eggs fixed by European Communities. Nevertheless, a concentration lower than 0.6 ng TEQ/kg in feed would be needed to produce breast muscles less contaminated than 2 pg TEQ/g fat authorized in European.     

An agent based evacuation model utilising hybrid space discretisation

Egress models typically use one of three methods to represent the physical space in which the agents move: coarse network, fine network or continuous. In this work, we present a novel approach to represent space, which we call the ‘Hybrid Spatial Discretisation’ (HSD), in which all three spatial representations can be utilised to represent the physical space of the geometry within a single integrated software tool. The aim of the HSD approach is to encompass the benefits of the three spatial representation methods and maximise computational efficiency while providing an optimal environment to represent the movement and interaction of agents.