Data Analysis Procedures for the Ozone NAAQS Statistical Format

The Clear Air Act of 1970 established the authority to control hazardous air pollutants. Section 112 of the legislation requires the Administrator to publish, and from time to time revise, a list of hazardous air pollutants for which he intends to establish emission standards, and to establish emission standards for those pollutants. These national emission standards for hazardous air pollutants are commonly referred to as “NESHAP” standards. All of the NESHAP that have been promulgated as of April 1984 are summarized in the table which accompanies this article. Two types of references are included in the table. The first reference identifies the issue of the Federal Register in which the NESHAP is explained in detail. The second reference identifies the background information document (BID) which contains the technical and economic information developed to support the NESHAP.     

Assessment of Tree Rings as a Hydrologic Record in a Humid Subtropical Environment1

Crockett, Kris, Jonathan B. Martin, Henri D. Grissino-Mayer, Evan R. Larson, and Thomas Mirti, 2010. Assessment of Tree Rings as a Hydrologic Record in a Humid Subtropical Environment. Journal of the American Water Resources Association (JAWRA) 1-13. DOI: 10.1111/j.1752-1688.2010.00464.x Abstract: Information about long-term variability of streamflow is important to allocate water resources, but few historical records extend more than 75 years into the past, requiring proxy records to evaluate flow prior to that time. Flow proxies have been found in tree-ring widths in temperate regions, but have rarely been used in humid subtropical environments because the relationship between tree growth and climate was believed to be weakened by limited seasonality and stress on tree growth from drought conditions. Tree-ring residual chronologies from two forests sampled from northern Florida correlate well with historical annual discharge (r² values as high as 0.47) from 3 of 15 river-gauging stations that were used to compare with the tree-ring chronologies. The best correlations occur where streamflow has little contribution from spring discharge or continuous flow from lakes and wetlands. Streams lack correlations with the tree-ring residual chronologies (r² values as low as 0.0002) where springs and continuous discharge from lakes mute variations in their flow. Tree-ring chronologies appear to be useful for reconstruction of prehistorical variations of some streamflow in humid subtropical regions, but interpretations of the reconstructions must consider the local hydrologic conditions.     

Systematic Biases in Measured PM10 Values with U.S. Environmental Protection Agency-Approved Samplers at Owens Lake,California

ABSTRACT

From 1993 through 1998, Wedding or Graseby high-volume PM₁₀ samplers were collocated with tapered element oscillating microbalance (TEOM) samplers at three sites at Owens Lake, CA. The study area is heavily impacted by windblown dust from the dry Owens Lake bed, which was exposed as a result of water diversions to the city of Los Angeles. A dichotomous (dichot) sampler and three collocated Partisol samplers were added in 1995 and 1999, respectively. U.S. Environmental Protection Agency (EPA) operating procedures were followed for all samplers, except for a Wedding sampler that was not cleaned for the purpose of this study. On average, the TEOM and Partisol samplers agreed to within 6%, and the dichot, Graseby, and Wedding samplers measured lower PM₁₀ concentrations by about 10, 25, and 35%, respectively. Surprisingly, the “clean” Wedding sampler consistently measured the same concentration as the “dirty” Wedding sampler through 85 runs without cleaning. The finding that the Graseby and Wedding high-volume PM₁₀ samplers read consistently lower than the TEOM, Partisol, and dichot samplers at Owens Lake is consistent with PM₁₀ sampler comparisons done in other fugitive dust areas, and with wind tunnel tests showing that sampler cut points can be significantly lower than 10 um under certain conditions. However, these results are opposite of the bias found for TEOM samplers in areas that have significant amounts of volatile particles, where the TEOM reads low due to the vaporization of particles on the TEOM's heated filter. Coarse particles like fugitive dust are relatively unaffected by the filter temperature. This study shows that in the absence of volatile particles and in the presence of fugitive dust, a different systematic bias of up to 35% exists between samplers using dichot inlets and high-volume samplers, which may cause the Graseby and Wedding PM₁₀ samplers to undermeasure PM₁₀ by up to 35% when the PM₁₀ is predominantly from coarse particulate sources.     

