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981.
钼磷酸氧化萜烯醇光度法测定矿山废水中松脂油(二号油) 总被引:1,自引:0,他引:1
在文献的基础上,利用钼磷酸在浓硫酸作用下于乙醇介质中优先氧化萜烯酸及其衍生物,而本身被还原为钼兰的性质,本文建立了测定矿山废水中松脂油的方法,方法检出限为0.006mg/5ml,回收率在88%—107%之间,相对标准偏差为5.05%。本文还对钼磷酸的溶剂选择,钼磷酸和浓硫酸的用量对吸光度的影响,以及浓盐酸的用量对萃取效率影响做了详细研究。 相似文献
982.
The present article studies the effect of CeO2 and Al2O3 on the activity of Pd/Co3O4/cordierite catalyst in conversion of NO, CO, CnHm. The catalysts were characterized by temperature programmed reduction with hydrogen, X-ray diffraction, X-ray photoelectron spectroscopy and transmission electron microscopy. It is shown that the effect of CeO2 on the properties of Pd/Co3O4/cordierite catalyst depends on preparation method. The catalyst obtained by co-deposition of cerium and cobalt oxides has higher activity in CO oxidation (CO + O2 and CO + NO) and total hexane oxidation (C6H14 + O2). Such phenomenon is probably caused by more than stoichiometric amount of formed oxygen vacancies, an increase in both mobility of surface oxygen and dispersity of components in the catalytic composition. It is demonstrated that CeO2 addition promotes the SO2 resistance of Pd/Co3O4/cordierite. The second support decreases the activity of Pd/Co3O4/cordierite catalyst in the reactions of CO and C6H14 with oxygen because of CoAl2O4 formation. 相似文献
983.
Sarah A. Styler 《环境科学学报(英文版)》2015,27(4):132-134
<正>In their recent Journal of Environmental Sciences publication,Wang and colleagues provide field evidence that industrial activities can contribute substantially to atmospheric carbonyl concentrations(Wang et al.,2015).These results may helpto explain underestimations of carbonyl emissions in currently available emission inventories,and highlight the need for an improved understanding of industrial sources of this class of compounds.In the atmosphere,carbonyl compounds photolyze to yield 相似文献
984.
985.
Assessment of groundwater pollution in West Delhi, India using geostatistical approach 总被引:3,自引:0,他引:3
Partha Pratim Adhikary H. Chandrasekharan Debashis Chakraborty Kalpana Kamble 《Environmental monitoring and assessment》2010,167(1-4):599-615
The exploration, exploitation, and unscientific management of groundwater resources in the National Capital Territory (NCT) of Delhi, India have posed a serious threat of reduction in quantity and deterioration of quality. The objective of the study is to determine the groundwater quality and to assess the risk of groundwater pollution at Najafgarh, NCT of Delhi. The groundwater quality parameters were analyzed from the existing wells of the Najafgarh and the thematic maps were generated using geostatistical concepts. Ordinary kriging and indicator kriging methods were used as geostatistical approach for preparation of thematic maps of the groundwater quality parameters such as bicarbonate, calcium, chloride, electrical conductivity (EC), magnesium, nitrate, sodium, and sulphate with concentrations equal or greater than their respective groundwater pollution cutoff value. Experimental semivariogram values were fitted well in spherical model for the water quality parameters, such as bicarbonate, chloride, EC, magnesium, sodium, and sulphate and in exponential model for calcium and nitrate. The thematic maps of all the groundwater quality parameters exhibited an increasing trend of pollution from the northern and western part of the study area towards the southern and eastern part. The concentration was highest at the southernmost part of the study area but it could not reflect correctly the groundwater pollution status. The indicator kriging method is useful to assess the risk of groundwater pollution by giving the conditional probability of concentrations of different chemical parameters exceeding their cutoff values. Thus, risk assessment of groundwater pollution is useful for proper management of groundwater resources and minimizing the pollution threat. 相似文献
986.
