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141.
R. San José M.A. Rodríguez I. Salas R.M. González 《Environmental monitoring and assessment》2000,65(1-2):477-484
Operational air quality models have become an important tool to assist the decision makers in European Environmental Offices at different levels: cities, regional and state. Because of the important advance on computing capabilities during the last few years the possibility of incorporating the complex research and academic mesoscale air quality models under routine operational basis has become a reality. OPANA model is the operational version of the research model ANA (Atmospheric mesoscale Numerical pollution model for regional and urban Areas). This model is a limited area model (mesoscale beta) and the capability to extend the prediction horizon is limited unless proper boundary conditions are provided during long simulations. In this contribution we show how AVN/MRF (NOAA) vertical numerical meteorological soundings are incorporated to the OPANA system by using JAVA technology. This new feature helps to keep the air quality model into medium power workstations and the performance is improved accordingly. This technology avoids running mesoscale models over larger areas (continental scale) to accordingly increase the forecasting temporal horizon. 相似文献
142.
Sotelo JL Rodríguez AR Mateos MM Hernández SD Torrellas SA Rodríguez JG 《Journal of environmental science and health. Part. B》2012,47(7):640-652
Adsorption has been used to study the removal of atenolol, caffeine, diclofenac and isoproturon, pharmaceutical compounds as emerging contaminants and an endocrine disruptor from ultrapure water and a municipal wastewater treatment plant effluent with three carbonaceous materials: activated carbon, multiwalled carbon nanotubes and carbon nanofibers. The adsorption capacities were studied in the temperature range of 25-65°C and pH range from 3 to 9. Several model isotherms were used to model the adsorption equilibrium data. Also, the competitive adsorption was evaluated. 相似文献
143.
C. Rodríguez Alvárez M. Jiménez Moreno L. López Alonso B. Gómara F. J. Guzmán Bernardo R. C. Rodríguez Martín-Doimeadios M. J. González 《Environmental science and pollution research international》2013,20(8):5361-5372
Total mercury (Hg), monomethylmercury (MeHg), and selenium (Se) were determined in blood of 11 bird species living in Doñana National Park (DNP, Southwestern Spain) and the surrounding area in 1999 and 2000 after a mine spill accident. The total Hg contents found varied from 1.00 to 587 ng/mL, with an MeHg percentage higher than 80 %, except in mallard species. In all the cases, the concentrations found were below the threshold of high risk for the bird populations. The parameters which most affected the accumulation of Hg and MeHg in the birds studied were, first, species, or trophic position, and second sampling area. Age does not seem to have a great influence on the content of Hg in the blood of these birds. The levels of Se found ranged from 108 to 873 ng/mL, and they were not affected by species, trophic level, age, or sampling area. The blood Hg concentrations of birds living in the area directly affected by the toxic mud, outside the park, were higher than those found in the other birds, and this could be explained by the mine spill accident happened in 1998. 相似文献
144.
J. Peñalbert-Ramos M. Rodríguez-Rosario 《Journal of the Air & Waste Management Association (1995)》2013,63(6):719-721
Abstract Acid rain precipitation has become a major environmental concern. Many long-range projects in the United States and Europe are devoted to the problems associated with acid rain pollution. In Puerto Rico, there has been no formal study on acid rain. The rainfall pH values and the air-mass trajectory of the northeastern part of the island of Puerto Rico on the surface were analyzed from January 1998 to December 2000. The air-mass trajectory was classified in five different sectors, according to where it originates. The mean pH value measured during that period showed a tendency toward acidity. The 80% of the air-mass trajectory that arrived at the station occurred in Sector I, with a pH value of 4.30. The lowest pH value measured was 4.16, and it occurred in Sector V, where the air mass originates in the northwest part of the island. 相似文献
145.