Treatment of municipal landfill leachate by catalytic wet air oxidation: Assessment of the role of operating parameters by factorial design

The wet air oxidation (WAO) of municipal landfill leachate catalyzed by cupric ions and promoted by hydrogen peroxide was investigated. The effect of operating conditions such as WAO treatment time (15-30 min), temperature (160-200 °C), Cu²⁺ concentration (250-750 mg L⁻¹) and H₂O₂ concentration (0-1500 mg L⁻¹) on chemical oxygen demand (COD) removal was investigated by factorial design considering a two-stage, sequential process comprising the heating-up of the reactor and the actual WAO. The leachate, at an initial COD of 4920 mg L⁻¹, was acidified to pH 3 leading to 31% COD decrease presumably due to the coagulation/precipitation of colloidal and other organic matter. During the 45 min long heating-up period of the WAO reactor under an inert atmosphere, COD removal values up to 35% (based on the initial COD value) were recorded as a result of the catalytic decomposition of H₂O₂ to reactive hydroxyl radicals. WAO at 2.5 MPa oxygen partial pressure advanced treatment further; for example, 22 min of oxidation at 200 °C, 250 mg L⁻¹ Cu²⁺ and 0-1500 mg L⁻¹ H₂O₂ resulted in an overall (i.e. including acidification and heating-up) COD reduction of 78%. Amongst the operating variables in question, temperature had the strongest influence on both the heating-up and WAO stages, while H₂O₂ concentration strongly affected the former and reaction time the latter. Nonetheless, the effects of temperature and H₂O₂ concentration were found to depend on the concentration levels of catalyst as suggested by the significance of their 3rd order interaction term.     

Aerial and terrestrial-based monitoring of channel erosion,headcutting, and sinuosity

Headcuts are points of accelerated channel erosion that frequently have ecological consequences. A particularly large and dynamic headcut in southwest Wyoming has affected natural and anthropogenic resources for decades. To better understand and address this issue, we undertook a review of the headcut’s upstream retreat, followed by photogrammetric monitoring of the present condition for erosion monitoring. Aerial photography shows the Bitter Creek headcut retreated >?200 m upstream in 68 years (1948–2016) at ~?1.4 m year^?1. Following installation of a concrete slab structure in the mid-1970s, headcut retreat slowed to ~?0.5 m year^?1. Channel sinuosity downstream of the headcut is greater than upstream, which we attribute to the presence of the headcut, given that there are no major changes in valley geometry, geology, or soils through this reach. Both aerial and terrestrial-based image platforms were used to collect stereo imagery and create 3D photogrammetric models of the headcut in 2016. From these two models, we measured soil loss downstream of the headcut at ~?126 m³ m^?1 valley length. Since 1954, soil loss within the channel has been ~?98 m³ year^?1 or ~871 t ha^?1 year^?1since then. Models created from aerial- and terrestrial-based images differed in volumetric estimates by 2%, indicating that either method could be used for this type of monitoring. The ground-based imagery model showed more detail, especially on vertical and overhanging surfaces, while the aerial imagery model produced a more realistic orthomosaic and efficiently covered a larger area. Ground-based image acquisition took longer and was more costly per unit area, but is an efficient method for small project areas, or areas where aerial imagery cannot be safely or practically acquired. Historical imagery and photogrammetric modeling proved very useful in elucidating stream dynamics associated with this large, dynamic headcut.     

Terbuthylazine persistence in an organic amended soil

The aim of this work was to study the effect of the application of a solid waste from olive oil production (alperujo) on the movement and persistence of the herbicide terbuthylazine (N2-tert-butyl-6-chloro-N4-ethyl-1,3,5-triazine-2,4-diamine). An experimental olive grove was divided in two plots: (i) Plot without organic amendment (blank) and (ii) Plot treated with alperujo during 3 years at a rate of 17920 kg of alperujo ha(- 1). Terbuthylazine was applied to both plots at a rate of 2 kg ha(- 1) a.i. Triplicates from each plot were sampled at 3 depths (0-10, 10-20 and 20-30 cm), air-dried, remains of olive leaves, grass roots, and stones removed and sieved through a 5 mm mesh sieve. Terbuthylazine was extracted with methanol 1:2 weight:volume ratio, the extracts were evaporated to dryness, resuspended in 2 mL of methanol, filtered and anylized by high performance liquid chromatography (HPLC). Higher amounts of terbuthylazine were detected at each sampling depth in plots treated with alperujo. The increase in soil organic matter content upon amendment with alperujo slightly increased sorption, suggesting that other factors beside sorption affect terbuthylazine degradation rate in organic amended soils.     

