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151.
The selective catalytic reduction (SCR) rate of NO with N-containing reducing agents can be enhanced considerably by converting
part of NO into NO2. The enhanced reaction rate is more pronounced even at lower temperatures by using an equimolar mixture of NO and NO2 (fast SCR reaction). The oxidation characteristics of NO over catalyst Pt/TiO2 have been determined in a fixed bed reactor (8 mm-ID) with different concentrations of oxygen, nitric oxide and nitrogen
dioxide in the presence of 8% water. The conversion of NO to NO2 increases with increasing oxygen (O2) concentration from 3 to 12%, but it levels off at higher O2 concentrations. The NO conversion to NO2 decreases with increasing NO concentration and it also decreases by an addition of NO2 in the feed stream. Therefore, the oxidation of NO over Pt/TiO2 catalyst could be auto-inhibited by the reaction product of NO2. The effects of CO and SO2 on NO oxidation characteristics have also been determined. In fact, the presence of SO2 significantly suppresses oxidation of NO but due to the less stability of sulfate on anatase structure in TiO2, it becomes less significant. On the other hand, the presence of CO increases NO oxidation significantly due to the auto-inhibition
effect by CO. Moreover, the effect of SO2/CO on NO oxidation has also been determined and it was observed that NO oxidation decreases with the increase in SO2/CO ratio. 相似文献
152.
South Korea’s Civilian Control Zone (CCZ), a relatively untouched area due to tight military oversight since the end of Korean
War, has received considerable attention nationally and internationally for its rich biodiversity. However, the exclusion
of local communities from the process of defining problems and goals and of setting priorities for biodiversity conservation
has halted a series of biodiversity conservation efforts. Through qualitative research, we explored CCZ farmers’ views of
key problems and issues and also the sources of their opposition to the government-initiated conservation approaches. Key
findings include the farmers’ concerns about the impact of conservation restrictions on their access to necessary resources
needed to farm, wildlife impacts on the value of rice and other agricultural goods they produce, and farmers’ strong distrust
of government, the military, and planners, based on their experiences with past conservation processes. The findings regarding
farmers’ perceptions should prove useful for the design of future participatory planning processes for biodiversity conservation
in the CCZ. This case highlights how conservative measures, perceived to be imposed from above—however scientifically valuable—can
be undermined and suggests the value that must be placed on communication among planners and stakeholders. 相似文献
153.
A novel process for a simultaneous removal of ammonia and organics was developed on the basis of ion exchange and biological reactions. From batch experiments, it was found out that NH4+ could be removed effectively by combining cation exchange and biological nitrification showing 0.98 mg N/m2?s of a maximum flux. On the other hand, the removal of NO3− was 3.5 times faster than NH4+ and the maximum flux was calculated to be 3.4 mg N/m2?s. The systems for NH4+ and NO3− removal were combined for establishing the IEBR process. When the process was operated in a continuous mode, approximately 95.8% of NH4+ was removed showing an average flux of 0.22 mg N/m2·s. The removal efficiency of total nitrogen was calculated as 94.5% whereas that of organics was 99.5%. It was concluded that the IEBR process would be effectively used for a simultaneous removal of NH4+ and organics. 相似文献
154.
Feng Qin Shujuan Wang Inna Kim Hallvard F. Svendsen Changhe Chen 《International Journal of Greenhouse Gas Control》2011,5(3):405-412
A reaction calorimeter was used to determine the enthalpies of absorption of CO2 in aqueous ammonia and in aqueous solutions of ammonium carbonate at temperatures of 35–80 °C. The heat of absorption of CO2 with 2.5 wt% aqueous ammonia solution was found to be about 70 kJ/mol CO2, which is lower than that with MEA (around 85 kJ/mol) at 35 and 40 °C. The value decreases with increased loading, but not to as low a value as expected by the carbonate–bicarbonate reaction (26.88 kJ/mol). The enthalpy of absorption of CO2 in aqueous ammonia at 60 and 80 °C decreases with loadings at first, then increases between 0.2 mol CO2/mol NH3 and 0.6 mol CO2/mol NH3, and then decreases again. The behavior of the heat of absorption of CO2 in 10 wt% ammonium carbonate solution was found to be the same as that of aqueous ammonia at loadings above 0.6 mol CO2/mol NH3. The heat of absorption increases with increasing temperature. The heats of absorption are directly related to the extent of the various reactions with CO2 and can be assessed from the species variation in the liquid phase. 相似文献
155.
The research questions posed in this study highlight the importance of valuing proactivity in both prompting an individual to engage in proactive behavior and encouraging the expression of that behavior. We integrate a variety of constructs from the proactivity literature to gain a deeper understanding of proactive behavior as it relates to proactive motivation and supervisory performance evaluations. First, we draw upon self‐determination theory, expectancy–value theory, and the recent integration of the proactive motivation literature to hypothesize that proactive behavior is predicted by the interaction of “can do” and “reason to” proactive motivational states. Second, on the basis of performance theory, we hypothesize that the relationship between proactive behavior and performance depends upon the extent to which the supervisor values proactivity. Specifically, we argue that supervisors with proactive personalities are more likely to value and reward subordinate proactive behavior than passive supervisors. Results provide support for both of our hypotheses. Interestingly, results show that proactive behavior did not result in negative consequences but rather that there was a cost (i.e., lower performance rating) for not taking charge for employees with proactive supervisors. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
156.
