Heavy metal pollution in soil and plants at bone char site

This study determined the heavy metal concentration in soil and plants at a bone char site in Umuahia, Nigeria. Soil and plant samples collected in a randomized complete block design (RCBD) were analyzed for zinc (Zn), lead (Pb), cadmium (Cd), nickel (Ni), and arsenic (As). The concentration of metals in soil and plants in the vicinity of the bone char site are as follows: Zn (172?mg?kg^?1) and Ni (0.62?mg?kg^?1) in soil were highest at site P₃, Pb (2.37?mg?kg^?1) and As (0.08?mg?kg^?1) at site P₁, and Cd (18.30?mg?kg^?1) at site P₂. In plants, the concentrations of Zn (41.17?mg?kg^?1) and Cd (3?mg?kg^?1) were highest in Albizia ferruginea, Ni in Dialium guineense (0.09?mg?kg^?1), while Pb was in D. guineense (0.08?mg?kg^?1) and Spathodea companulata (0.06?mg?kg^?1). The levels of Zn, Cd, Pb, Ni, and As in soil ranged from 11.2 to 172, 2.68 to 18.2, 0.026 to 2.37, 0.33 to 0.62, and 0.02 to 0.08?mg?kg^?1, respectively. In plants, the concentration of Zn, Cd, Pb, and Ni ranged from 2.01 to 41.17, 0.12 to 3, 0.02 to 0.08, and 0.03 to 0.09?mg?kg^?1, respectively. There were significant correlations between Zn and Cd, and Pb and As in soil. The high concentration of Cd in soil might affect soil productivity.     

Exploring relationships between conservation and poverty reduction in wetland ecosystems: lessons from 10 integrated wetland conservation and poverty reduction initiatives

It is well known that whilst wetlands deliver a wide range of services vital for human well-being, they are being rapidly degraded and lost. Losses tend to be higher where human populations are increasing most and demands for economic development are greatest. Multidisciplinary management approaches that integrate conservation and development objectives in wetlands are therefore urgently requested for by the Ramsar Convention on Wetlands. This paper describes the evaluation of 10 wetland management case studies from Asia, Africa and South America that adopted such an integrated approach. The evaluation assessed the outcomes of these integrated initiatives to identify conditions and processes for linking conservation and poverty reduction objectives in wetlands. The findings are also compared with other assessments of integrated approaches, particularly in terms of their effectiveness in optimizing conservation and poverty reduction outcomes. The results from our studies suggest an ongoing evolution of such integrated interventions, which also implies cycles of learning from past mistakes. Overall, our results highlight the significant variation between wetlands in types and quantities of services they provide and emphasize the need to view many ecological issues as social challenges for equitable solutions to both wetlands and people. The analysis further shows that the positive on-ground results owe much to the interdisciplinary problem analysis, whereby interventions can move from treating symptoms to addressing root causes. while no blueprint emerged on how to successfully integrate conservation and poverty reduction in wetlands, important lessons for future interventions were drawn.     

Trace elements in fish and oysters from Sepetiba Bay (Rio de Janeiro – Brazil) determined by total reflection X-ray fluorescence using synchrotron radiation

Trace elements were determined in fish and oysters from Sepetiba Bay, Brazil, by total reflection Xray fluorescence using synchrotron radiation (SRTXRF). Cr, Mn, Fe, Ni, Cu, Zn and Se were determined in fish muscles and organs and in oyster soft tissue. SRTXRF was shown to be a good tool for the analysis of trace elements from biological tissue samples. Overall, the levels of the analysed metals were higher in oysters than in the fish samples. Metals were not uniformly distributed throughout the body of the analysed fish. The detected concentrations of Cr, Zn and Se were very high in some samples, surpassing the maximum limits established by Brazilian legislation.     

