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111.
112.
Hu J Eriksson L Bergman A Jakobsson E Kolehmainen E Knuutinen J Suontamo R Wei X 《Chemosphere》2005,59(7):1043-1057
Polybrominated diphenyl ethers (PBDEs) are widely used as flame retardants and are increasingly turning up in the environment. Their structural similarities to polychlorinated biphenyls and thyroid hormones suggest they may be a risk to human health. The present study examines the reactivity of brominated diphenyl ethers (BDEs) on the basis of the electronic structures as calculated by semiempirical AM1 self-consistent field molecular orbital (SCF-MO) method. Frontier orbital energies were used to elucidate the reactivity of BDEs in electrophilic, nucleophilic and photolytic reactions. From an examination of the frontier electron densities, the regioselectivity, or orientation, of metabolic reactions of BDEs was predicted. Furthermore, satisfactory quantitative structure-activity (property) relationship (QSAR and QSPR) models were derived to calculate gas chromatographic and ultraviolet spectral properties and luciferase induction activities from the AM1-computed electronic parameters. 相似文献
113.
Eva Linden B-E Bengtsson O Svanberg G Sundstrm National Swedish Environment Protection Board 《Chemosphere》1979,8(11-12)
The toxicity of 78 chemicals and pesticide formulations against the bleak, Alburnus alburnus (Pisces) and the harpacticoid Nitocra spinipes has been tested. The results are expressed as the 96 hr LC(I) 50 i.e. the initial concentration of a substance killing 50 per cent of the test organisms during 96 hours. Among the compounds tested are inorganic and organic compounds (metal salts, solvents and a few more complex compounds such as organotin compounds), pesticide formulations and other industrial chemicals (PCB-substitutes, phthalic acid esters and polychlorinated paraffins). 相似文献
114.
115.
Investigation of the Aerobic Biodegradability of Several Types of Cyclodextrins in a Laboratory-Controlled Composting Test 总被引:1,自引:0,他引:1
Steven Verstichel Bruno De Wilde Eva Fenyvesi József Szejtli 《Journal of Polymers and the Environment》2004,12(2):47-55
The biodegradation of several types of cyclodextrins (CDs) under laboratory-controlled composting conditions was investigated. CDs are used in a broad range of applications in food, pharmaceutical, medical, chemical, and textile industries because of their specific chemical characteristics related to their hydrophobic interior and hydrophilic exterior. The three naturally occurring cyclodextrins -CD, -CD, and -CD proved to be completely and readily biodegradable. Chemical modification of these basic compounds can have a major impact on the biodegradation rate and final biodegradation percentage. Fully acetylated -CD and -CD were found to be nonbiodegradable during 45 days of composting. Reducing the degree of acetylation had a positive effect on the biodegradation. Complete biodegradation was obtained for partially acetylated -CD with a degree of substitution (DS) of 7. The methylation (DS = 13) of -CD resulted in an undegradable compound during the 47 days composting, while (2-hydroxy)propyl--CD reached a plateau in biodegradation at a percentage of 20%. The incorporation of the antimicrobial agents imazalil and allyl-isothiocyanate into -CD had no negative impact on biodegradation, which makes these antimicrobial agents/CD complexes suitable for incorporation into biodegradable active packaging. 相似文献
116.
Christian Pansch Ivan Gómez Eva Rothäusler Karina Veliz Martin Thiel 《Marine Biology》2008,155(1):51-62
Chemical defense is assumed to be costly and therefore algae should allocate defense investments in a way to reduce costs
and optimize their overall fitness. Thus, lifetime expectation of particular tissues and their contribution to the fitness
of the alga may affect defense allocation. Two brown algae common to the SE Pacific coasts, Lessonia nigrescens Bory and Macrocystis integrifolia Bory, feature important ontogenetic differences in the development of reproductive structures; in L. nigrescens blade tissues pass from a vegetative stage to a reproductive stage, while in M. integrifolia reproductive and vegetative functions are spatially separated on different blades. We hypothesized that vegetative blades
of L. nigrescens with important future functions are more (or equally) defended than reproductive blades, whereas in M. integrifolia defense should be mainly allocated to reproductive blades (sporophylls), which are considered to make a higher contribution
to fitness. Herein, within-plant variation in susceptibility of reproductive and vegetative tissues to herbivory and in allocation
of phlorotannins (phenolics) and N-compounds was compared. The results show that phlorotannin and N-concentrations were higher
in reproductive blade tissues for both investigated algae. However, preferences by amphipod grazers (Parhyalella penai) for either tissue type differed between the two algal species. Fresh reproductive tissue of L. nigrescens was more consumed than vegetative tissue, while the reverse was found in M. integrifolia, thus confirming the original hypothesis. This suggests that future fitness function might indeed be a useful predictor of
anti-herbivore defense in large, perennial kelps. Results from feeding assays with artificial pellets that were made with
air-dried material and extract-treated Ulva powder indicated that defenses in live algae are probably not based on chemicals that can be extracted or remain intact after
air-drying and grinding up algal tissues. Instead, anti-herbivore defense against amphipod mesograzers seems to depend on
structural traits of living algae. 相似文献
117.