Dongjin Lee Jisu Bae Jungu Kang Kiheon Kim 《Journal of Material Cycles and Waste Management》2016,18(3):445-454
This study was to find out potential of methane yield on food waste and food waste leachate as biomass in Korea. The seven biogasification facilities were selected for comparison of theoretical methane yield and actual methane yield. The theoretical methane yield was calculated based on organic constituents (carbohydrate, protein, fat) and based on element analysis. The actual methane yield was investigated based on volatile solids and CODcr. Theoretical methane yields by organic constituents were 0.52 Sm3CH4/kg VS and 0.35 Sm3CH4/kg CODcr and these by element analysis were 0.53 Sm3CH4/kg VS and 0.36 Sm3CH4/kg CODcr. Actual methane yields were 0.36 Sm3CH4/kg VSin and 0.26 Sm3CH4/kg CODcrin. Considering the average removal efficiency of organic materials of seven FWL biogasification facilities, actual methane yields were 0.48 Sm3CH4/kg VSrem and 0.33 Sm3CH4/kg CODcrrem. Methane yield by organic constituents is very similar to that by element analysis and actual methane yields of volatile solids and CODcr were similar to theoretical value. The actual methane yield in this study showed approximated boundary values with previous other references which conducted in lab-scale or biochemical methane potential (BMP) tests. In conclusion, Korean food waste and food waste leachate have sufficient potential of methane yield in the ongoing biogasification facilities. 相似文献
157.
Junmo Ahn Eun Hea Jho Moonkyung Kim Kyoungphile Nam 《Journal of Polymers and the Environment》2016,24(2):98-103
Bacterial synthesis of 3-hydroxybutyrate (3HB) and 3-hydroxyvalerate (3HV) copolymer [P(3HB-co-3HV)] using the hydrolysate of rice straw waste as a carbon source was affected by the composition of the hydrolysate, which depends highly on the rice straw pretreatment condition. Acid digestion with 2 % sulfuric acid generated larger production of P(3HB-co-3HV) than 6 % sulfuric acid, but 3HV concentration in the copolymer produced with 2 % acid hydrolysate was only 8.8 % compared to 18.1 % with 6 % acid hydrolysate. To obtain a higher 3HV mole fraction for enhanced flexibility of the copolymer, an additional heating was conducted with the 2 % acid hydrolysate after removal of residual rice straw. As the additional heating time increased a higher concentration of levulinic acid was generated, and consequently, the mole fraction of 3HV in P(3HB-co-3HV) increased. Among the conditions tested (i.e., 20-, 40-, 60-min), 60-min additional heating following 2 % sulfuric acid digestion achieved the highest 3HV mole fraction of 22.9 %. However, a longer heating time decreased the P(3HB-co-3HV) productivity, probably due to the increased intermediates concentrations acting as inhibitors in the hydrolysates. Therefore, the use of additional heating needs to consider both the increase in the 3HV mole fraction and the decrease in the P(3HB-co-3HV) productivity. 相似文献
158.
Sidney Aluani Maria Cristina F. Spilborghs Rebecca H. H. Kim 《补救:环境净化治理成本、技术与工艺杂志》2016,26(4):117-125
Polychlorinated biphenyls (PCBs) are a persistent environmental issue worldwide. This study summarizes the results obtained from a bench‐scale test of remediating PCB‐impacted soil. The research aimed to evaluate the effectiveness of extracting the PCB Aroclor 1260 from soil, transferring it to a liquid matrix, and then treating the PCB‐containing liquid using an Activated Metal Treatment System, a technology developed by NASA based on zero valent magnesium (ZVMg). The soil was from a former electrical plant area impacted by PCBs. The initial concentration of untreated soil contained an average of 4.7 ± 0.15 mg/kg of Aroclor 1260. The results showed that the mass transfer phenomena is possible using ethanol as a liquid matrix, reaching transfer results up to 93 percent. The ZVMg enabled the destruction of the Aroclor 1260, which reached 20 percent without any buildup of undesirable by‐products, such as less chlorinated PCBs. ©2016 Wiley Periodicals, Inc. 相似文献
159.
160.
We investigate a recent proposal that invasive species display patterns of spatial "spread regulation" analogous to density-dependent regulation of population abundances. While invasive species do offer valuable tests of ecological theories about spatial spread, we argue that the statistical approach used in the study is not useful, and that the proposed definition of "spread regulation" is likely to be confusing. While concepts of negative feedbacks in spatial spread may be reasonable, the proposed definition of "spread regulation" encompasses accelerating, constant, or decelerating spread. There is no compelling biological or practical reason to adopt such a definition. Moreover, we show that the statistical patterns (from time series of ratios of newly to recently invaded sites) proposed as evidence of spread regulation are predictable from basic diffusion models or other common models of constant spread with some stochasticity in dynamics and/or observations. Because such a wide range of processes would generate the observed patterns, no clear biological conclusions emerge from the proposed approach to spread analysis. When regarded in the context of the impacts and management of invasive species, the proposed regulation concept has the potential to create costly misunderstandings. 相似文献