Leadership and employees’ perceived safety behaviours in a nuclear power plant: A structural equation model

Leadership is considered an essential element in guaranteeing the safe running of organizations. The purpose of the present study is to find out how leader behaviours influence employees’ safety behaviours (perceived safety behaviours) in the nuclear field. In an attempt to answer this question, the authors of this research have considered the way this influence is exercised, taking into consideration some important factors like safety culture and safety climate. To achieve this, the empowerment leadership model, based on a behavioural approach to leadership, was used. The sample was made up of 566 employees from a Spanish nuclear power plant. The results indicated that when safety culture was strong, leader behaviour generated a higher safety climate among the members, which predicted their perceived safety behaviours. Support was found for a structural model linking leadership and safety behaviour to safety culture and safety climate. The implications of these findings for the theory of safety and the way they can be put into practice are outlined.     

Non-catalytic and catalytic wet air oxidation of pharmaceuticals in ultra-pure and natural waters

A wet air oxidation (WAO) process was applied to four selected pharmaceuticals (metoprolol, naproxen, amoxicillin, and phenacetin) individually dissolved in ultra-pure water, varying the temperature and oxygen pressure. Due to the moderate (amoxicillin) or low (metoprolol, naproxen, and phenacetin) efficiency found in the oxidation of these pollutants, a catalytic wet air oxidation (CWAO) process was then tested using a platinum catalyst supported on multi-walled carbon nanotubes (CNT). In this CWAO process, the pharmaceuticals were dissolved together in ultra-pure water and in four natural water matrices—a reservoir water, a groundwater, and two waters from different municipal wastewater treatment plants. On the basis of the measurements of their removals, a discussion is given of the influence of the main operating variables: the presence or absence of catalyst, type of catalyst (the synthesized Pt/CNT or a commercial Pt/AC), catalyst dosage (0.005–0.050 g), temperature (120–140 °C), and oxygen pressure (20–40 bar). In most experiments, the removals were in the sequence: amoxicillin > naproxen > phenacetin. In addition, total organic carbon (TOC) removal measurements were made of some of the natural waters tested.     

Reactivity of litter leachates from California oak woodlands in the formation of disinfection by-products

Litter materials from forested watersheds can be a significant source of dissolved organic matter (DOM) to surface waters that can contribute to the formation of carcinogenic disinfection by-products (DBPs) during drinking-water chlorination. This study characterized the reactivity of DOM from litter leachates of representative vegetation in oak woodlands, a major plant community in the Foothill Region of California. Leachates from fresh and decomposed litter (duff) from two oak species, pine, and annual grasses were collected for an entire rainy season to evaluate their reactivity to form DBPs on chlorination. Relationships among specific ultraviolet absorbance (SΔUVA), fluorescence index (FI), specific differential ultraviolet absorbance (SΔUVA), specific chlorine demand (SCD), and the dissolved organic carbon:dissolved organic nitrogen (DOC:DON) ratio to the specific DBP formation potential (SDBP-FP) were examined. The DOM derived from litter materials had considerable reactivity in forming trihalomethanes (THMs) (1.80-3.49 mmol mol), haloacetic acid (HAAs) (1.62-2.76 mmol mol(-1)), haloacetonitriles (HANs) (0.12-0.37 mmol mol(-1)), and chloral hydrate (CHD) (0.16-0.28 mmol mol). These values are comparable to other identified watershed sources of DBP precursors reported for the California Delta, such as wetlands and organic soils. Vegetation type and litter decomposition stage (fresh litter versus 1-5 yr-old duff) were key factors that determined characteristics of DOM and their reactivity to form DBPs. Pine litter had significantly lower specific THM formation potential compared with oak and grass, and decomposed duff had a greater DON content, which is a precursor of HANs and other nitrogenous DBPs. The SΔUVA and SDBP-FP were temporally variable and dependent on vegetation type, degree of decomposition, and environmental conditions. Among the optical properties of DOM, SΔUVA was the only parameter that was consistently correlated with SDBP-FP.     