Nur Okur A. Levent Tuna Bülent Okur Hakan Altunlu H. Hüsnü Kayikçioğlu Hasan S. Civelek 《Environmental monitoring and assessment》2010,165(1-4):389-397
Efficacious botanical derivatives can provide an alternative to synthetic pesticides for organic farming systems. However, there is lack of information regarding the side effects of organic pesticides on key soil ecological processes. In this study, we investigated the effects of aqueous extracts from Urginea maritima and Euphorbia myrsinites exhibiting translaminar and systemic activity against pests on microbial biomass and enzymatic activities in soil. Two grams of plant material was extracted with 100 ml of water and then diluted 1:100, 2:100, and 4:100 with distilled water. Diluted plant extracts were applied around hypocotyl of tomato by soil drench. The effect of both plant extracts on microbial biomass C, amount of total N and organic C, and enzymatic activity in soil was significant. After the last application, the highest microbial biomass C was determined in the lowest U. maritima concentration (U 1:100). Soils treated with the highest concentration of U. maritima (U 4:100) had always lower SMBC content than control soil. All concentrations of E. myrsinites decreased microbial biomass C by 18% to 27% compared to the control. Total nitrogen and organic carbon decreased in soils without (control) and with treated U. maritima extract from first application to last application. Phosphatase, urease, and β-glucosidase activities were monitored in plant extract-treated soils. Except U. maritima 1:100 treatments of second and fourth applications, the other treatments of plant extracts negatively affected enzymatic activity in soil. U. maritima and E. myrsinites plant extracts exhibited different effects on soil microbial biomass and activity, probably because of their different chemical contents. 相似文献
987.
Nityananda Mondal Mayalagu Rajkumar Jun Sun Sourav Kundu P. S. Lyla Seyed Ajmal Khan Jean Paul Trilles 《Environmental monitoring and assessment》2010,171(1-4):471-486
The present study about the gammarid amphipods of Vellar and Uppanar estuaries was performed during two seasons (pre-monsoon and post-monsoon, 2005–2006), respectively, in nine habitats: five in the Vellar estuary and four in the Uppanar estuary. Amphipod samples were collected from sediments, oyster beds, seaweeds, sea grass, and mangroves. A total of 29 species of gammarid amphipods were collected in each area. The surface water temperature ranged from 16°C to 26°C, the salinity from 20 to 32 psu, and the pH between 7.5 and 8.3. Dissolved oxygen ranged from 5.3 to 7.8 ml/l. The maximum abundance of amphipods was observed during the pre-monsoon (July to September) in Vellar mangrove, and it was minimum during the pre-monsoon in Uppanar sea grass. It was found that several physicochemical factors, such as salinity, temperature, dissolved oxygen, pH, and the substrate have a marked effect on the distribution and the relative abundance of amphipods. The ranges of species diversity, richness, dominance, and evenness in the Vellar and Uppanar estuaries were 1.58–4.15, 1.82–5.29, 0–0.11, and 0.96–1, respectively. Using multivariate analyses, in each estuary, it was possible to identify different communities of amphipod species according to their habitats. 相似文献
988.
989.
Ha T.T. Dinh Hiromi Kambar Shuji Matsushit Yoshiteru Aoi Tomonori Kindaichi Noriatsu Ozaki Akiyoshi Ohashi 《环境科学学报(英文版)》2022,34(6):68-78
Methane is produced in a microbial electrosynthesis system (MES) without organic substrates. However, a relatively high applied voltage is required for the bioelectrical reactions. In this study, we demonstrated that electrotrophic methane production at the biocathode was achieved even at a very low voltage of 0.1 V in an MES, in which abiotic HS− oxidized to SO42− at the anodic carbon-cloth surface coated with platinum powder. In addition, microbial community analysis revealed the most probable pathway for methane production from electrons. First, electrotrophic H2 was produced by syntrophic bacteria, such as Syntrophorhabdus, Syntrophobacter, Syntrophus, Leptolinea, and Aminicenantales, with the direct acceptance of electrons at the biocathode. Subsequently, most of the produced H2 was converted to acetate by homoacetogens, such as Clostridium and Spirochaeta 2. In conclusion, the majority of the methane was indirectly produced by a large population of acetoclastic methanogens, namely Methanosaeta, via acetate. Further, hydrogenotrophic methanogens, including Methanobacterium and Methanolinea, produced methane via H2. 相似文献
990.
A laboratory scale study was conducted to assess the feasibility of the new coupling of rotating biological contactor (RBC) plus porous biomass support system (PBSS) using polyurethane foam as porous support media to biodegrade petroleum refinery wastewater. Polyurethane foam was attached on disks of two four-stage laboratory scale cascade connected RBC units.The two RBC units were operated simultaneously at different but constant, flowrates giving hydraulic loading rates of 0.01, 0.02, 0.03, 0.04 m3/m2/d in two runs keeping the same rotational speed 10 r/min throughout. Organic loading was a less controllable factor in this study.For all of the hydraulic loadings, it was found that the removal efficiency of total chemical oxygen demand (TCOD) and oil were above 80 percent. Ammonia nitrogen and phenol removal were above 90 and 80 percent respectively. The maximum biomass concentration within polyurethane foam was about 30 g/m2 in the first stage for 0.03 m3/m2/d hydraulic loading.The results show that t 相似文献