Bottom-up approach for downscaling CO2 emissions in Taiwan: robustness analysis and policy implications

The roles and responsibilities of cities in CO₂ mitigation have drawn increasing attention in recent years. To facilitate optimal design of effective mitigation policies, it is important for city authorities to understand the magnitudes and sources of their CO₂ emissions, and their relative shares of emissions at a higher spatial level. Although several studies estimate CO₂ emissions at the city level, the robustness of these estimates and their linkage to emissions at a higher level remains unclear. This kind of localized information on emissions is important for coordination of climate policies at different spatial scales. The study aims to fill a gap in understanding by building a systematic bottom-up approach for estimating urban CO₂ emissions and offering a consistency check with IPCC top–down estimates. Using Taiwan as a case study, we display the geographic distribution of CO₂ emissions. The significance and implications of the downscaling CO₂ emissions are indicated accordingly.     

Total-factor water efficiency of regions in China

Water is a limited and unevenly distributed resource in China, with the per capita amount of water resource there only about one-fourth of the world's average. However, water is an essential resource for people's lives and economic development. Over the past two decades China has seen the fruit of its rapid economic growth; nevertheless, a severe water shortage is behind this prosperous scenario and is becoming worse. Efficient water supply is certainly essential for the sustainable development of human beings. This paper analyzes water efficiency by incorporating water as an input as well as using conventional inputs such as labor employment and capital stock. An index of a water adjustment target ratio (WATR) is established from the production frontier constructed by data envelopment analysis (DEA) including water as an input. The water efficiency of regions is obtained from a total-factor framework with both residential and productive water use. A U-shape relation is discovered between the total-factor water efficiency and per capita real income among areas in China. The central area has the worst water efficiency ranking and the total adjustment amount of water used there is around three-fourths of China's total. More efficient production processes and advanced technologies need to be adopted in the central area to improve its water efficiency, especially for its productive use of water.     

Potential and Limitations of Microbial Reductive Dechlorination for Bioremediation Applications

Current knowledge and recent advances in the area of microbial reductive dechlorination of polychlorinated organic compounds are summarized. Factors which may limit the efficacy of the dechlorination process for the in situ bioremediation of contaminated soil and sediment systems are identified. Results of recent studies on the anaerobic biotransformation of soil-sorbed chlorinated ethenes and sediment-sorbed chlorinated benzenes are provided to illustrate how low contaminant bioavailability may control the rate and extent of dechlorination in subsurface systems, especially those with long-term contamination. Use of nonionic, polysorbate surfactants as the sole electron donors of a mixed, methanogenic culture supported the microbial sequential reductive dechlorination of either free or sediment-bound hexachlorobenzene (HCB) to primarily 1,3-dichlorobenzene, but did not enhance the bioavailability of sediment-bound HCB as compared to microcosms, which used glucose. Because current knowledge on the interactions of dechlorinating populations with other microbial populations in the presence of alternative terminal electron acceptors (e.g., nitrate, Fe³⁺ , Mn⁴⁺) is limited, such interactions and their effect on the dechlorination process in subsurface systems need to be further explored to improve our understanding of the reductive dechlorination process in complex environmental systems and lead to the development of more efficient in situ bioremediation technologies and strategies.     

OPTIMAL ALLOCATION OF ARTIFICIAL AERATION ALONG A POLLUTED STREAM USING DYNAMIC PROGRAMMING1

ABSTRACT: When a series of aerators are used to raise the level of dissolved oxygen in a polluted stream through instream artificial aeration augmentation, the system is governed by the basic dissolved oxygen mass balance equation with the existence of artificial aeration as its boundary conditions. A mathematical model is formulated for the optimization of the allocation of aeration capacity to each of the series of aerators subject to a limitation on total available aeration capacity. The objective function is the minimization of the sum of the squares of the aeration costs and the costs incurred by damaging or unnecessarily improving the system. The original constrained allocation problem is simplified by converting it to an unconstrained one via the use of Lagrange multiplier. A discretized dynamic programming algorithm is formulated for finding the optimal allocation policy. A typical optimal aeration capacity allocation policy and its corresponding dissolved oxygen sag profile for the illustrated numerical example is presented, and the relationship between the total available aeration capacity and Lagrange multiplier is also developed treating weighting factors as parameters.     

Enhanced decomposition of NO on the alkalized PdO/Al2O3 catalyst

Experimentally, decomposition of NO on the alkalized Pd/Al2O3 catalyst is remarkably enhanced at 825-1000 K. The enhancement in N2 yield may be due to the additional basic sites on the alkalized catalyst that can trap NO molecules. However, at T > 1000 K, due to the fact that the absorbed oxygen in subsurface or bulk of Pd was involved in the formation and desorption of oxygen molecules, yield of oxygen was enhanced.     

Destruction of PCDD/Fs by SCR from flue gases of municipal waste incinerator and metal smelting plant