Alberto Notario Iván Bravo José Antonio Adame Yolanda Díaz-de-Mera Alfonso Aranda Ana Rodríguez Diana Rodríguez 《Environmental science and pollution research international》2013,20(1):188-200
The purpose of this work is to contribute to the understanding of the photochemical air pollution in central-southern of the Iberian Peninsula, analysing the behaviour and variability of oxidant levels (OX?=?O3?+?NO2), measured in a polluted area with the highest concentration of heavy industry in central Spain. A detailed air pollution database was observed from two monitoring stations. The data period used was 2008 and 2009, around 210,000 data, selected for its pollution and meteorological statistics, which are very representative of the region. Data were collected every 15 min, however hourly values were used to analyse the seasonal and daily ozone, NO, NO2 and OX cycles. The variation of OX concentrations with NO x is investigated, for the first time, in the centre of the Iberian Peninsula. The concentration of OX was calculated using the sum of a NO x -independent ‘regional’ contribution (i.e. the O3 background), and a linearly NO x -dependent ‘local’ contribution. Monthly dependence of regional and local OX concentration was observed to determine when the maximum values may be expected. The variation of OX concentrations with levels of NO x was also measured, in order to pinpoint the atmospheric sources of OX in the polluted areas. The ratios [NO2]/[OX] and [NO2]/[NO x ] vs. [NO x ] were analysed to find the fraction of OX in the form of NO2, and the possible source of the local NO x -dependent contribution, respectively. The progressive increase of the ratio [NO2]/[OX] with [NO x ] observed shows a greater proportion of OX in the form of NO2 as the level of NO x increases. The higher measured values in the ratio [NO2]/[NO x ] should not be attributed to NO x emissions by vehicles; they could be explained by industrial emission, termolecular reactions or formaldehyde and HONO directly emitted by vehicles exhausts. We also estimate the rate of NO2 photolysis, J NO2?=?0.18–0.64 min?1, a key atmospheric reaction that influence O3 production and then the regional air quality. The first surface plot study of annual variation of the daily mean oxidant levels, obtained for this polluted area may be used to improve the atmospheric photochemical dynamic in this region of the Iberian Peninsula where there are undeniable air quality problems. 相似文献
146.
Sánchez B Sánchez-Muñoz M Muñoz-Vicente M Cobas G Portela R Suárez S González AE Rodríguez N Amils R 《Chemosphere》2012,87(6):625-630
The photocatalytic elimination of microorganisms from indoor air in realistic conditions and the feasibility of simultaneous elimination of chemical contaminants have been studied at laboratory scale. Transparent polymeric monoliths have been coated with sol-gel TiO(2) films and used as photocatalyst to treat real indoor air in a laboratory-scale single-step annular photocatalytic reactor. The analytical techniques used to characterize the air quality and analyze the results of the photocatalytic tests were: colony counting, microscopy and PCR with subsequent sequencing for microbial quantification and identification; automated thermal desorption coupled to gas chromatography with mass spectrometry detection for chemical analysis. The first experiments performed proved that photocatalysis based on UVA-irradiated TiO(2) for the reduction of the concentration of bacteria in the air could compete with the conventional photolytic treatment with UVC radiation, more expensive and hazardous. Simultaneously to the disinfection, the concentration of volatile organic compounds was greatly reduced, which adds value to this technology for real applications. The fungal colony number was not apparently modified. 相似文献
147.
Armenteras Dolors Rodríguez Nelly Retana Javier Morales Mónica 《Regional Environmental Change》2011,11(3):693-705
Colombian Andean forests cover nine million ha. These forests provide an informative case study of mountain deforestation
in South America. They are surrounded by tropical lowland forests, and they host most of the country’s human population. This
study evaluates the relative importance of human and natural variables in deforestation of the Colombian Andes between 1985
and 2005 using remote sensing methods, geographic information system (GIS) technology and general linear models (GLM). The
following factors affected the annual deforestation in the region positively: forced population migration, unsatisfied basic
needs, economic activity, crops, pastures, illicit crops, protected areas and slope. Factors having a negative effect were
tenure of small land parcels, road density, water scarcity and mean temperature. The results of this study also provide insight
into the differences between the dynamics of lowland forests and those of montane forests. Montane forests had a lower annual
rate of deforestation than did forests in the lowlands. Socio-economic, demographic and biophysical factors explain overall
deforestation rates for the region. However, when altitude variation is taken into account, intraregional differences in the
Andes become evident. Deforestation processes differ between those areas adjacent to the high Andean valleys where most of
the country’s population concentrates and those areas in the tropical lowlands north, west and east of the Andean chain. Differences
between lowland and montane forest dynamics are due partly to the accessibility of forests and differences in wealth and economic
activities. In montane forests, deforestation is positively influenced by economic activity, the presence of protected areas
and higher slopes. Deforestation in montane forests is negatively affected by tenure of small land parcels, road density,
water scarcity and mean temperature. Lowland deforestation rates are more closely related to rural population, pasture percentage,
crops, protected areas and temperature. Our results suggest that montane forests appear to be in a more advanced stage of
colonisation and economic development, whereas lowland forests are closer to the colonisation frontier and to rapidly growing
colonist populations. This study reinforces the idea that although the most common tropical drivers of deforestation are found
in the Andes, these drivers operate differently when intraregional differences are considered. 相似文献
148.