Count, identification and antimicrobial susceptibility of bacteria recovered from dental solid waste in Brazil

In Brazil, few studies on microbial content of dental solid waste and its antibiotic susceptibility are available. An effort has been made through this study to evaluate the hazardous status of dental solid waste, keeping in mind its possible role in cross-infection chain. Six samples of solid waste were collected at different times and seasons from three dental health services. The microbial content was evaluated in different culture media and atmospheric conditions, and the isolates were submitted to antibiotic susceptibility testing. A total of 766 bacterial strains were isolated and identified during the study period. Gram-positive cocci were the most frequent morphotype isolated (48.0%), followed by Gram-negative rods (46.2%), Gram-positive rods (5.0%), Gram-negative-cocci (0.4%), and Gram-positive coccobacillus (0.1%). Only two anaerobic bacteria were isolated (0.3%). The most frequently isolated species was Staphylococcus epidermidis (29.9%), followed by Stenotrophomonas maltophilia (8.2%), and Enterococcus faecalis (6.7%). High resistance rate to ampicillin was observed among Gram-negative rods (59.4%) and Gram-positive cocci (44.4%). For Gram-negative rods, high resistance was also noted to aztreonam (47.7%), cefotaxime (47.4%), ceftriaxone and cefazolin (43.7%), and ticarcillin-clavulanic acid (38.2%). Against Gram-positive cocci penicillin exhibit a higher resistance rate (45.0%), followed by ampicillin, erythromycin (27.2%), and tetracycline (22.0%). The present study demonstrated that several pathogenic bacteria are present in dental solid waste and can survive after 48 h from the waste generation time and harbor resistance profiles against several clinical recommended antibiotics.     

Paradigm changes in freshwater aquaculture practices in China: Moving towards achieving environmental integrity and sustainability

Contribution of fisheries and aquaculture to global food security is linked to increased fish consumption. Projections indicate that an additional 30–40 million tonnes of fish will be required by 2030. China leads global aquaculture production accounting for 60% in volume and 45% in value. Many changes in the Chinese aquaculture sector are occurring to strive towards attaining environmental integrity and prudent use of resources. We focus on changes introduced in freshwater aquaculture developments in China, the main source of food fish supplies. We bring forth evidence in support of the contention that Chinese freshwater aquaculture sector has introduced major paradigm changes such as prohibition of fertilisation in large water bodies, introduction of stringent standards on nutrients in effluent and encouragement of practices that strip nutrients among others, which will facilitate long-term sustainability of the sector.     

Molecular changes of aquatic humic substances formed from four aquatic macrophytes decomposed under different oxygen conditions

Aquatic macrophytes’ decomposition is a source of recalcitrant carbon in the long term contributing to humic substances (HS) formation. Understanding the influence of plant detritus quality and oxygen availability over molecular changes of these compounds provides ecological information related to their cycling. This study described the molecular variation of dissolved HS from Eichhornia azurea, Egeria najas, Oxycaryum cubense and Salvinia molesta decomposition under aerobic and anaerobic conditions. The aquatic HS formed from the four aquatic macrophytes showed similar features (e.g. molecular weight and aromaticity). This fact indicates little influence of the detritus quality or availability of oxygen on the fulvic acids (FA) and humic acid characteristics. Under aerobic condition a decrease in the polysaccharides content in FA occurred. HS from E. najas were related to less-recalcitrant features, while HS from S. molesta were related to recalcitrant.     

Influence of selected cyclodextrins in sorption-desorption of chlorpyrifos,chlorothalonil, diazinon,and their main degradation products on different soils

