中美气候变化论坛

由美国加州大学伯克利分校和北京大学联合主办的中美气候变化论坛于5月23日至24日在旧金山开幕．有来自中美两国以及欧洲等地的专家学者近200人参加了论坛。     

资源核算及其纳入国民经济核算体系初步研究

实施资源核算并将其纳入国民经济核算体系是保障和促进国民经济持续、稳定、协调发展的重要措施之一。本文论述了对这一问题初步研究的基本思路、框架、方法,并以1988年我国森林资源状况为研究范例,说明了核算方法的具体应用。     

圆管空拔壁厚变化分析

此文利用主应力法推导出圆管空拔壁厚变化量解析式。该式计算结果与以定常三维流动上界解析同类问题结果相接近,且表达式简单,也与拔管的实验结果相一致。因而,可在圆管空拔壁厚计算时推广应用。     

台湾7.6级地震及其强余震前电磁辐射特征

本文总结了1986年11月15日台湾花莲海域地震及其强余震前电磁辐射的前兆特征。所用的仪器为DDC-2型电子补偿仪、XWX-2042电位差计,记录极距为100m的两埋地电极间所接收到的电磁辐射信息,震前异常波形最大幅度可达187.5mv,为正常背景的十数倍,频谱较宽(0.005—5Hz)。这种特征对认识发生在太平洋板块与亚欧板块上的地震有一定意义。     

循环热处理对高速钢超塑性的影响

此文研究了循环热处理工艺对W6Mo5Cr4V2钢超塑性的影响.结果表明:该钢在1040℃两次循环淬火是实现其超塑性的最佳热处理工艺;按此工艺进行预处理后,在810℃、初始应变速率为5.56×10~(-1)s~(-1)的条件下,该钢的超塑延伸率可达187%.     

Adsorption of arsenate on soils. Part 2: modeling the relationship between adsorption capacity and soil physiochemical properties using 16 Chinese soils

An attempt has been made to elucidate the effects of soil properties on arsenate adsorption by modeling the relationships between adsorption capacity and the properties of 16 Chinese soils. The model produced was validated against three Australian and three American soils. The results showed that nearly 93.8% of the variability in arsenate adsorption on the low-energy surface could be described by citrate-dithionite extractable Fe (Fe(CD)), clay content, organic matter content (OM) and dissolved organic carbon (DOC); nearly 87.6% of the variability in arsenate adsorption on the high-energy surface could be described by Fe(CD), DOC and total arsenic in soils. Fe(CD) exhibited the most important positive influence on arsenate adsorption. Oxalate extractable Al (Al(OX)), citrate-dithionite extractable Al (Al(CD)), extractable P and soil pH appeared relatively unimportant for adsorption of arsenate by soils.     

乐山市核单位环境放射性水平的调查分析

乐山市为全省核单位较多的地区之一.其环境陆地γ辐射剂量率、土壤、水体中放射性核素含量或元素浓度均接近于地区直水平.说明对环境无显著性影响.     

PRED问题与地理工程

本文首先定义了由人口、资源、环境和发展构成的PRED问题的思路,讨论了它的性质;然后提出用地理工程解决PRED问题,并构建了地理工程的理论框架。     

耕地不同产量水平的面积与分布监测法

查清中低产田的面积、分布与开发条件是制定农业综台开发规划的重要依据。采用按公里网布设的农业资源动态监测系统,开展对耕地不同产量水平的面积与分布的动态监测,其方法具有准确、简便和实用的特点。     

Reductive dechlorination of 1,2,4-trichlorobenzene with palladized nanoscale Fe(zero-valent) particles supported on chitosan and silica

In this study, nanoscale Pd-Fe particles, with diameters less than 100 nm, were synthesized and dispersed over the chitosan and silica supports. Three different Pd-Fe particles were synthesized, namely 0.1% Pd-Fe, 0.5% Pd-Fe and 1.0% Pd-Fe. SEM images confirmed that the Pd-Fe particles were dispersed over the surface of the supports while SEM-EDX confirmed evenly distribution of Pd over Fe(zero-valent). alpha-Fe(zero-valent) crystallites were identified by means of XRD and observed in TEM. Reductive dechlorinations of 1,2,4-trichlorobenzene (1,2,4-TCB) with the nanoscale Pd-Fe/chitosan and Pd-Fe/silica were carried out in the batch experiment system. Disappearance of the parent species and formation of the reaction intermediates and end product were monitored at discrete times. The results show that the nano-scale Pd-Fe particles were able to completely dechlorinate the chlorinated benzenes within a very short timescale. Complete dechlorinations of 1,2,4-TCB to benzene were achieved within 60 min with the 1.0% Pd-Fe/chitosan and within 100 min with the 1.0% Pd-Fe/silica. Reaction rates were observed to increase with increasing Pd content of the Pd-Fe/support. The reactions apparently followed pseudo-first-order kinetics with respect to the 1,2,4-TCB transformation. A kinetic model is constructed to fit the experimental results for the reactions, enabling identification of the major and minor dechlorination pathways of 1,2,4-TCB. The model suggests that the 1,2,4-TCB transformation mainly followed the primary pathway of direct reductive dechlorination to benzene and secondary pathway of sequential hydrogenolysis to 1,2-dichlorobenzene (1,2-DCB) and then chlorobenzene (CB) or benzene.