Evaluation of environmental management resources (ISO 14001) at civil engineering construction worksites: a case study of the community of Madrid

In recent years, significant advances have been made in business organization and management. The growing demands of clients as well as the globalization of world markets are among the many factors that have led to the establishment of systems of quality control and environmental management as a competitive strategy for businesses. When compared to other professional sectors, the construction sector has been slower to respond to environmental problems and to adopt Environmental Management Systems (EMS). In the world today the ISO 14001 standard is currently the main frame of reference used by construction companies to implement this type of management system. This article presents the results of a general study regarding the evaluation of the application of the ISO 14001 standard at civil engineering construction worksites in the Community of Madrid (Spain), specifically pertaining to requirement 4.4.1, Resources, roles, responsibilities, and authority. According to requirement 4.4.1, company executives should appoint people responsible for implementing the EMS and also specify their responsibilities and functions. The personnel designated for supervising environmental work should also have sufficient authority to establish and maintain the EMS. The results obtained were the following: - EMS supervisors did not generally possess adequate training and solid experience in construction work and in the environment. Furthermore, supervisors were usually forced to combine their environmental work with other tasks, which made their job even more difficult. - Generally speaking, supervisors were not given sufficient authority and autonomy because productivity at the construction site had priority over environmental management. This was due to the fact that the company management did not have a respectful attitude toward the environment, nor was the management actively involved in the establishment of the EMS. - Insufficient resources were allocated to the Environmental Management Unit. As a result, the application of EMSs in construction projects often appeared to be more of a formality, which was merely a way of maintaining the certification of the Environmental Management System. It was more a means of meeting the requirements for submitting a tender to contracting organisms rather than an indicator of any real commitment to improving the environmental performance of construction companies.     

Recycling, reuse and energetic valuation of meat industry wastes in Extremadura (Spain)

The environmental problem caused by the effluents from the four main agrifood industries in Extremadura (W Spain) is evaluated in the present work. In particular, attention is paid to the management of wastes from slaughterhouse operations. Pollution is quantified in terms of equivalent population and biological oxygen demand, for which very high values are reported.Efforts are also focused on the search of viable technical solutions for the treatment of those residues and their energetic valuation. In this sense, anaerobic digestion techniques are proposed, not only because they lead to a drastic decrease in their pollution potential, but also because significant volumes of biogas are obtained. This biogas might be used to produce electricity to be transferred to the electrical network. This way, anaerobic digestion plants would allow depreciation within a relatively short period.In particular, an analysis of the economics of a plant for the codigestion of solid and liquid effluents from meat industry is carried out, and a payback time between 7 and 8 years was achieved.     

Mercury levels and health parameters in the threatened Olrog��s Gull (Larus atlanticus) from Argentina

Mercury (Hg) exposure was investigated through feathers of Olrog's Gull and related to health parameters in adults (hematocrit, total plasma proteins, morphometric measures, sex) and chicks (hematocrit, total plasma proteins, immunoglobulins G and M) from a colony located in estuary of Bahía Blanca, Argentina. Mercury concentrations were 5.50 ± 2.59 μg g?1 (n = 44) in live adults, 1.85 ± 0.45 μg g?1 (n = 45) in live chicks and 1.81 ± 0.41 μg g?1 (n = 41) in dead chicks. Large differences were observed between live adults and live or dead chicks and small differences between live and dead chicks. In the adults, the sex of the birds was the variable that best explained Hg concentrations. Male birds had higher concentrations than females; this suggests that the clutch provides a sink for mercury during egg laying. Hg concentrations in both adults and live chicks were associated with higher hematocrits. This could be associated with upregulated erythropoiesis to compensate for increased rate of destruction of prematurely senescent, Hg-contaminated erythrocytes. Based on our results, on the levels of Hg pollution in the past in the study area, and on the dietary specialization of Olrog's Gull, we must be vigilant about potential negative effects of Hg pollution on this population and recommend continued monitoring on this threatened species.     