Cyclodextrins (CDs) can improve the apparent solubility and bioavailability of a variety of organic compounds through the formation of inclusion complexes; accordingly, they are suitable for application in innovative remediation technologies of contaminated soils. However, the different interactions in the tertiary system CD/contaminant/soil matrix can affect the bioavailability of the inclusion complex through the possible sorption of CD and CD complex in the soil matrix, as well as with the potential of the sorbed CD to form the complex, concurrent with the desorption processes. This work focuses in changes produced by three different CDs in soil sorption-desorption processes of chlorpyrifos (CPF), diazinon (DZN), and chlorothalonil (CTL), and their major degradation products, 3,5,6-trichloro-2-pyridinol (TCP), 2-isopropyl-6-methyl-4-pyrimidinol, and hydroxy-chlorothalonil (OH-CTL). Cyclodextrins used were β-cyclodextrin (β-CD), methyl-β-cyclodextrin (Mβ-CD), and 2-hydroxypropyl-β-cyclodextrin (HPβ-CD). The studied soils belong to the orders Andisol, Ultisol, and Mollisol with different organic matter contents, mineral composition, and pH. The apparent sorption constants were significantly lower for the three pesticides in the presence of all CDs. The highest displacement of sorption equilibria was produced by the influence of Mβ-CD, with the most pronounced effect for CPF, a pesticide strongly sorbed on soils. The same was obtained for TCP and OH-CTL, highlighting the need to assess the risk of generating higher levels of groundwater contamination with polar metabolites if degradation rates are not controlled. The highest desorption efficiency was obtained for the systems CPF-β-CD, DZN-Mβ-CD, and CTL-Mβ-CD. Since the degree of adsorption of the complex is relevant to obtain an increase in the bioavailability of the contaminant, a distribution coefficient for the complexed pesticide in all CD–soil–pesticide system was estimated by using the apparent sorption coefficients, the stability constant for each CD–pesticide complex, and the distribution coefficients of free pesticide.     

Material and Symbolic Forces in the Evolution of Regulatory Institutions of Agrobiotechnology: A Case Study About Brazil

The wide and complex range of technologies produced and used in the contemporary societies has challenged the analysis from the different fields of social sciences. In this sense, in order to elaborate a study that aim at understanding the relationship between technological progress and the ongoing institutional changes that mark the capitalist societies, we believe it is necessary to adopt an interdisciplinary approach combining methodologies from Economics and Sociology fields. Therefore, this study proposes the development of an interdisciplinary dialogue between the economic sociology of Pierre Bourdieu and the evolutionary economics developed by authors such as Giovanni Dosi, Sidney Winter, Richard Nelson and Bhaven Sampat. In doing so, we intend to demonstrate that a theory guided by Marx’s historical materialism, as it is the case of evolutionary economics, can be enriched by a materialist theory of symbolic, such as that of Pierre Bourdieu. In searching the comprehension of the complementarity between material and symbolic forces, this study addresses the conflictual process surrounding the formulation of the regulatory institutions to the biotechnology sector in Brazil over the last two decades. More precisely, through a case study, we seek to demonstrate that the convergence of discourses and interests between prestigious scientific organizations and the multinational companies that control the agrobiotechnology industry has been relevant to allow this new technological paradigm to make progress. Finally, we raise some questions concerning this alliance between business and science and the conflicts that revolve around the rapid expansion of the genetically modified crops worldwide.     

Sustainable farming practices of the Chinese mitten crab (<Emphasis Type="Italic">Eriocheir sinensis)</Emphasis> around Hongze Lake,lower Yangtze River Basin,China

Results of a survey of 156 Chinese mitten crab (Eriocheir sinensis) grow-out farms around Hongze Lake (118.48–118.72°E; 33.36–33.38°N) are reported. Area farmed has remained relatively unchanged but production (59 932 t in 2012) increased steadily over the last 7 years, indicative of the viability and sustainability of the farming system that has gradually replaced intensive Chinese major carp polyculture around Hongze Lake. Results showed that production range was 135–2400 kg ha⁻¹ cycle⁻¹ (mean 1144 ± 34). Crab yields correlated linearly to stocking density and conformed to a normal distribution curve, with 66.7 % of farms yielding 900 kg ha⁻¹ cycle⁻¹ or more. Yield was negatively correlated to pond size and capture size (p < 0.01), and farms with macrophyte coverage rate lower than 30 % of water surface were significantly (p < 0.05) lower than those exceeding 30 %.

Electronic supplementary material

The online version of this article (doi:10.1007/s13280-015-0722-0) contains supplementary material, which is available to authorized users.