Masiá Paula Ardura Alba Gaitán Mario Gerber Steve Rayon-Viña Fernando Garcia-Vazquez Eva 《Environmental science and pollution research international》2021,28(24):30722-30731
Environmental Science and Pollution Research - Plastic pollution is a major environmental issue that affects coasts all around the world. Many studies point out the importance of a better... 相似文献
118.
Johann Köppel Marie Dahmen Jennifer Helfrich Eva Schuster Lea Bulling 《Environmental management》2014,54(4):744-755
Wildlife planning for renewable energy must cope with the uncertainties of potential wildlife impacts. Unfortunately, the environmental policies which instigate renewable energy and those which protect wildlife are not coherently aligned—creating a green versus green dilemma. Thus, climate mitigation efforts trigger renewable energy development, but then face substantial barriers from biodiversity protection instruments and practices. This article briefly reviews wind energy and wildlife interactions, highlighting the lively debated effects on bats. Today, planning and siting of renewable energy are guided by the precautionary principle in an attempt to carefully address wildlife challenges. However, this planning attitude creates limitations as it struggles to negotiate the aforementioned green versus green dilemma. More adaptive planning and management strategies and practices hold the potential to reconcile these discrepancies to some degree. This adaptive approach is discussed using facets of case studies from policy, planning, siting, and operational stages of wind energy in Germany and the United States, with one case showing adaptive planning in action for solar energy as well. This article attempts to highlight the benefits of more adaptive approaches as well as the possible shortcomings, such as reduced planning security for renewable energy developers. In conclusion, these studies show that adaptive planning and operation strategies can be designed to supplement and enhance the precautionary principle in wildlife planning for green energy. 相似文献
119.
Eva Panagiotakopulu Thomas Higham Anaya Sarpaki Paul Buckland Christos Doumas 《Die Naturwissenschaften》2013,100(7):683-689
Attributing a season and a date to the volcanic eruption of Santorini in the Aegean has become possible by using preserved remains of the bean weevil, Bruchus rufipes, pests of pulses, from the storage jars of the West House, in the Bronze Age settlement at Akrotiri. We have applied an improved pre-treatment methodology for dating the charred insects, and this provides a date of 1744–1538 BC. This date is within the range of others obtained from pulses from the same context and confirms the utility of chitin as a dating material. Based on the nature of the insect material and the life cycle of the species involved, we argue for a summer eruption, which took place after harvest, shortly after this material was transported into the West House storeroom. 相似文献
120.
Large quantities of floating macroalgae are traveling in coastal waters of the SE Pacific and in other temperate climate zones.
While afloat, these algae are potentially exposed to full solar radiation, including UVA and UVB, which can have profound
effects on their physiological and growth performance. Latitudinal variations in UV-radiation (UVR) are hypothesized to affect
floating algae differently with higher impacts at low latitudes than at high latitudes. In addition, UVR together with grazing
might accelerate the demise of floating kelps. This hypothesis was tested with outdoor laboratory experiments in which sporophytes
of the giant kelp Macrocystis pyrifera (L.) C. Agardh were exposed to a combination of different UVR regimes (PAR only, PAR + UV) and grazing at three sites along
the Chilean coast (20°S, 30°S, and 40°S). A latitudinal trend in irradiance was detected with increasing values from 40°S
to 20°S. Surprisingly, floating M. pyrifera responded with a high acclimation potential within this latitudinal UVR gradient. At 20°S, floating kelps were slightly sensitive
to UVR, which was reflected in reduced blade growth. At 30°S, physiological responses were hardly affected by the prevailing
irradiance but sporophyte growth and thus persistence mainly depended on the presence or absence of amphipod grazers. At high
latitudes, grazing had only minor impacts on algal biomass and blade growth, and kelps thrived well under all tested environmental
conditions. Overall, our results reveal that floating M. pyrifera was only slightly affected by UVR and that sporophytes can efficiently acclimate over a latitudinal UVR gradient that spans
from 20°S to 40°S. Given this high acclimation potential, we suggest that these (and possibly other) positively buoyant algae
are important dispersal agents over a wide range of temperate latitude conditions. 相似文献