CO2-free paper?

Black liquor gasification–combined cycle (BLGCC) is a new technology that has the potential to increase electricity production of a chemical pulping mill. Increased electricity generation in combination with the potential to use biomass (e.g. bark, hog fuel) more efficiently can result in increased power output compared to the conventional Tomlinson-boiler. Because the BLGCC enables an integrated pulp and paper mill to produce excess power, it can offset electricity produced by power plants. This may lead to reduction of the net-CO₂ emissions. The impact of BLGCC to offset CO₂ emissions from the pulp and paper industry is studied. We focus on two different plant designs and compare the situation in Sweden and the US. The CO₂ emissions are studied as function of the share of recycled fibre used to make the paper. The study shows that under specific conditions the production of “CO₂-free paper” is possible. First, energy efficiency in pulp and paper mills needs to be improved to allow the export of sufficient power to offset emissions from fossil fuels used in boilers and other equipment. Secondly, the net-CO₂ emission per ton of paper depends strongly on the emission reduction credits for electricity export, and hence on the country or grid to which the paper mill is connected. Thirdly, supplemental use of biomass to replace fossil fuel inputs is important to reduce the overall emissions of the pulp and paper industry.     

Innovative aspects of environmental chemistry and technology regarding air,water, and soil pollution

Environmental Science and Pollution Research -     

Challenges in quantifying biosphere-atmosphere exchange of nitrogen species

Recent research in nitrogen exchange with the atmosphere has separated research communities according to N form. The integrated perspective needed to quantify the net effect of N on greenhouse-gas balance is being addressed by the NitroEurope Integrated Project (NEU). Recent advances have depended on improved methodologies, while ongoing challenges include gas-aerosol interactions, organic nitrogen and N(2) fluxes. The NEU strategy applies a 3-tier Flux Network together with a Manipulation Network of global-change experiments, linked by common protocols to facilitate model application. Substantial progress has been made in modelling N fluxes, especially for N(2)O, NO and bi-directional NH(3) exchange. Landscape analysis represents an emerging challenge to address the spatial interactions between farms, fields, ecosystems, catchments and air dispersion/deposition. European up-scaling of N fluxes is highly uncertain and a key priority is for better data on agricultural practices. Finally, attention is needed to develop N flux verification procedures to assess compliance with international protocols.     

Influence of operating conditions on nitrous oxide formation during nitritation and nitrification

Nitrous oxide (N₂O), a strong greenhouse gas, can be produced by ammonium-oxidizing bacteria (AOB) as a by-product of ammonium oxidation and can potentially be formed in all types of nitrification processes. However, partial nitritation has been reported to cause significantly higher N₂O emissions than complete nitrification. In the study presented here, the mechanisms and factors that drive N₂O formation by AOB were investigated with respect to different operational strategies to achieve nitrite accumulation base on combined evaluation of oxygen uptake rate (OUR) and N₂O formation rate. On the one hand, N₂O formation during partial nitritation and nitrification in a continuously stirred tank reactor (CSTR) with continuous aerobic conditions was observed. On the other hand, the effect of intermittent aeration on N₂O formation during nitrification was investigated. The presence of nitrite, the extend of sludge-specific ammonium loading, low oxygen concentration, and transition from aerobic to anoxic conditions significantly increased N₂O formation in this reactor independently from each other, indicating that different formation pathways, supposedly via nitrite or hydroxylamine, were active.     

Determination of the nitrous oxide emission potential of deammonification under anoxic conditions

Various studies have been performed to determine nitrous oxide (N2O) emissions from conventional biological nitrogen removal processes in wastewater treatment like nitrification and denitrification in the main stream. However, with respect to the overall emissions of a wastewater treatment plant, part-stream treatment for high-strength wastewater (e.g., sludge liquor) is also expected to hold a significant emission potential because of high concentrations and extreme boundary conditions. This paper presents results from a laboratory-scale study on nitrous oxide production by biomass from a deammonification process (nitritation + anammox) under anoxic conditions. It was discovered that N2O formation results from incomplete endogenous denitrification rather than anammox and is dependent on substrate availability. Based on direct measurements of the dissolved N2O concentrations in a sequencing batch reactor, the dynamic behavior of N2O production is characterized in more detail. The results show that, during anoxic conditions, the N2O emission potential of deammonification is significantly lower than from conventional denitrification.