The occurrence of Shiga toxin-producing Escherichia coli in bathing water of the Sierra de la Ventana region, Buenos Aires Province, Argentina

The region of Sierra de la Ventana is located in the southwest of Buenos Aires Province, Argentina. Traditionally, this area has been devoted to livestock and agriculture, but tourism has had a significant development in recent years. In the region, there are many rivers and streams that are used for swimming and bathing. A survey of the occurrence of Shiga toxin-producing Escherichia coli (STEC) in these waters was conducted, and the microbiological quality of rivers and streams was investigated. No E. coli O157 was recovered by immunomagnetic separation. Nevertheless, the Shiga toxin gene, exclusively stx2 genotype, was detected in four non-O157 E. coli strains. Two STEC strains carried eae factor, but none of them harbored the EHEC-hlyA gene. Three of the STEC isolates belonged to samples obtained in the warm months, and one to the winter sampling. In the sample sites where STEC strains were isolated the counts of E. coli/100 ml exceeded or were close to the limit recommended by the United States Environmental Protection Agency for bathing water. The relationship observed between the rainy season and E. coli counts suggests that among the main causes for the hygienic indicator increase is the runoff of manure deposited on soils that may also induce the entrance of pathogens into the aquatic environment. This research, the first reporting STEC isolation from recreational waters in this area, revealed that streams and rivers from a beef-producing area of Argentina are a reservoir of STEC strains.     

Little Egret (Egretta garzetta) as a bioindicator of trace element pollution in Tunisian aquatic ecosystems

The Little Egret, Egretta garzetta, has breeding colonies in the island of Chikly (in the lake of Tunis) and in Thyna saltpans (in the gulf of Gabès), two important Tunisian wetlands that are strongly affected by anthropogenic activity. Here, we used E. garzetta chick feathers for environmental monitoring of breeding grounds of this species. Since trophic ecology is fundamental when interpreting contamination levels, our approach combined both trace-element (Hg, Pb, Cd, and Se) and stable-isotope analysis of ??¹³C, ??¹⁵N, and ??³⁴S. Hg, Se, and ??¹⁵N levels were higher in specimens collected on Chikly than in Thyna. These observations highlight the degree of eutrophication of the lake of Tunis. Yellow-legged gulls (Larus michahellis) breeding in the same areas also feeds in the lake and attains similar concentrations of Hg and Se. In Thyna, egrets and gulls exploit distinct foraging habitats, as demonstrated by stable isotope analysis. The highest Hg and Se concentrations were found in Thyna. This result is consistent with greater exploitation of marine resources from the gulf of Gabès.     

Woody Vegetation Composition and Structure in Peri-urban Chongming Island, China

Chongming, the world’s largest alluvial island, is located within the municipality of Shanghai, China. Recent projects have now linked peri-urban Chongming to Shanghai’s urban core and as a result will soon undergo substantial changes from urbanization. We quantitatively analyzed the structure and composition of woody vegetation across subtropical, peri-urban Chongming as a basis for sustainable management of these rapidly urbanizing subtropical ecosystems elsewhere. We used 178 permanent, random plots to statistically and spatially analyze woody plant composition and tree structure across the 1,041 km² of Chongming. A total of 2,251 woody plants were measured comprising 42 species in 37 genera. We statistically and geospatially analyzed field data according to land uses and modeled air pollution removal by trees. Average tree diameter at breast height, total height, and crown widths on transportation land uses were greater than other land uses. These same values were lowest on forest land use and greater tree cover was associated with areas of increased anthropogenic activity. Less than 20 % of the woody vegetation was exotic and a species richness index was significantly different between land uses due to legacy effects. Composition of agriculture and forest land uses were similar to residential and transportation. Tree cover across Chongming was also estimated to annually remove 1,400 tons of air pollutants. We propose that this integrated and quantitative method can be used in other subtropical, peri-urban areas in developing countries to establish baseline trends for future sustainability objectives and to monitor the effects of urbanization and climate change.