Recovery of high purity zinc from filter ash produced during the thermal treatment of waste and inerting of residual materials.

The method described below recovers zinc, a valuable metal that is present in high concentrations in filter ash from the thermal treatment of waste, and returns the filter ash stripped of heavy metals to the combustion process in order to destroy organic substances. On an industrial scale, the heavy metals in the filter ash were mobilized by means of hydrochloric acid in the acidic fluids produced in the flue-gas scrubbing process without the addition of further chemicals. A pilot plant for implementing the selective reactive extraction (SRE) method on the ash extracts, using a highly selective complexant, was operated over a period of several months in order to obtain a concentrated, high-purity zinc salt solution (mono metal solution). A zinc depletion rate of 99.8% in the aqueous extract was achieved using mixer-settler units. The residual zinc concentration in the waste water was then < 2 mg L(-1). By stripping the loaded organic phase, a concentrated, high-purity mono metal solution with 190 g L(-1) zinc was obtained. Zinc metal with a purity > 99.99% is then separated by means of electrolysis. To destroy organic substances present in the filter ash, particularly dioxins and furans, the extracted filter ash cake was returned to the combustion process together with household waste. Plant operation, raw and pure gas parameters, and quality of the bottom ash produced were not impacted by such recirculation. The profitability of the overall process is attributable both to the recovery of valuable zinc metal and to the cost savings made in waste water treatment and in the disposal of the waste combustion residues because the remaining mixture of filter ash and bottom ash can be reused in a combined form. This method therefore supports the sustainable and economically viable reuse of filter ash.     

Evaluation of Water Quality Projects in the Lake Tahoe Basin

Lake Tahoe is a large sub alpine lake located in the Sierra Nevada Range in the states of California and Nevada. The Lake Tahoe watershed is relatively small (800 km(20) and is made up of soils with a very low nutrient content and when combined with the Lake's enormous volume (156 km(3)) produces water of unparalleled clarity. However, urbanization around the Lake during the past 50 yr has greatly increased nutrient flux into the Lake resulting in increased algae production and rapidly declining water clarity. Lake transition from nitrogen limiting to phosphorous limiting during the last 30 yr suggests the onset of cultural eutrophication of Lake Tahoe. Protecting Lake Tahoe's water quality has become a major public concern and much time, effort, and money has been, and will be, spent on this undertaking. The effectiveness of remedial actions is the subject of some debate. Local regulatory agencies have mandated implementation of best management practices (BMPs) to mitigate the effects of development, sometimes at great additional expense for developers and homeowners who question their effectiveness. Conclusive studies on the BMP effectiveness are also expensive and can be difficult to accomplish such that very few such studies have been completed. However, several project evaluations have been completed and more are underway. Such study usually demonstrates support of the project's effectiveness in decreasing nutrient flux to Lake Tahoe. Here, we review the existing state of knowledge of nutrient loading to the Lake and to highlight the need for further evaluative investigations of BMPs in order to improve their performance in present and future regulatory actions.     

Comparison of palladium and platinum in environmental matrices: Palladium pollution by automobile emissions?

A new type of automobile catalyst based on an active Pd/Rh-layer is presently being introduced into the European market. Accordingly, in order to establish baseline information, this work attempts to assess the magnitude of Pd emissions by automobile catalysts to date. Thus, a survey is presented on Pd and Pt levels detected in polluted environmental matrices (grass, soil, dust, sludges) as available from the literature. Additionally, Pd data measured by selective preconcentration/GF-AAS-detection in polluted grass, in a time series of sewage sludge ashes back to 1972, in dust, as well as in urban rain are presented. Since the data basis from the literature is partly inconsistent, the possible impact of different analytical attempts on the data is discussed. The relationship between Pt and Pd concentration from most of the results is between 5 and 10 (Pt/Pd). However, relations down to 0.04 are also reported, thus implying anthropogenic Pd input from additional sources.     

The ‘new’ economics of iron and steel

The author commences his analysis of the iron and steel industry by examining the historical background of the industry, and discusses its importance for the world economy. He examines the implications for the world industry of the successful development of the steel industry in Japan, and traces the evolution of a commodity cartel in the iron ore market, analysing the price levels of the commodity in the ‘free’ and ‘controlled’ markets. Following a discussion of the role of energy and coking coal supplies in the industry, the author examines the evolution of this industry in the less developed countries, with particular reference to the role of technology in the industry's development. He concludes that there have been important structural changes in the world industry, embraced by the concept of ‘partial demise’.     

Response of native plants of northeastern United States and southern Spain to ozone exposures; determining exposure/response relationships

Tropospheric ozone has been identified as the most important regional scale air pollutant across much of eastern United States of America and many areas of Mediterranean climes in southern Europe. Recent field surveys in the northeastern USA and in southeastern Spain have revealed many additional plant species that exhibit symptoms typical of ozone-induced injuries. Objectives of this study were to confirm ozone as the cause of the observed foliar symptoms, determine ozone induced exposure/response relationships, and identify possible bio-indicator species. Thirteen native species of northeastern USA and 27 native species of southeastern Spain were selected for study. Plant species were exposed to ozone within 16 CSTR chambers in a greenhouse during the summer seasons of 2000 and 2001; ozone exposures of 30, 60, 90, and 120 ppb were delivered for 7 h/day, 5 days/week. Results have confirmed that with few exceptions, symptoms observed in the field were induced by exposures to ambient ozone. Species differed significantly in terms of the exposures required for the initiation of visible symptoms and subsequent injury progression.