Modeling Effects of Natural Flow Restoration on Metals Fate and Transport in a Mountain Stream Impacted by Mine Waste1

Abstract: The effects of natural flow restoration on metals fate and transport in the Upper Tenmile Creek Watershed, Montana, were modeled using the Water Quality Analysis Simulation Program developed by the U.S. Environmental Protection Agency (USEPA). This 50‐km² watershed has over 150 historic abandoned mines, including mine waste rock and tailings, as well as adits discharging acid mine drainage, and is the primary drinking water supply for the City of Helena. Water supply diversions almost completely dewater some stream reaches during summer low flows, but the city is considering a new drinking water source and restoration of natural flows in Tenmile Creek as part of acid mine drainage remediation and broader aquatic habitat restoration. One dimensional steady‐state simulation of total recoverable cadmium, copper, lead, and zinc in the mainstem was performed, and the model was calibrated to June 2000 base‐flow data. Representative low‐flows in August and high‐flow snowmelt conditions in June were modeled using mean monthly natural flow estimates from the U.S. Geological Survey and representative USEPA metals concentrations data. The modeling showed that total recoverable metals concentrations, and especially loads, can vary significantly among input locations and over time in the watershed. Some data gaps limit evaluation of variability and increase uncertainty in several locations. Model results indicated, however, that natural low‐ and high‐flow restoration by itself can reduce some metals concentrations in the mainstem compared to June 2000 values, which were influenced by significant water diversion. Some values (such as Zn) may still exceed standards during natural August low flow due to the remaining high concentrations and loads in the primary inputs to the mainstem. Others (such as Cu) can increase during high flow due to remaining mine waste sources and loading of particulate Cu associated with erosion and transport of solids. Greater than 50% reduction in concentrations and loads from some of the main tributaries may be necessary to meet all standards, especially for potential particulate loads with higher flows in June.     

Ground-Cover Measurements: Assessing Correlation Among Aerial and Ground-Based Methods

Wyoming’s Green Mountain Common Allotment is public land providing livestock forage, wildlife habitat, and unfenced solitude, amid other ecological services. It is also the center of ongoing debate over USDI Bureau of Land Management’s (BLM) adjudication of land uses. Monitoring resource use is a BLM responsibility, but conventional monitoring is inadequate for the vast areas encompassed in this and other public-land units. New monitoring methods are needed that will reduce monitoring costs. An understanding of data-set relationships among old and new methods is also needed. This study compared two conventional methods with two remote sensing methods using images captured from two meters and 100 meters above ground level from a camera stand (a ground, image-based method) and a light airplane (an aerial, image-based method). Image analysis used SamplePoint or VegMeasure software. Aerial methods allowed for increased sampling intensity at low cost relative to the time and travel required by ground methods. Costs to acquire the aerial imagery and measure ground cover on 162 aerial samples representing 9000 ha were less than $3000. The four highest correlations among data sets for bare ground—the ground-cover characteristic yielding the highest correlations (r)—ranged from 0.76 to 0.85 and included ground with ground, ground with aerial, and aerial with aerial data-set associations. We conclude that our aerial surveys are a cost-effective monitoring method, that ground with aerial data-set correlations can be equal to, or greater than those among ground-based data sets, and that bare ground should continue to be investigated and tested for use as a key indicator of rangeland health.     

Survival of Porcine Reproductive and Respiratory Syndrome Virus in Pork Products

There is a risk of virus transmission through contaminated pork, and many viruses are considered potential hazards for both humans and livestock. The risk of transmission may be elevated with importation/exportation of meat between countries globally. Survival of porcine reproductive and respiratory syndrome virus (PRRSV) in different pork products has not been studied. The present study evaluated PRRSV survival in four different products: fresh sausage, ham, bacon, and acidified sausage prepared with experimentally contaminated pork. These products were prepared according to standard methods used by the manufacturers of pork products, and then stored at room temperature, 4 °C and ?20 °C. PRRSV was detected only in fresh sausage for up to 15 days at 4 °C and for 30 days at ?20 °C. No PRRSV was detected at any temperature in any of the other three products. These preliminary data provide valuable information for the pork processing industry, as well as in planning for import/export of these products among different countries.