Partitioning of PCDD/F congeners between vapor/solid phases and removal and destruction efficiencies achieved with selective catalytic reduction (SCR) system for PCDD/Fs at an existing municipal waste incinerator (MWI) and metal smelting plant (MSP) in Taiwan are evaluated via stack sampling and analysis. The MWI investigated is equipped with electrostatic precipitators (EP, operating temperature: 230 degrees C), wet scrubbers (WS, operating temperature: 70 degrees C) and SCR (operating temperature: 220 degrees C) as major air pollution control devices (APCDs). PCDD/F concentration measured at stack gas of the MWI investigated is 0.728 ng-TEQ/Nm(3). The removal efficiency of WS+SCR system for PCDD/Fs reaches 93% in the MWI investigated. The MSP investigated is equipped with EP (operating temperature: 240 degrees C) and SCR (operating temperature: 290 degrees C) as APCDs. The flue gas sampling results also indicate that PCDD/F concentration treated with SCR is 1.35 ng-TEQ/Nm(3). The SCR system adopted in MSP can remove 52.3% PCDD/Fs from flue gases (SCR operating temperature: 290 degrees C, Gas flow rate: 660 kN m(3)/h). In addition, the distributions of PCDD/F congeners observed in the flue gases of the MWI and MSP investigated are significantly different. This study also indicates that the PCDD/F congeners measured in the flue gases of those two facilities are mostly distributed in vapor phase prior to the SCR system and shift to solid phase (vapor-phase PCDD/Fs are effectively decomposed) after being treated with catalyst. Besides, the results also indicate that with SCR highly chlorinated PCDD/F congeners can be transformed to lowly chlorinated PCDD/F congeners probably by dechlorination, while the removal efficiencies of vapor-phase PCDD/Fs increase with increasing chlorination.     

Heavy metal concentrations of the soldier crab (Mictyris brevidactylus) along the inshore area of Changhua, Taiwan

In order to compare with and assess the metal-accumulating ability of the soldier crab (Mictyris brevidactylus), the concentrations of copper (Cu), zinc (Zn), nickel (Ni), lead (Pb) and cadmium of ambient water and the Pacific oyster (Crassostrea gigas) were investigated. Seawater, soldier crabs and Pacific oysters were simultaneously collected from the Changhua coastal area, located in West-Central Taiwan. The Pacific oyster and stream results proved that site B is contaminated by Cu, Zn and Pb from streams B-1 and B-2. The highest Cu, Zn, Ni and Pb concentrations in soldier crabs appeared at site B, and significant differences in the accumulated concentrations of Cu, Pb, Zn and Ni in soldier crabs were found between the sites tested. The highest bioconcentration factors of Cu, Zn, Ni and Pb in soldier crabs appeared at site B, indicating that the soldier crab can accumulate Cu, Zn and Pb to the same degree as the Pacific oyster. In fact, soldier crabs can accumulate more Ni than Pacific oysters, better reflecting the conditions of the ambient environment. These phenomena, as well as the fact that the soldier crab is able to accumulate relatively high levels of Cu, Zn, Pb and Ni, suggest that this crab is a potential biomonitor of Pb and Ni pollution in aquatic ecosystems.     

Bisphenol A occurred in Kao-Pin River and its tributaries in Taiwan

Bisphenol A (BPA), one of the endocrine-disrupting chemicals, was detected in water collected from Kao-Pin River and its tributaries. Results indicated that 59% of the water samples contained BPA. Concentrations ranged from less than the limit of detection (LOD, 0.037) to 4.23 μg/L. The mean concentrations were 0.16, 0.20, 1.02, 1.30, and 0.30 μg/L for sampling sites S1, S2, S3, S4, and S5, respectively. Concentrations were not significantly different between high and low-flow periods in sites S2, S3, and S4. In site S1, concentrations in the high-flow period were significantly greater than during the lower flow period, and in site S5, BPA concentration in the low-flow period was significantly greater than in the high-flow period. The BPA mass flow rate in site S5 was greater in the high-flow period than in the low-flow period.     

The Role of Climate and Human Influences in the Dry‐Up of the Jinci Springs,China1

Abstract: One of the largest karst springs in North China, the Jinci Springs, dried up and has remained dry since 1994. We develop a correlation analysis with time‐lag and a regression analysis with time‐lag to study the relation between spring flow and precipitation. This allows us to obtain a better understanding of karst hydrological processes by differentiating the contribution of variation in precipitation from anthropogenic impacts on the dry‐up of Jinci Springs. We divided the karstic hydrological processes into two phases: pre‐1961 and post‐1961. In the first phase (i.e., 1954‐1960) the groundwater recharge was affected by precipitation alone, and in the second phase (i.e., 1961‐1994) the groundwater recharge was influenced by both precipitation and human activities. Using precipitation and groundwater recharge data in the first phase, we set up a groundwater recharge model with time‐lags. By running the time‐lags model, we acquired the groundwater recharge likely to occur under the sole effect of precipitation in the second phase. Using a water‐balance calculation, we conclude that the groundwater recharge exhibited statistical stationarity, and the Jinci Springs dry‐up was the result of anthropogenic activities. At least three specific types of anthropogenic activities contributed to the drying‐up of Jinci Springs: (1) groundwater pumping accounts for 51%, (2) the dewatering from coal mining accounts for 33%, (3) and dam‐building 14%. The drying‐up of Jinci Springs meant that the groundwater drained from the aquifer’s fractures, and subsequently changed the structure of the karst aquifer. Although groundwater exploitation has been reduced, the flow at Jinci Springs has not reoccurred.     

Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies

Abstract

This paper reviews the regulatory history for nitrogen oxides (NO_x) pollutant emissions from stationary sources, primarily in coal-fired power plants. Nitrogen dioxide (NO₂) is one of the six criteria pollutants regulated by the 1970 Clean Air Act where National Ambient Air Quality Standards were established to protect public health and welfare. We use patent data to show that in the cases of Japan, Germany, and the United States, innovations in NO_x control technologies did not occur until stringent government regulations were in place, thus “forcing” innovation. We also demonstrate that reductions in the capital and operation and maintenance (O&M) costs of new generations of high-efficiency NO_x control technologies, selective catalytic reduction (SCR), are consistently associated with the increasing adoption of the control technology: the so-called learning-by-doing phenomena. The results show that as cumulative world coal-fired SCR capacity doubles, capital costs decline to ~86% and O&M costs to 58% of their original values. The observed changes in SCR technology reflect the impact of technological advance as well as other factors, such as market competition and economies of scale.