Lumbricus terrestris L. activity increases the availability of metals and their accumulation in maize and barley 总被引:1,自引:0,他引:1
Ruiz E Alonso-Azcárate J Rodríguez L 《Environmental pollution (Barking, Essex : 1987)》2011,159(3):722-728
The effect of the earthworm Lumbricus terrestris L. on metal availability in two mining soils was assessed by means of chemical extraction methods and a pot experiment using crop plants. Results from single and sequential extractions showed that L. terrestris had a slight effect on metal fractionation in the studied soils: only metals bound to the soil organic matter were significantly increased in some cases. However, we found that L. terrestris significantly increased root, shoot and total Pb and Zn concentrations in maize and barley for the soil with the highest concentrations of total and available metals. Specifically, shoot Pb concentration was increased by a factor of 7.5 and 3.9 for maize and barley, respectively, while shoot Zn concentration was increased by a factor of 3.7 and 1.7 for maize and barley, respectively. Our results demonstrated that earthworm activity increases the bioavailability of metals in soils. 相似文献
149.
Hector Hernan Rodríguez Omar Espinoza-Navarro Ivan Silva Douglas Needham María Eugenia Castro Luis Sarabia Juan Inostroza Leonella Jimenez 《Environmental science and pollution research international》2011,18(3):497-502
Introduction and aims
The Chilean Altiplano ecosystem is conserved free from contaminants and pollutants because of the absence of major local human activities such as agriculture or other industries. We studied the effects of paraoxon on proliferation and apoptosis of testicular cells during active spermatogenesis in Dugesia gonocephala collected from a pristine river (Guacollo) in the Altiplano region nearby Visviri town, Chile. 相似文献150.
MD Basallote A Rodríguez-Romero J Blasco A DelValls I Riba 《Environmental science and pollution research international》2011,19(7):2550-2560
CO(2) leakages during carbon capture and storage in sub-seabed geological structures could produce potential impacts on the marine environment. To study lethal effects on marine organisms attributable to CO(2) seawater acidification, a bubbling CO(2) system was designed enabling a battery of different tests to be conducted, under laboratory conditions, employing various pH treatments (8.0, 7.5, 7.0, 6.5, 6.0, and 5.5). Assays were performed of three exposure routes (seawater, whole sediment, and sediment elutriate). Individuals of the clam (Ruditapes philippinarum) and early-life stages of the gilthead seabream, Sparus aurata, were exposed for 10?days and 72?h, respectively, to acidified clean seawater. S. aurata larvae were also exposed to acidified elutriate samples, and polychaete organisms of the specie Hediste diversicolor and clams R. philippinarum were also exposed for 10?days to estuarine whole sediment. In the fish larvae elutriate test, 100?% mortality was recorded at pH?6.0, after 48?h of exposure. Similar results were obtained in the clam sediment exposure test. In the other organisms, significant mortality (p?0.05) was observed at pH values lower than 6.0. Very high lethal effects (calculating L[H(+)]50, defined as the H(+) concentration that causes lethal effects in 50?% of the population exposed) were detected in association with the lowest pH treatment for all the species. The implication of these results is that a severe decrease of seawater pH would cause high mortality in marine organisms of several different kinds and life stages. The study addresses the potential risks incurred due to CO(2) leakages in marine environments. 相似文献